Physical Sciences and Mathematics Commons^™

Toward A Greater Comprehension Of The Paraná Epicontinental Sea During The Late Paleozoic Ice Age: The Glacial And Postglacial Record In The Western Paraná Basin (Brazil) And The Kaokoveld Fjord Network (Namibia), Eduardo Luiz Menozzo Da Rosa

Theses and Dissertations

The late Paleozoic Ice Age (LPIA; 362 to 255 Ma) was an icehouse interval that drove substantial changes in Earth’s surficial systems. Numerous paradigms regarding aspects of the LPIA were established throughout ~150 years of research based primarily on the evolving state of knowledge in sedimentology. The near-field lithological evidence for widespread glaciation across sedimentary basins of Gondwana are the building blocks for comprehensive paleoclimatic, biologic, paleogeographic, and ice volume models. Nevertheless, the embodied glacial record from several late Paleozoic Gondwanan depocenters still rely on insufficient and/or outdated sedimentologic and stratigraphic studies, which can lead to misinterpretations in models built …

Hf Radar: Shining A Light On Ocean Currents, Douglas Cahl

Theses and Dissertations

High Frequency (HF) radar systems are commonly used to estimate surface ocean currents over the coastal ocean. Their range depends on their operational frequency and low frequency systems (≤ 10 MHz) can reach distances up to 200 km from the coastline. These systems are used to estimate surface currents by measuring the phase speed of wind-driven waves and comparing the measured speed with that expected theoretically; deviations from the theoretical still-water phase speed are attributed to ocean surface currents. Although HF radar systems are considered a mature technology and the accuracy of the radar-derived surface current estimates is well studied, …

Groundwater Flow And Salt Marsh Migration: The Forest/Marsh Boundary, Camille Rossiello

Theses and Dissertations

Salt marshes migrate landward in response to sea level rise, but the rate of this migration is not constant and can be influenced by pulse disturbances. Long term observations at Sapelo Island, Georgia, show that salt marsh migration has occurred during droughts, but the mechanism for this migration is unclear. Drought is thought to influence salt marsh migration by reducing fresh groundwater discharge from the upland. Rising sea level also encroaches on the upland, which could cause movement of the freshwater lens inland. A two-dimensional numerical model was built to simulate groundwater flow and solute transport based on the Marsh …

Evaluating The Relationship Between Methane Seeps And Seafloor Geomorphology On The Northern Us Atlantic Margin, Gabriel Hernandez

Theses and Dissertations

Methane seeps are a transport pathway for carbon from seafloor sediments to the marine environment with important implications for global biogeochemical cycling. Accordingly, there is substantial interest in better understanding the processes that control seep location and predicting the distribution of seeps with existing seafloor datasets. Visual evaluation of methane seeps, in multibeam sonar water column data, suggests a spatial relationship between seeps and specific seafloor morphologic features such as ridge crests. In this thesis, seafloor geomorphology at 1996 seep detection sites on the US Atlantic margin was quantitatively characterized by geomorphologic phonotype, bathymetric position index, slope, rugosity, and aspect …

Testing The Use Of Anisotropy Of Magnetic Susceptibility (Ams) In Determining Genetic Origins Of Paleoproterozoic Diamictites, Miles A. Harbury

Theses and Dissertations

The Huronian Supergroup (2.4-2.1 Ga) in Ontario, Canada is widely accepted as an important stratigraphic interval for interpreting Paleoproterozoic climate. This is because it contains some of the oldest glaciogenic rocks on the planet. However, massive and poorly-stratified diamictites in the Gowganda Formation of the Huronian Supergroup have varying depositional interpretations among sedimentologists (subglacial, rainout, sediment gravity flow etc.). Diamictites can occur from a variety of processes and, therefore, proper depositional interpretation is essential for unraveling detailed environmental conditions at the time of deposition. Anisotropy of magnetic susceptibility (AMS) looks at the orientation of magnetic particles within a rock and …

Exploring The Current Training Of Undergraduate Geology Students And Teaching Spatial Skills To Improve Student Outcomes, Ann Marie Klyce

Theses and Dissertations

Spatial skills, which represent the ability to mentally manipulate objects (Schneider & McGrew, 2012; Atit et al., 2020) have been shown to be correlated with entrance, persistence and success in STEM (Shea et al., 2001; Wai et al., 2009). Specifically, these skills have been shown to be necessary to geologists and geoscientists (Hegarty, 2014; Gagnier et al., 2016). While we recognize the importance of these skills, explicit training in them is rarely offered (NRC 2006). Consequently, cognitive scientists and discipline based education researchers have begun concerted efforts to offer training in spatial skills to improve student outcomes (e.g. Uttal et …

Dust Production And Transport In A Long-Lived Fluvial-Eolian System In The Pampas Of South America, Blake Marcus Stubbins

Theses and Dissertations

Wind-blown dust from southern South America links the terrestrial, marine, atmospheric, and biologic components of Earth’s climate system. The Pampas of central Argentina (~33-40° S) contain an extensive upper Miocene to Holocene eolian record that spans the relatively warm conditions of the Late Miocene to cooler climates of the Plio-Pleistocene and Holocene. We collected 13 loess, paleosol, and fluvial samples from the upper Miocene Cerro Azul and Rio Negro Formations which resulted in n = 5129 new detrital zircon U-Pb ages. Late Miocene rivers conveyed sediment from northern Patagonia, the Andes adjacent to the Pampas, and the Sierras Pampeanas to …

Geologic Mapping Of The Sparta 7.5-Minute Quadrangle In Northern Mississippi Via Remote Sensing, Traditional Geologic Survey, And Applied Geospatial Information Systems Methods, Rayford Dean Parnell

Theses and Dissertations

Traditional geologic mapping involves substantial time and labor in the field as geologic contacts are manually examined and interpreted. The processes of mapping geologic contacts can be condensed into a quicker and less laborious process using advances in remote sensing and GIS (geospatial information systems), including increased resolution and computerized data management and interpretation. Application of these advances reduces the costs and time of geologic mapping. The Sparta 7.5-minute quadrangle provides a mostly unaltered view of regional Paleocene and Upper Cretaceous geology due to its rural locale, lack of development, and stream topography. Recently LiDAR (Light Detection And Ranging) survey …

Surficial Geologic Mapping Of The Starkville 7.5-Minute United States Geological Survey Quadrangle 33088d-7 In Oktibbeha County, Mississippi, Jonathan Leard

Theses and Dissertations

The Starkville Quadrangle is a hotspot for geological research. The Late Cretaceous is represented by the Demopolis Formation in the northeast corner of the quadrangle, followed by the Ripley Formation, and the Prairie Bluff Formation. The K-Pg boundary is exposed in the quadrangle, and the remarkable paleontology is of global importance. The Clayton Formation is the first Paleocene unit. Where the Clayton Formation channel sands are in contact with the underlying Prairie Bluff Formation, springs occur. Springs were a rare source of water in the Black Prairie and spurred the settlement of the area over 10,000 years ago. The Paleocene …

Mitigating The Shrink-Swell Capacities Of The Yazoo Clay Through Application Of Lime And Biochar, Austin Alan Brister

Theses and Dissertations

Shrinking and swelling in Yazoo Clay is a cause of concern for construction projects in Mississippi. This thesis investigated the effects of adding lime and Douglas Fir biochar on the shrinking and swelling capabilities of Yazoo Clay. Samples of Yazoo Clay were mixed with the additives in defined ratios and subjected to the free swell test and the COLE(rod) test. Biochar addition reduced the COLE(rod) of the samples a large amount, while increasing the swelling potential of the clay samples. The addition of lime slightly reduced both the shrinking and swelling potentials of the samples. The mineralogical variability of Yazoo …

Using Anisotropy Of Magnetic Susceptibility (Ams) To Identify A Tectonic Lineation In The Pulo Do Lobo Formation In The Southern Iberian Shear Zone Near Aracena, Spain, Devin Levang

Theses and Dissertations

The Southern Iberian Shear Zone (SISZ) is a Variscan-aged suture representing the closure of a small ocean basin during the Carboniferous. The SISZ is bounded on either side by the well-studied, relatively homogeneous Beja-Acebuches Metabasites (BAM) and the complex and heterogeneous accretionary metasedimentary rocks of the Pulo do Lobo (PdL). The SISZ underwent a combination of shortening and lateral shearing known as transpression. Despite a very well-developed tectonic foliation, kinematic interpretation in the PdL is made difficult by a lack of easily identifiable lineations. Anisotropy of magnetic susceptibility (AMS), a geophysical technique measuring the relative anisotropy of magnetic susceptibility axes …

Unraveling Deformation Mechanisms And Kinematics In Metasedimentary Rocks Along The Southern Iberian Shear Zone, Kayla P. Kopinski

Theses and Dissertations

The primary goal of this project is to document deformation mechanisms in quartz-rich rocks across a 100 m wide ductile shear zone to evaluate whether strain localization at the brittle-ductile transition is accompanied by variations in active or dominant deformation mechanisms. A secondary goal of this project is to evaluate whether the kinematic framework varies across a shear zone with a major rheological boundary. The Southern Iberian Shear Zone (SISZ), a major terrane bounding shear zone within the Iberian Massif, is an ideal location to study these questions because it is a regional scale shear zone currently exposed at the …

Strain Development And Partitioning Across A Transpressional Shear Zone Along A Quartzite- Metagabbro Contact In The Black Hills Uplift, South Dakota, Eric L. Schuemann

Theses and Dissertations

The Nemo region of South Dakota’s Black Hills offers an ideal location to study transpressional shear zones because it hosts an exposed Archean lithological boundary between two contrasting rheological units, the Boxelder Creek Quartzite (BCQ), a rift-depositional quartzite, and the Blue Draw Metagabbro (BDM), a metagabbro sill, deformed within a ductile shear zone that represents the beginning of main-phase formation of the North American continent as we know it today. The tectonic setting of the Black Hills is at the eastern edge of the Archean Wyoming province, located near the Trans-Hudson Orogeny suture zone that formed between the Wyoming and …

Immobilization Of Uranium And Iodine By Calcium Phosphate Minerals, Angel L. Jimenez-Arroyo

Theses and Dissertations

This dissertation is comprised of three independent but interconnected studies with the scope of further understanding uranium and iodine partitioning between apatite and fluid. The studies herein presented investigated: 1) brushite to apatite crystallization method; 2) the degree of uranium incorporation into apatite; 3) the degree of iodine incorporation into apatite. The importance of this work is assessing the role of apatite in immobilizing these elements, where uranium is a major component of spent nuclear fuel and iodine is a chemical analog of its radioactive isotope (¹²⁹I). Once we understand the incorporation mechanisms, we will provide data that …

Stratigraphy, Sedimentology, And Deformational Significance Of Cambrian And Early Ordovician Strata Along The Southeast Wisconsin Arch, Allison Raeann Kusick

Theses and Dissertations

A detailed study of the stratigraphic units in and around the Wisconsin Arch of central and southeast Wisconsin are presented to refine the sedimentologic record and the geologic implications within the Cambrian and early Ordovician strata. The Cambrian and early Ordovician sediments in central and southeast Wisconsin unconformably overlie a topographic high composed of Precambrian basement rocks, called the Wisconsin Arch, and consist of various clastic deposits, dolostones, and several horizons of deformation. Bedrock cores, made available through the Wisconsin Geological and Natural History Survey (WGNHS), were analyzed, to understand sedimentation in the Cambrian and early Ordovician. My analyses focused …

An Assessment Of The Performance Of The Earthscope Automated Receiver Survey: A User’S Guide To Ears., Erin L. Taxon

Theses and Dissertations

An Assessment of the Performance of the EarthScope Automatic Receiver Survey: A User's Guide to EARS.

With the advent of digital seismic recording, the ability to process and interpret large quantities of seismic data has become increasingly vital. EarthScope Automated Receiver Survey, EARS, was launched in 2005 to estimate bulk crustal properties in real time, at all broadband seismograph stations, globally. EARS utilizes the receiver function HK stacking method to estimate a station’s crustal thickness (H) and ratio of P wave velocity (Vp) and S wave velocity (Vs), known as Vp/Vs (K). Receiver function analysis observes the arrival times …

Differentiating Pleistocene Alloformations In The South Carolina Coastal Plain Through Lithologic, Textural, Mineralogical, And Cluster Analyses, Charles Andrew Wykel

Theses and Dissertations

Currently, there is no textural or mineralogic basis for identifying and differentiating Pleistocene strand deposits in the South Carolina (SC) Lower Coastal Plain (LCP). Historically, geologic mapping of the SC coastal plain uses geomorphologic and biostratigraphic techniques for identifying and mapping LCP surficial strand deposits. While useful, both approaches have problems. The aim of this study is to develop a cost-effective approach to differentiate and identify strand deposits of different Pleistocene alloformations occurring in the SC LCP. To accomplish this task, four strand samples were taken from the Ten Mile Hill, the Ladson, and Wicomico alloformations in Horry County, SC. …

Characterization Of Quaternary Stratigraphy In The Mississippi Sound To Evaluate The Influence Of Geologic Heterogeneity On Submarine Groundwater Transport And Discharge, Zachary Peoples

Theses and Dissertations

Submarine Groundwater Discharge (SGD) through seafloor sediments is gaining recognition as an important component of coastal water quality. Stratigraphic features creating geologic heterogeneity, such as incised paleochannels, may influence preferential pathways for SGD. The central Mississippi Sound is underlain by paleochannels that were incised into Pleistocene sediments while the area was subaerially exposed during the last glacial maximum and are now buried by transgressive Holocene deposits. In this thesis, newly collected chirp, previously published seismic reflection, and sediment core data are used to characterize the three-dimensional structure of the Holocene-Pleistocene contact. Results indicate that Pleistocene paleochannels cross-cut the study area, …

Terrestrial Perspective On The Formation, Evolution, And Detection Of Zeolites In Lacustrine Environments On Early Mars, Gayantha Roshana Loku Kodikara

Theses and Dissertations

This study evaluates the possible formation and evolution mechanisms of zeolites on early Mars with possible explanations for their limited detections using Earth analogs. This study focuses on the formation of zeolites in the closed basin lakes where the largest relatively pure concentrations of natural zeolites are found on Earth. Five working hypotheses were formulated to explore the limited detection of zeolites in closed basin lakes on Mars and different styles of scientific reasoning with suitable examples were used to test the independent, converging lines of inquiry. Zeolites may not be identifiable in certain locations on Mars using orbital data …

Alkalinity Enhanced Mass Reduction Of Uranium Contaminated Sediment, Cullen Edward Meurer

Theses and Dissertations

Uranium is a toxic and radioactive metal that is naturally occurring in the Earth’s crust. The uranium mining boom of the 1950’s produced many contaminated aquifers throughout the United States. Monitoring of groundwater data suggests that uranium concentrations may take 100’s of years to naturally attenuate to below the maximum contamination limit. This project examines a potential and novel remediation technique of groundwater contaminated with uranium through alkalinity enhanced desorption from the solid phase. Alkalinity enhances the desorption of uranium by complexing uranyl (UO22+) with Ca and CO3 which allows for further desorption. Since remediation is time consuming and expensive, …

Baseflow Variability Due To Changes In Climate, Basin Characteristics, And Groundwater Withdrawals In The State Of Wisconsin, Usa, Susan Borchardt

Theses and Dissertations

ABSTRACT

BASEFLOW VARIABILITY DUE TO CHANGES IN CLIMATE,BASIN CHARACTERISTICS, AND GROUNDWATER WITHDRAWALS IN THE STATE OF WISCONSIN, USA

bySusan Borchardt The University of Wisconsin-Milwaukee, 2022 Under the Supervision of Professor Woonsup Choi

In Wisconsin, the number of high-capacity wells has increased substantially, and concerns have been raised about their impact on both groundwater levels and streamflow. At the same time Wisconsin’s climate has been changing, and both the annual precipitation (5%) and temperature (1.5oC) have been trending upward over the last 68 years and both are predicted to increase into the future. This study attempted to demonstrate the simultaneous effects …

Quantifying The Controls Of Shear-Coupled P-Waves, Jackson Saftner

Theses and Dissertations

Shear-coupled P-waves have been shown to possess great utility in resolving crustal and upper mantle models, however these phases remain largely untapped due to their ephemeral nature. Shear-coupled P-waves are a type of seismic phase that undergo S-to-P conversion either at the free-surface or at the base of the crust. Under the proper conditions, it is possible for the converted crustal P phases to achieve total internal reflection, allowing these phases to remain large in amplitude and sample long segments of the crust. In this study, we use a combination of real-world observations collected from literature, and synthetic seismograms, to …

Identifying Biogeochemical Factors Responsible For The Cyclical Precipitation Of Sphalerite And Galena In Low Temperature Mississippi Valley Type Ore Deposits, Daniel John Makowsky

Theses and Dissertations

Mississippi Valley Type (MVT) lead and zinc deposits provide a significant source of sedimentary galena and sphalerite. However, geochemical characteristics and genesis including the source and production of hydrogen sulfide required for galena and sphalerite ore formation and the reasoning for quick, episodic mineralization is not fully understood. By simulating regional MVT brines, the input and effect of biological by-products during the development of these ores as well as the cause of cyclicity within MVT deposits have been observed. Experiments using compositions from MVT fluid inclusions were conducted over two-week periods. Variables during the experiments included temperature, CO2, hydrogen sulfide …

Chemical And Physical Weathering Rates Of Basaltic Volcanic Regions: Utilizing Space In Place Of Time In The Hawaiian Archipelago, Benjamin Clyde Barton

Theses and Dissertations

With large populations living in tropical regions of the world with volcanic substrates, understanding basalt weathering processes is vital. The Hawaiian Islands are an excellent natural analogue to study chemical weathering rates due to a uniform bedrock (basalt), large variations in rainfall, and varying ages across the islands. Laterite weathering profiles (LWP) develop over time through chemical weathering, where LWP thickness is influenced by many factors, including precipitation and time. Using the rapid, non-invasive horizontal-to-vertical spectral ratio (HVSR) method, LWP thicknesses can be estimated to constrain chemical weathering rates. Studying the laterite weathering profiles developed from basaltic bedrock of varying …

Analyzing Weathering Patterns In Modern And Paleolake Deposits Of Tecopa, California: Implications For The Detection Of Paleolakes On Mars, Jason Benjamin Carman

Theses and Dissertations

This study focuses on two stratigraphic sections from the Tecopa paleolake and samples from the modern Tecopa and Amargosa River basins as a terrestrial analogue to Martian paleolakes. Previous work shows that the later stages of Pleistocene Lake Tecopa were highly alkaline and saline due to evaporation, which led to the formation of authigenic lacustrine minerals such as zeolites, clays, and precipitates that are potentially similar to Martian paleolakes. Paleolakes can provide information on past aqueous processes, such as the changes in the hydrologic cycle that a particular area experienced over the lifespan of a lake on Earth or Mars. …

A South Polar View Of Late Paleozoic Glaciation: Physical Sedimentology And Provenance Of Glacial Successions In The Tasmanian And Transantarctic Basins, Elizabeth Rosa Woodford Ives

Theses and Dissertations

The Late Paleozoic Ice Age (LPIA; ~ 374 – 256 Ma) is the longest Phanerozoic icehouse interval. this interval in Earth’s history was largely defined by extensive glaciation of the southern hemisphere at both polar and temperate latitudes. Glaciers are powerful climatic and geologic actors, especially during icehouse periods, and widespread glaciation can have a significant influence on both regional and global climate and geology. Therefore, constraining the characteristics of LPIA glaciers is essential to developing a global-scale understanding of this key climatic event in Earth’s history. The manuscripts in this dissertation examine the sedimentology, transport directions, stratigraphy, and detrital …

Carbon Storage Via Mineral Bonding In Subsoils A Review Of Soil Processes, Kiele Goins

Theses and Dissertations

Soil is an important but often poorly understood portion of the carbon cycle. Soil can store more carbon than twice today’s atmosphere, but the factors that control carbon storage are often unclear. Carbon enters the soil through input of organic matter, erosion, and aerosol deposition and is lost mostly via microbial decomposition. Carbon loss in soil is impacted by the chemical composition of organic compounds, environmental factors, and human activities. Furthermore, as climate changes soil, carbon storage may be vulnerable. Although carbon can be stored throughout soil, carbon storage varies with depth. In topsoil, carbon is stored for short periods …

Groundwater Flow And Transport At The Forest-Marsh Boundary: A Modeling Study, Sophia Chason Sanders

Theses and Dissertations

The forest-marsh boundary, where tidally influenced salt marshes meet a forested upland, is hydrologically complex due to its multiple water inputs. Groundwater flow and salinity transport at this boundary are not well understood. In order to make predictions about salinity at this boundary as it responds to climatic factors, a two-dimensional model was built to simulate groundwater flow and solute transport at a salt marsh on Sapelo Island, Georgia. After calibration based on observed data from wells at the study site, the model can be used to identify patterns in groundwater movement and solute transport that may influence the vegetation …

Groundwater Discharge From Passive Continental Margins: Rethinking Marine Chemical Budgets, Andrew William Osborne

Theses and Dissertations

Geothermal convection and sediment compaction drive large-scale flow in continental shelves. We suggest that this flow is an overlooked control on the major ion chemistry of the ocean. Conventional ocean chemical budgets are constructed using river discharge, axial mid-ocean ridge (MOR) convection and CaCO3 production, but these budgets are still poorly quantified. We synthesized data from 17 passive continental margin basins to calculate a range of estimated groundwater and chemical fluxes from continental shelves, considering five major ions (Ca2+, Na+, K+, Mg2+, and Cl-). When extrapolated globally, volumetric groundwater flux estimates were comparable to those for MOR axial circulation, and …

Fluid Flow And Deformation: Exploring The Relationships Between Fluid Flow, Deformation Mechanisms, Quartz Crystallographic Preferred Orientation Fabric Development, And Kinematics In The Willard Thrust Fault, Utah, Falyn Strey

Theses and Dissertations

Thirty-four quartz-rich samples were collected across the Willard thrust fault in Utah to explore the effects that fluid has on faulting. In particular, the relationships between fluid, deformation mechanisms, crystallographic preferred orientation (CPO) fabric development, and kinematic vorticity were investigated. A petrographic analysis of all 34 samples determined the relative contributions of brittle fracturing, crystal plasticity, and diffusional processes along with their possible relation to fluid interaction. Crystal plasticity dominates throughout most of the field area except where significant contributions from diffusive deformation occurs in rocks with significant mica concentrations and fine grain sizes, especially those located near the fault. …