Physical Sciences and Mathematics Commons^™

Continental Saline Environments Interpreted From Bedded Gypsum Of The Triassic Red Peak Formation (Chugwater Group), Northcentral Wyoming, Maya Yamei Bradford

Graduate Theses, Dissertations, and Problem Reports

Bedded evaporites and associated red bed siliciclastics record saline lake and groundwater systems from Permo-Triassic Pangea. A major component of these red bed and evaporite systems is bedded gypsum. However, little attention has been paid to the textures of ancient gypsum. Observations of gypsum textures can refine interpretations of depositional environment and diagenetic history. This project describes textures of bedded gypsum from an outcrop of the Triassic Red Peak Formation (Chugwater Group) near Greybull, Wyoming.

This thesis uses fieldwork, petrography, and x-ray diffraction to describe an outcrop of the upper Red Peak Formation, with a focus on textures of bedded …

Natural Fracture Evolution: Investigations Into The Middle Devonian Marcellus Shale, Appalachian Basin, Usa, Natalie Abigail Mitchell

Graduate Theses, Dissertations, and Problem Reports

Optimizing recovery from unconventional shale reservoirs has generated considerable research into optimal recovery methods through hydraulic fracturing design and shale reservoir characterization in the development of long-term hydrocarbon producers. Permeability at multiple scales from nanometer-scale pore sizes and nano-darcy permeability to completion-induced fractures defining a 100’s of meter stimulated reservoir volume plays a significant role in hydrocarbon flow during production in shale reservoirs. Preexisting cemented fractures in unconventional shale reservoirs are abundant and preferentially reactivate during induced hydraulic fracturing treatment to create necessary large-scale permeability. While previous investigations have significantly improved our knowledge of shale reservoirs, it has also highlighted …

Bedrock Channel Geometry: Meter To Micron Scale Controls On Fluvial Incision, Nicholas J. Colaianne

Graduate Theses, Dissertations, and Problem Reports

The relative resistance of various rock types to incisional processes vary widely and the properties governing bedrock erodibility are poorly understood. Lithologic properties influencing erodibility are the culmination of a rock’s depositional, diagenetic, and exhumation processes. Difficulty identifying a convenient physical proxy for erodibility suggests examining evidence of these processes holistically may offer insight into the role of each in setting a rock’s resistance to incisional forces. In this study we use measured channel geometries along a short stretch of the Dry Fork, WV hosting three distinct lithologic settings to infer relative erodibility against measured and observed fluvial, lithologic, and …

A Study Of Accidental Daughter Crystals In Fluid Inclusions In Bedded Halite From The Permian Opeche Shale And Cedar Hills Sandstone Of The Midcontinental United States, Ryan James Prchlik

Graduate Theses, Dissertations, and Problem Reports

Ancient acid-saline lakes of the midcontinental United States deposited bedded halite during Permian time. These deposits are not typically preserved at the surface, but drill cores of the Opeche Shale of North Dakota and Cedar Hills Sandstone of Kansas contain preserved beds of halite. Halite from these ancient lakes have primary fluid inclusions that contain Permian lake water. Also included are accidental daughter crystals that were trapped inside the fluid inclusions at time of halite precipitation. Both the fluid and daughter crystals inside bedded halite can tell us about the geochemistry of original lake waters of Pangea.

Petrography and laser …

Use Of Carbonation For Treatment Of Coal Mine Drainage To Increase Limestone Dissolution And Generate Alkalinity, Dietrich Henry Kuhlmann Iv

Graduate Theses, Dissertations, and Problem Reports

Abstract

Use of Carbonation for Treatment of Coal Mine Drainage to Increase Limestone Dissolution and Generate Alkalinity

Dietrich Kuhlmann IV

Anoxic limestone drains (ALDs) are a common component used within passive treatment systems for coal mine drainage (CMD). Contact between limestone aggregate and CMD results in limestone dissolution, producing carbonate alkalinity. Though ALDs are one of the least expensive CMD treatment technologies, alkalinity generation is limited by limestone solubility. This necessitates a long retention time (>12 hours) and sometimes results in net acidic effluent which requires additional alkalinity generation steps downstream. One way to increase calcite dissolution and alkalinity …

Regional Correlation And Depositional History Using Well Log And Core Data Of The Geneseo-Burket From The Poseidon 8m Well, Westmoreland County Pa, Usa, Spencer Leonard Williams Jr.

Graduate Theses, Dissertations, and Problem Reports

Abstract

Regional Correlation and Depositional History using Well Log and Core Data of the Geneseo-Burket from the Poseidon 8M Well, Westmoreland County PA, USA

Spencer Williams

Natural gas producers have invested billions of dollars in Pennsylvania and West Virginia to establish significant gas production from the Devonian Marcellus Shale and the deeper Ordovician Utica-Point Pleasant interval. In addition, commercial gas production has been reported from several other Devonian shale units in the Appalachian region, including the Rhinestreet, Levanna, and Geneseo-Burket. The Marcellus Shale is the largest natural gas play in the United States. The Marcellus is located directly under the …

Understanding Surface Water--Groundwater Connectivity And Discharge In Arctic Deltas, Lindsey N. Aman

Graduate Theses, Dissertations, and Problem Reports

Increased warming is driving unprecedented hydrologic changes within arctic deltas with implications for water storage, solute processing, and terrestrial and marine ecology. Thermokarst lakes within Arctic deltas store flood waters and filter solutes and sediments, thus moderating the impact of flood water discharge to arctic seas. However, this moderating influence is diminishing as lakes shrink on annual and seasonal time scales, especially close to active channels where lakes are shrinking most rapidly. This study investigates surface water-groundwater connectivity in arctic delta plains with coupled flow and heat transport models to provide a mechanistic understanding of how lake-channel proximity will impact …

Application Of Artificial Intelligence For Co2 Storage In Saline Aquifer (Smart Proxy For Snap-Shot In Time), Marwan Mohammed Alnuaimi

Graduate Theses, Dissertations, and Problem Reports

In recent years, artificial intelligence (AI) and machine learning (ML) technology have grown in popularity. Smart Proxy Models (SPM) are AI/ML based data-driven models which have proven to be quite crucial in petroleum engineering domain with abundant data, or operations in which large surface/ subsurface volume of data is generated. Climate change mitigation is one application of such technology to simulate and monitor CO2 injection into underground formations.

The goal of the SPM developed in this study is to replicate the results (in terms of pressure and saturation outputs) of the numerical reservoir simulation model (CMG) for CO2 injection into …

The Potential Of Diabase Sills In Eastern Pennsylvania To Store Co2 And H2, Rhiannon R. Schmitt

Graduate Theses, Dissertations, and Problem Reports

With anthropogenic CO₂ concentrations rising, geologic carbon sequestration and H₂ storage are essential processes in mitigating climate change. Typical geologic carbon sequestration involves the capture of anthropogenic CO₂ and injection into depleted oil/gas reservoirs or saline formations with an impermeable cap rock to prevent the buoyant migration of CO₂. The risk of eventual CO₂ migration through these low permeability cap rocks adds expensive monitoring costs to this traditional sequestration strategy. Another method for CO₂ sequestration utilizes the reaction of CO₂ with mafic and ultramafic rocks. CarbFix, a sequestration project in Iceland, has …

Chemical Characterization Of Clastic Cave Sediments And Insights Into Particle Transport And Storage In Karst Aquifers, Jill L. Riddell

Graduate Theses, Dissertations, and Problem Reports

Abstract

Chemical characterization of clastic cave sediments and insights into particle transport and storage in karst aquifers

Jill L. Riddell

Cave sediments can be divided into two groups: precipitates and clastics. Precipitates are speleothems, or lithologic or mineral features that are chemically precipitated in the cave environment. Clastic cave sediments are frequently described by depositional facies, sorting, and particle size (Bosch and White, 2004). Robust analytical chemical analyses of these sediments to quantify their physical and chemical components is rarely performed although some chemical characterization of mineralogy and paleomagnetism has become prevalent in recent years (Chess et al., 2010; Sasowsky …

Variations In Produced Water Chemistry And Relation To Regional Geology And Production In The Marcellus Shale, Northcentral West Virginia, Jonathan M. Brady

Graduate Theses, Dissertations, and Problem Reports

An investigation of 74 Marcellus Shale wells across northcentral West Virginia indicates changes in produced water chemistry and quantity can be related to geologic conditions based on well logs and core data. These changes are determined by reviewing multiple produced water analyses for individual wells for periods up to ten years. Results show variations among the areas in this study. From west to east across central Harrison County to central Taylor County, then north into Monongalia County, gamma-ray logs show increasing intensity, especially in the middle and lower Marcellus. XRD mineralogy from core data shows increasing clay content from west …

Independent, Semi-Automated Classification Of Petrographic Features In Volcanic Rocks Using Fiji And Weka, Holly Danielle Pettus

Graduate Theses, Dissertations, and Problem Reports

Traditional methods of collecting quantitative petrographic data from thin sections (modal mineralogy, size distribution, shapes, etc.) are time- and labor-intensive, and rarely have sample sizes adequate to statistically describe complex rocks (i.e. volcanic rocks). Although manual counting and measurements are now routinely supplemented by digital image analysis, the majority of quantitative petrographic studies still go through a manual digitization stage where object classes are traced before further analyses. This is a major rate-limiting step that reproduces the same problems of small n-values resulting from significant effort. We have valuated the potential and limitations of using the Trainable Weka Segmentation (TWS) …

Reservoir Characteristics And Lateral Variability Of The Marcellus Formation At The Allegheny Mountain Front, Bruno J. Abersold

Graduate Theses, Dissertations, and Problem Reports

The Marcellus Formation, a large shale gas reservoir located within in the Appalachian basin, produces the energy that fuels the economy across the United States. Well data and rock core for the Coastal 1H well, found in Fayette County, Pennsylvania, provides the basis to understand reservoir characteristics and depositional processes of the Marcellus Formation across the basin. The well is located near along the eastern edge of the productive fairway and adjacent to the Allegheny mountain front. We used characteristics, such as total organic carbon (TOC), geomechanical properties, and lithology, to integrate with ten other available wells across the basin. …

Application Of 3d Seismic Signal And Geomechanical Attributes For Subsurface Fracture Characterization: A Case Study In Clearfield County, Central Pennsylvania, Iman F. Zulkapeli

Graduate Theses, Dissertations, and Problem Reports

Hydrocarbon exploration in unconventional reservoirs is highly risky due to the nature of the reservoirs and the variability in fractures and reservoir geomechanical properties in the subsurface. The reservoir needs to be fully characterized to avoid any complication such as frac hit, wellbore failure, blowout, or even a dry hole. The Clearfield reservoir produces an exceptionally low amount of gas, compared to the neighboring region in the proximity, which has been poorly understood. This raises the question as to what causes the reservoir to have low productivity.

This study focuses on the natural fracture characterization using high-quality 3D seismic signal …

Refining The Sedimentology And Geochemistry Of The Mid-Permian Blaine Formation Of The Rebecca K. Bounds Core From Greeley County, Kansas, Brigitte Petras

Graduate Theses, Dissertations, and Problem Reports

Red siliciclastics and evaporites of Permian Nippewalla Group in mid-continental US were deposited in western equatorial Pangea. Previous studies of these rocks record Permian air temperatures as high as 73 °C, saline lake waters with a pH as low as ~1, and sedimentology that shows arid conditions. This current study conducts detailed sedimentological observations and geochemical analyses of the Blaine Formation of the Nippewalla Group. The Rebecca K. Bounds core from west-central Kansas is used to interpret the depositional environments and diagenetic history of the Blaine Formation.

The lithologies of the Blaine Formation, listed in order of most to least …

Effect Of Oxidative Breakers On Organic Matter Degradation, Contaminant Mobility And Critical Mineral Release During Shale-Fracturing Fluid Interactions In The Marcellus Shale, Shaun Donmoyer

Graduate Theses, Dissertations, and Problem Reports

Production of oil and gas from organic-rich shale formations has become viable through advancements in multi-stage hydraulic fracturing. The decline of shale gas production after the initial days of fracturing operations coupled with falling oil and gas prices, has pushed industry operators to use new chemical additives as an attempt to increase hydrocarbon production. The implementation of highly reactive fracturing fluids that include strong oxidizing agents, pose as a potential solution to increase well productivity. Strong oxidizing chemicals commonly known in fracturing operations as breakers, are used to improve the viscosity of gel-based fluids after the proppant is transported into …

Regional Correlation And Depositional History Using Well Log And Core Data Of The Middle Devonian Marcellus Poseidon 8m Well, Westmoreland County, Pennsylvania, Usa, Emily R. Jackson

Graduate Theses, Dissertations, and Problem Reports

The Marcellus Shale is the largest natural gas producing formation in the Appalachian basin, and as such, presents a unique opportunity for continued research on an area that is critical to meeting the energy needs of the current society. Although the Marcellus has historically been extensively researched, acquisition of well log and core data from the Marcellus Poseidon 8M well in Westmoreland County, PA, allows for application of a new method of data integration, which was utilized in this project to specifically understand the depositional environment and create a correlation with other study wells throughout the basin. This integration was …

Petrographic And Core Analysis Of The Jurassic Norphlet Formation: A Case Study In The Lithofacies Control Of Diagenesis And Porosity In The Flomaton Field, Al, Jarrett Thomas Smith

Graduate Theses, Dissertations, and Problem Reports

This study includes a sedimentologic and petrographic study of cores and thin-sections from the Jurassic Norphlet Formation in the Flomaton Field in southern Alabama to define a specific paragenetic history of each facies encountered and to identify key controls on reservoir quality. Eolian dune, nearshore, sand flat, and wadi facies were likely encountered in Norphlet core and thin-section samples that displayed a high degree of heterogeneity between them in terms of porosity, grain contacts, cement abundance/type, intergranular volume, and overall diagenetic processes. These distinct petrographic differences suggest that the paragenesis in the Flomaton Field is primarily facies controlled. The eolian …

A Snapshot Of Ancient Microbial Life: Microorganisms And Organic Compounds In Primary Fluid Inclusions In Bedded Halite, Neoproterozoic Browne Formation Of Central Australia, Sara I. Schreder-Gomes

Graduate Theses, Dissertations, and Problem Reports

Modern shallow brine environments contain an abundance of microorganisms. Microorganisms, mineral crystals, and air bubbles can be trapped with those brines in primary fluid inclusions in bedded halite as it grows in shallow saline surface waters. Primary fluid inclusions and their contents can be preserved, unaltered, for millions of years.

The ~830 million-year-old Browne Formation of central Australia contains intervals of bedded halite with unaltered primary fluid inclusions. Intervals of bedded halite were sampled in the Empress 1A core from ~1480 m – 1520 m depths. Here, I used petrography to describe suspect microorganisms and organic compounds that were trapped …

Reservoir Characterization And Static Earth Modeling For Potential Co2 Storage In Upper Pennsylvanian Cyclothems Of Midcontinent, Usa, Valerie Lynn Smith

Graduate Theses, Dissertations, and Problem Reports

This dissertation details the estimation of CO₂ storage volume using reservoir characterization and the building of static earth models in two papers: 1) for Sleepy Hollow Field in Red Willow County, Nebraska and, 2) for Huffstutter Field, Phillips County, Kansas. These models are used to obtain estimates of CO₂ storage capacity in stacked carbonate intervals of the Pennsylvanian Lansing and Kansas City groups (LKC). The LKC constitutes a regional succession of interbedded carbonates and shales. Located over the Cambridge Arch of Nebraska, these interbedded units were evaluated for carbon storage potential. Understanding the occurrence of carbonate porosity among …

Process Based Analysis Of Fluvial Stratigraphic Record: Middle Pennsylvanian Allegheny Formation, North-Central Wv, Oluwasegun O. Abatan

Graduate Theses, Dissertations, and Problem Reports

Fluvial deposits represent some of the best hydrocarbon reservoirs, but the quality of fluvial reservoirs varies depending on the reservoir architecture, which is controlled by allogenic and autogenic processes. Allogenic controls, including paleoclimate, tectonics, and glacio-eustasy, have long been debated as dominant controls in the deposition of fluvial strata. However, recent research has questioned the validity of this cyclicity and may indicate major influence from autogenic controls. To further investigate allogenic controls on stratal order, I analyzed the facies architecture, geomorphology, paleohydrology, and the stratigraphic framework of the Middle Pennsylvanian Allegheny Formation (MPAF), a fluvial depositional system in the Appalachian …

Physical And Chemical Properties Of Clastic Sediments From Two Caves In The Northern Karst Region Of Puerto Rico, Autum R. Downey

Graduate Theses, Dissertations, and Problem Reports

Geochemical properties and organic characteristics are essential to understanding the general depositional dynamics of a cave. Most work on clastic cave sediments focuses on physical properties of sediments. Little work has been done on bulk organic matter and geochemical properties.

This project reports physical and geochemical characterization of cave sediments from two caves in the northern karst region of Puerto Rico: El Tallonal Cave and Cueva Clara. Core and grab samples were collected and analyzed for particle size, total organic carbon, total nitrogen, organic matter characteristics using fluorescence spectroscopy, and major and minor elements using X-ray fluorescence (XRF). The sediments …

Relating Sonic Velocities, Minimum Horizontal Stress, And Natural Fracture Distribution To Stimulation Efficiency During Completion Of The Marcellus Shale Mip-3h Unconventional Well, West Virginia, Usa, Kaitlin Gayle Evans

Graduate Theses, Dissertations, and Problem Reports

Log data from the Marcellus Shale Energy and Environment Laboratory (MSEEL) was acquired along the lateral of the MIP-3H well. This unconventional shale-gas well was completed within the Marcellus Shale just above the Cherry Valley Limestone, a thin limestone member separating organic rich units of the Marcellus. The geomechanical moduli, Poisson’s Ratio (PR) and Young’s Modulus (YME), were generated using compressional and shear sonic logs to indicate zones of increasing brittleness for each of the 28 stages along the 6124 ft. (1867m) horizontal lateral. Brittle reservoir rock is more readily fractured during hydraulic stimulation than more malleable rock. Stages with …

Mapping Surficial Geology In The New River Gorge National River And Bluestone National Scenic River, West Virginia, Using Lidar-Derived Digital Elevation Data, Marla K. Denicola

Graduate Theses, Dissertations, and Problem Reports

The purpose of this thesis was to determine if the surficial geology of Bluestone National Scenic River (BLUE) and New River Gorge National River (NERI), two areas of similar geology, can be mapped using visual interpretation methods applied to digital elevation models (DEMs) derived from light detection and ranging (LiDAR) data. Surficial geology in BLUE was field mapped using GPS, following definitions and characterizations for surficial geology units established with the guidance of Dr. J. Steven Kite. A 2m x 2m LiDAR-derived DEM was used for BLUE and most of NERI using US Army Corps of Engineers (USCOE) LiDAR data, …

Paleoecological Successions From Shallow-Marine Depositional Environments In Upper Silurian Carbonate Rocks Of Blair County, Pennsylvania, Shadya El-Ashkar

Graduate Theses, Dissertations, and Problem Reports

Studies of paleoenvironment and paleoecology are important for investigating relationships between the different environmental and biological variables that influenced biodiversification patterns during the Silurian Period. The mixed carbonate and siliciclastic rocks of the Bloomsburg and Mifflintown Formations in central Pennsylvania represent transitions between carbonate ramp and deltaic settings. The goal of this study was to assess changes in depositional environment and paleoecology of an undescribed Bloomsburg/Mifflintown locality in Bellwood, Pennsylvania. In central Pennsylvania, the interfingered relationship of mixed carbonate and siliciclastic mudstones of the Mifflintown Formation with red fine-grained sandstones and shales of the Bloomsburg Formation presented challenges for deciphering …

Alluvial Fans, Loess Plains, Lakes, And Distributive Fluvial Systems: Depositional Systems Of The Permian-Triassic Red Beds And Evaporites Of Wyoming (Usa), Jonathan Knapp

Graduate Theses, Dissertations, and Problem Reports

The end-Permian ecological crisis was a period of warming and aridity reaching extreme levels by the end Permian and not recovering before the Middle Triassic. The Permian Goose Egg Formation and the Chugwater Group’s Early Triassic Red Peak Formation and Middle Triassic Alcova Limestone are a continuous or nearly continuous succession of rocks deposited during this warm, arid time in Wyoming. Comprised of red beds, evaporites, and rare carbonates, these rocks have not been subjected to detailed sedimentological investigations in the modern era. Previous interpretations of marine and marginal marine deposition have largely been based on the laterally extensive nature …

A Machine Learning And Data-Driven Prediction And Inversion Of Reservoir Brittleness From Geophysical Logs And Seismic Signals: A Case Study In Southwest Pennsylvania, Central Appalachian Basin, Tobi Micheal Ore

Graduate Theses, Dissertations, and Problem Reports

In unconventional reservoir sweet-spot identification, brittleness is an important parameter that is used as an easiness measure of production from low permeability reservoirs. In shaly reservoirs, production is realized from hydraulic fracturing, which depends on how brittle the rock is–as it opens natural fractures and also creates new fractures. A measure of brittleness, brittleness index, is obtained through elastic properties of the rock. In practice, problems arise using this method to predict brittleness because of the limited availability of elastic logs.

To address this issue, machine learning techniques are adopted to predict brittleness at well locations from readily available geophysical …

Evolution Of Extreme Continental Saline Environments: A Sedimentological Investigation Of Permo-Triassic Redbeds And Evaporites In Northern Ireland And Kansas, Anna Sofia S. Andeskie

Graduate Theses, Dissertations, and Problem Reports

The Permo-Triassic was a time of extreme environments, unusually warm and arid climates, and biotic crises. This study investigates Pangean environments and climate leading to extreme acid saline lake systems represented by the Permian Nippewalla Group of Kansas and the Triassic Mercia Mudstone Group of Northern Ireland. Sedimentological observations of the underlying rocks, the Permian Hutchinson Salt Member of Kansas and the Permian Belfast Harbour Evaporite Formation of Northern Ireland, help to understand trends in environmental and climatic conditions leading to these extreme environments. This dissertation also refines the geographic extent of extreme acid saline lake and groundwater systems through …

Structural Style And Stratigraphic Architecture Of The Northeastern Brooks Range, Alaska, Benjamin G. Johnson

Graduate Theses, Dissertations, and Problem Reports

The Arctic Alaska–Chukotka microplate is a large Mesozoic–Cenozoic composite terrane that resides at the northern limit of the North American Cordillera. Although its Mesozoic origins are assuredly linked to the opening of the Amerasian Basin of the Arctic Ocean, its Paleozoic origins can be linked to at least three separate paleocontinents, including northern Laurentia, Baltica, and Siberia. Across the Arctic Alaska portion of the microplate, an internal, mid-Paleozoic suture zone presumably separates rocks of the North Slope subterrane (Laurentian affinity) from a collection of smaller subterranes in the southern Brooks Range and Seward Peninsula (Baltic affinity).

The mountains of the …

Beneath The Gypsum Dunes: Cenozoic History Of Wind And Water From A Core Drilled At White Sands, New Mexico, Jackson Bentley Jakeway

Graduate Theses, Dissertations, and Problem Reports

White Sands, New Mexico is the largest gypsum dune field on planet Earth, the result of reworking of gypsum deposits. The dunes have been well studied, but the Cenozoic history preceding the formation of the dune field has been poorly studied. A core drilled to a depth of 192 ft (58.5 m) beneath the modern dune field contains deposits from saline lakes, sandflats, perennial freshwater lakes, perennial brackish to saline lakes, and saline mudflats.

The core is composed of bottom-growth bedded gypsum, gypsum sandstone and siltstone, mixed siliciclastic-gypsum sandstones and siltstones, laminated siliciclastic mudstones, gypsum mudstones, and carbonate mudstones. Bottom-growth …