Physical Sciences and Mathematics Commons^™

Boron In Antarctic Granulite-Facies Rocks: Under What Conditions Is Boron Retained In The Middle Crust?, Edward S. Grew

University of Maine Office of Research Administration: Grant Reports

This award, provided by the Antarctic Geology and Geophysics Program of the Office of Polar Programs, supports a project to investigate the role and fate of Boron in high-grade metamorphic rocks of the Larsemann Hills region of Antarctica. Trace elements provide valuable information on the changes sedimentary rocks undergo as temperature and pressure increase during burial. One such element, boron, is particularly sensitive to increasing temperature because of its affinity for aqueous fluids, which are lost as rocks are buried. Boron contents of unmetamorphosed pelitic sediments range from 20 to over 200 parts per million, but rarely exceed 5 parts …

Mri: Acquisition Of A High Performance Cluster For The University Of Maine Scientific Grid Portal, Phillip M. Dickens, Yifeng Zhu, Bruce E. Segee, James L. Fastook, Sudarshan S. Chawathe

University of Maine Office of Research Administration: Grant Reports

This project, acquiring a cluster to establish a scientific grid portal in Maine, aims to enable projects requiring large datasets. The work makes available to the wider community results such as widely-used whole-ice sheet models, tools for climate change research, prototype versions of object-based caching system (bundled with MPI-IO implementation developed at Argonne National Lab), the data management system, real-time animations, videos, etc. Additionally, the portal provides the larger community the compute power, storage capacity, and rendering engine to execute very high-resolution models, and receive animations and other visualized information in real time.

Broader Impact: The infrastructure enhances understanding of …

The Crystal Chemistry Of Holtite, L. A. Groat, Edward S. Grew, R. J. Evans, A. Pieczka, T. S. Ercit

Earth Science Faculty Scholarship

Holtite, approximately (Al,Ta,square)Al(6)(BO(3))(Si,Sb(3+),As(3+))(Sigma 3)O(12)(O,OH,square)(Sigma 3), is a member of the dumortierite group that has been found in pegmatite, or alluvial deposits derived from pegmatite, at three localities: Greenbushes, Western Australia; Voron'i Tundry, Kola Peninsula, Russia; and Szklary, Lower Silesia, Poland. Holtite can contain >30 wt.% Sb(2)O(3), As(2)O(3), Ta(2)O(5), Nb(2)O(5), and TiO(2) (taken together), but none of these constituents is dominant at a crystallographic site, which raises the question whether this mineral is distinct from dumortierite. The crystal structures of four samples from the three localities have been refined to R(1) = 0.02-0.05. The results show dominantly: Al, Ta, and vacancies …

Antarctic Climate Change And The Environment, Peter Convey, R. Bindschadler, G. Di Prisco, E. Fahrbach, J. Gutt, D. A. Hodgson, Paul Andrew Mayewski, C. P. Summerhayes, J. Turner, Acce Consortium

Earth Science Faculty Scholarship

The Antarctic climate system varies on timescales from orbital, through millennial to sub-annual, and is closely coupled to other parts of the global climate system. We review these variations from the perspective of the geological and glaciological records and the recent historical period from which we have instrumental data (similar to the last 50 years). We consider their consequences for the biosphere, and show how the latest numerical models project changes into the future, taking into account human actions in the form of the release of greenhouse gases and chlorofluorocarbons into the atmosphere. In doing so, we provide an essential …

Sensors: A Novel Lateral Field Excited Acoustic Wave Sensor For Chemical And Biological Agents, John F. Vetelino, David Frankel, Carl Tripp, Paul J. Millard

University of Maine Office of Research Administration: Grant Reports

Sensors for the sensitive and selective detection of chemical agents and a biological agent are being developed. The sensor structure consists of a piezoelectric platform that is coated with a film that selectively sorbs a chemical or biological agent of interest. The sensitivity of the sensor is embodied in the sensor platform, which consists of a quartz crystal that is excited by a lateral electric field. The exciting electrodes are placed opposite to the sensing surface, and the sensing film is attached directly to the sensor platform. This arrangement is in contrast to the standard quartz microbalance (QCM), where the …

Mri: Acquisition Of Interactive Visualization Tools For Supercomputer Models, Bruce E. Segee, Huijie Xue, Kiran Bhaganagar, James Fastook, Peter O. Koons

University of Maine Office of Research Administration: Grant Reports

This project, acquiring a visualization facility (vizwall with high resolution display and high volume storage system to visualize large size data generated from diverse research activities), models polar ice sheets, oceans, atmospheric turbulent boundary layers, and geodynamics. The facility, whose main components consist of a visualization wall, a PRISM visualization server, and RAID storage disks, will be integrated to the university's existing supercomputer cluster.

Atmospheric Soluble Dust Records From A Tibetan Ice Core: Possible Climate Proxies And Teleconnection With The Pacific Decadal Oscillation, B. Grigholm, Paul Andrew Mayewski, Shichang Kang, Y. Zhang, S. Kaspari, Sharon B. Sneed, Q. Zhang

Earth Science Faculty Scholarship

In autumn 2005, a joint expedition between the University of Maine and the Institute of Tibetan Plateau Research recovered three ice cores from Guoqu Glacier (33 degrees 34'37.80 '' N, 91 degrees 10'35.3 '' E, 5720 m above sea level) on the northern side of Mt. Geladaindong, central Tibetan Plateau. Isotopes ( delta(18)O), major soluble ions (Na(+), K(+), Mg(2+), Ca(2+), Cl(-), NO(3)(-), SO(4)(2-)), and radionuclide (beta-activity) measurements from one of the cores revealed a 70-year record (1935-2005). Statistical analysis of major ion time series suggests that atmospheric soluble dust species dominate the chemical signature and that background dust levels conceal …

The Science Behind Climate Change: A Journey To Reedy Glacier, Brenda L. Hall, Molly Schauffler

University of Maine Office of Research Administration: Grant Reports

This Communicating Research to Public Audiences project focuses on the Reedy Glacier Antarctic research of Brenda Hall (OPP 0229034) and its relevance to the residents of and visitors to Maine. Collaborators include the University of Maine, the Maine Discovery Museum, the Acadia National Park and Cadillac Mountain Sports (an environmentally active retail company with several stores around the state). The primary deliverable is the development of an interactive software program that presents information and experiences in a two-tiered concept approach -- on the Reedy Glacier and its connection to Maine and on the process of science. The software is being …

Collaborative Research: The Response Of Lakes To Disturbance And Climate Change: Calibrating Sedimentary Records To Test The Landscape Position Concept, Jasmine E. Saros

University of Maine Office of Research Administration: Grant Reports

Landscape disturbance and climate change affect lakes in proportion to their contact with ground water, sometimes resulting in different responses in neighboring lakes. This project develops methods for reconstructing past water chemistry and food webs of lakes. The biological and chemical deposits in surface sediment samples will be compared with the water in 62 modern lakes. The resulting relationships will be tested by comparing sediment cores with 24 years of observations from the North Temperate Lakes Long Term Ecological Research (NTL-LTER) site. The methods will then be used to reconstruct 150 years of history for several lakes, adding perspective to …

Us Itase Glaciochemistry Phase 2: East Antarctica, Paul Mayewski

University of Maine Office of Research Administration: Grant Reports

This award supports a project to undertake glaciochemical investigations of the Ross Sea Embayment Drainage System, and portions of Wilkes Land for purposes of understanding annual to multi-centennial scale climate variability. The glaciochemical data that will be collected will contribute to the U.S. component of the International Trans-Antarctic Scientific Expedition and will occur over a period of two years on an overland traverse that will begin at Taylor Dome in Northern Victoria Land and travel to the South Pole. This data, along with similar information collected on a series of earlier traverse in West Antarctica, will contribute to providing an …

A Science Management Office For The United States Component Of The International Trans Antarctic Expedition (Us Itase Smo) - A Collaborative Program Of Research From Taylor Dome To, Paul Mayewski

University of Maine Office of Research Administration: Grant Reports

This award supports the science management office (SMO) for a series of collaborative science proposals that are part of the U.S. contribution to the International Trans-Antarctic Scientific Expedition (US ITASE). It supports the science administration and the coordination of logistics needed in order to accomplish the research. The SMO will work with the Antarctic support contractor to coordinate field operations for the traverse platform so that US ITASE can undertake a series of scientific traverses in the region from Taylor Dome, in Northern Victoria Land to South Pole (NVL-SP) inclusive of interior portions of the East Antarctic plateau such as …

Atmospheric Soluble Dust Records From A Tibetan Ice Core: Possible Climate Proxies And Teleconnection With The Pacific Decadal Oscillation, B. Grigholm, Paul A. Mayewski, Kang Shichang, Y. Zang, S. Kaspari, Sharon B. Sneed, Q. Zhang

Climate Change Institute Faculty Scholarship

In autumn 2005, a joint expedition between the University of Maine and the Institute of Tibetan Plateau Research recovered three ice cores from Guoqu Glacier (33°34′37.8″N, 91°10′35.3″E, 5720 m above sea level) on the northern side of Mt. Geladaindong, central Tibetan Plateau. Isotopes (δ¹⁸O), major soluble ions (Na⁺, K⁺, Mg²⁺, Ca²⁺, Cl⁻, NO₃⁻, SO₄²⁻), and radionuclide (β-activity) measurements from one of the cores revealed a 70-year record (1935–2005). Statistical analysis of major ion time series suggests that atmospheric soluble …

Collaborative Research: Drillsite Reconnaissance And Snow Chemistry Survey In Denali National Park, Karl J. Kreutz

University of Maine Office of Research Administration: Grant Reports

This is a collaborative proposal by Principal Investigators from the Universities of New Hampshire (UNH) and Maine. Understanding the mechanisms responsible for interannual to decadal-scale climate variability during the late Holocene remains a fundamental research problem in Arctic science. The Principal Investigator's will: 1) perform a detailed reconnaissance to identify suitable locations in Denali National Park (DNP) from which to recover and develop high resolution ice core records; and (2) develop detailed snow chemistry records that document the spatial (both horizontally and vertically) and seasonal variation of major ion and trace element deposition in the region. This will be the …

Collaborative Research: Abandoned Elephant Seal Colonies In Antarctica: Integration Of Genetic, Isotopic, And Geologic Approaches Toward Understanding Holocene Environmental Change, Brenda L. Hall

University of Maine Office of Research Administration: Grant Reports

During previous NSF-sponsored research, the PI's discovered that southern elephant seal colonies once existed along the Victoria Land coast (VLC) of Antarctica, a region where they are no longer observed. Molted seal skin and hair occur along 300 km of coastline, more than 1000 km from any extant colony. The last record of a seal at a former colony site is at ~A.D. 1600. Because abandonment occurred prior to subantarctic sealing, disappearance of the VLC colony probably was due to environmental factors, possibly cooling and encroachment of land-fast, perennial sea ice that made access to haul-out sites difficult. The record …

Itr: A Computational Framework For Observational Science: Data Assimilation Methods And Their Application For Understanding North Atlantic Zooplankton Dynamics, Andrew J. Pershing

University of Maine Office of Research Administration: Grant Reports

This project will develop a modular data assimilation system, investigate several algorithms to make data assimilation more efficient, and will apply this system to investigate zooplankton dynamics in the North Atlantic. The goal of data assimilation is to find the value of the control variables (typically, the initial conditions or boundary conditions or model parameters) producing the best agreement between the model and the data. A data assimilation system consists of a forward model representing known dynamics. This model is integrated and the deviation between its predictions and available observations are quantified by a cost function. An adjoint model, representing …

Observing Biogeochemical Cycles At Global Scales With Profiling Floats And Gliders: Prospects For A Global Array, Kenneth S. Johnson, William M. Berelson, Emmanuel S. Boss, Zanna Chase, Hervé Claustre, Steven R. Emerson, Nicolas Gruber, Arne Körtzinger, Mary Jane Perry, Stephen C. Riser

Marine Sciences Faculty Scholarship

Chemical and biological sensor technologies have advanced rapidly in the past five years. Sensors that require low power and operate for multiple years are now available for oxygen, nitrate, and a variety of bio-optical properties that serve as proxies for important components of the carbon cycle (e.g., particulate organic carbon). These sensors have all been deployed successfully for long periods, in some cases more than three years, on platforms such as profiling floats or gliders. Technologies for pH, pCO 2, and particulate inorganic carbon are maturing rapidly as well. These sensors could serve as the enabling technology for a global …

Teaching Physical Concepts In Oceanography: An Inquiry-Based Approach, Lee Karp-Boss, Emmanuel Boss, Herman Weller, James Loftin, Jennifer Albright

Marine Sciences Faculty Scholarship

This supplement to Oceanography magazine focuses on educational approaches to help engage students in learning and offers a collection of hands-on/minds-on activities for teaching physical concepts that are fundamental in oceanography. These key concepts include density, pressure, buoyancy, heat and temperature, and gravity waves. We focus on physical concepts for two reasons. First, students whose attraction to marine science stems from an interest in ocean organisms are typically unaware that physics is fundamental to understanding how the ocean, and all the organisms that inhabit it, function. Second, existing marine education and outreach programs tend to emphasize the biological aspects of …

Magma Extraction From The Mantle Wedge At Convergent Margins Through Dikes: A Parametric Sensitivity Analysis, Scott E. Johnson, Z.-H. Jin

Earth Science Faculty Scholarship

We address under what conditions a magma generated by partial melting at 100 km depth in the mantle wedge above a subduction zone can reach the crust in dikes before stalling. We also address under what conditions primitive basaltic magma (Mg # >60) can be delivered from this depth to the crust. We employ linear elastic fracture mechanics with magma solidification theory and perform a parametric sensitivity analysis. All dikes are initiated at a depth of 100 km in the thermal core of the wedge, and the Moho is fixed at 35 km depth. We consider a range of melt …

Collaborative Research: Erosional Forcing Of Late Quaternary Compressive Strain, West Central Taiwan, Phaedra Upton

University of Maine Office of Research Administration: Grant Reports

The concept of steady-state growth of compressive orogens is one of the most accepted ideas in continental tectonics developed in the last two decades, yet surprisingly few direct data exist to test the models that have been advanced. Testing and refining the concept of steady-state mountain building requires identification of cases of transient response and dynamic feedback in compressive orogens, and documentation of the spatial and temporal scales at which crustal deformation responds to erosion. This project takes advantage of a unique natural experiment in the active fold-thrust belt of west-central Taiwan where enough modern seismologic, geodetic, structural and geochronologic …

Mechanisms Controlling Metal And Phosphorus Dynamics In An Experimentally Acidified Watershed In Maine, Ivan J. Fernandez

University of Maine Office of Research Administration: Grant Reports

The Bear Brook Watershed in Maine (BBWM) is a long-term (14+ years), whole-watershed experiment designed to study ecosystem responses to acid deposition. One watershed has been treated bimonthly by helicopter with nitrogen and sulfur since 1989. Results have documented progressive acidification of soils and streams, substantial losses of soil nutrients (e.g., calcium), increased nitrogen cycling, and changes in tree foliar chemistry. Little research has been done on phosphorus, a critical nutrient in ecosystems. This project will evaluate the effects of long-term watershed acidification on metal mobilization (focusing on aluminum and iron) and linked effects on phosphorus at BBWM by studying …

A High-Resolution Record Of Atmospheric Dust Composition And Variability Since Ad 1650 From A Mount Everest Ice Core, S. Kaspari, Paul Andrew Mayewski, M. Handley, Shichang Kang, S. Hou, Sharon B. Sneed, Kirk A. Maasch, D. Qin

Earth Science Faculty Scholarship

A Mount Everest ice core analyzed at high resolution for major and trace elements (Sr, Cs, Ba, La, Ce, Pr, Nd, Sm, Eu, Tb, Dy, Ho, Er, Tm, Yb, Lu, Bi, U, Tl, Al, S, Ca, Ti, V, Cr, Mn, Fe, Co) and spanning the period A. D. 1650- 2002 is used to investigate the sources of and variations in atmospheric dust through time. The chemical composition of dust varies seasonally, and peak dust concentrations occur during the winter-spring months. Significant correlations between the Everest dust record and dust observations at stations suggest that the Everest record is representative of …

Effect Of Particulate Aggregation In Aquatic Environments On The Beam Attenuation And Its Utility As A Proxy For Particulate Mass, Emmanuel Boss, Wayne Slade, Paul Hill

Marine Sciences Faculty Scholarship

Marine aggregates, agglomerations of particles and dissolved materials, are an important particulate pool in aquatic environments, but their optical properties are not well understood. To improve understanding of the optical properties of aggregates, two related studies are presented. In the first, an in situ manipulation experiment is described, in which beam attenuation of undisturbed and sheared suspensions are compared. Results show that in the sheared treatment bulk particle size decreases and beam attenuation increases, consistent with the hypothesis that a significant fraction of mass in suspension is contained in fragile aggregates. Interestingly, the magnitude of increase in beam attenuation is …

Turbulence-Plankton Interactions: A New Cartoon, Peter A. Jumars, John H. Trowbridge, Emmanuel Boss, Lee Karp-Boss

Marine Sciences Faculty Scholarship

Climate change redistributes turbulence in both space and time, adding urgency to understanding of turbulence effects. Many analytic and analog models used to simulate and assess effects of turbulence on plankton rely on simple Couette flow. There shear rates are constant and spatially uniform, and hence so is vorticity. Over the last decade, however, turbulence research within fluid dynamics has focused on the structure of dissipative vortices in space and time. Vorticity gradients, finite net diffusion of vorticity and small radii of curvature of streamlines are ubiquitous features of turbulent vortices at dissipation scales but are explicitly excluded from simple, …

Us-Globec Nep Phase Iiia-Ccs: Large-Scale Influences On Mesoscale Structure In The Ccs, A Synthesis Of Climate-Forced Variability In Coastal Ecosystems, Andrew C. Thomas

University of Maine Office of Research Administration: Grant Reports

A variety of extreme climate events occurred during the period of the US GLOBEC NEP monitoring and process studies in the California Current System (CCS) (1997-2003). These provided an unprecedented opportunity to examine a wide range of climate variability experienced by the CCS and its ecosystems. By relating these climate events to regional physical and biological observations, using multiple and diverse data sources (GLOBEC and other recent observations, historical datasets, satellites, circulation and physical-biological models), the investigators will determine how these events affect mesoscale ocean variability and target populations in the CCS. The overarching goal of this project is to …

Metallophilic Interactions In Closed-Shell Metal-Metal Bonded Luminescent Systems And Their Tunability For Excited State Energy Transfer, Howard H. Patterson

University of Maine Office of Research Administration: Grant Reports

Howard Patterson, University of Maine, is supported by the Inorganic, Bioinorganic and Organometallic Chemistry Program for photochemical studies of metal-metal bonded excimers and exciplexes. In solution or in the solid state, dicyanoaurate(I) and dicyanoargentate(I) ions oligomerize. The oligomers show complex photochemistry, including luminescence caused by metallophilic interactions. These systems can be tuned over 18,000 wavenumbers by doping or by adding various donor ions. This research project will look in detail at lifetime and time-resolved studies, vibrational analysis by Raman scattering and infrared, structural studies by x-ray and neutron diffraction, and theoretical analyses. The research will provide insight into metallophilic interactions …

Maine's Climate Future: An Initial Assessment, George L. Jacobson, Ivan J. Fernandez, Paul Andrew Mayewski, Catherine V. Schmitt

Earth Science Faculty Scholarship

Earth’s atmosphere is experiencing unprecedented changes that are modifying global climate. Discussions continue around the world, the nation, and in Maine on how to reduce and eventually eliminate emissions of carbon dioxide (CO2), other greenhouse gases, and other pollutants to the atmosphere, land, and oceans. These efforts are vitally important and urgent. However, even if a coordinated response succeeds in eliminating excess greenhouse gas emissions by the end of the century, something that appears highly unlikely today, climate change will continue, because the elevated levels of CO2 can persist in the atmosphere for thousands of years to come.

In late …

Along-Strike Differences In The Southern Alps Of New Zealand: Consequences Of Inherited Variation In Rheology, Phaedra Upton, Peter O. Koons, Dave Craw, C. Mark Henderson, Ray Enlow

Earth Science Faculty Scholarship

Long- and short-term strain variations along the Australian-Pacific plate boundary through the South Island of New Zealand, including a 300% increase in orogen width, coexistence of oblique thrusting on orthogonal structures, and variability in the locus of orogenic gold deposits, coincide with rheologically relevant geological variation. Our model investigates the consequences of thin, strong lower crust in the north and thick, weak lower crust in the south. Solution of the full 3-D mechanical equations reproduces the larger wavelength strain patterns of the orogen. A 3-D perturbation-based analytical solution leads to the identification of the sensitivity of displacement type to minor …

Recent Increases In Atmospheric Concentrations Of Bi, U, Cs, S And Ca From A 350-Year Mount Everest Ice Core Record, Susan D. Kaspari, Paul Andrew Mayewski, Michael Handley, Erich Osterberg, Shichang Kang, Sharon B. Sneed, Shugui Hou, Dahe Qin

Earth Science Faculty Scholarship

High-resolution major and trace elements (Sr, Cs, Ba, La, Ce, Pr, Nd, Sm, Eu, Tb, Dy, Ho, Er, Tm, Yb, Lu, Bi, U, Tl, Al, S, Ca, Ti, V, Cr, Mn, Fe, and Co) quantified in a Mount Everest ice core ( 6518 m above sea level) spanning the period 1650-2002 AD provides the first Asian record of trace element concentrations from the pre-industrial era, and the first continuous high-resolution Asian record from which natural baseline concentrations and subsequent changes due to anthropogenic activities can be examined. Modern concentrations of most elements remain within the pre-industrial range; however, Bi, U, …

Acceptance Angle Effects On The Beam Attenuation In The Ocean, Emmanuel Boss, Wayne H. Slade, M. Behrenfeld, G. Dall'olmo

Marine Sciences Faculty Scholarship

The beam attenuation serves as a proxy for particulate matter and is a key parameter in visibility algorithms for the aquatic environment. It is well known, however, that the beam attenuation is a function of the acceptance angle of the transmissometer used to measure it. Here we compare eight different transmissometers with four different acceptance angles using four different deployment strategies and sites, and find that their mean attenuation values differ markedly and in a consistent way with instrument acceptance angle: smaller acceptance angles provide higher beam attenuation values. This difference is due to variations in scattered light collected with …

Chevkinite-Group Minerals From Granulite-Facies Metamorphic Rocks And Associated Pegmatites Of East Antarctica And South India, H. E. Belkin, R. Macdonald, Edward S. Grew

Earth Science Faculty Scholarship

Electron microprobe data are presented for chevkinite-group minerals from granulite-facies rocks and associated pegmatities of the Napier Complex and Mawson Station charnockite in East Antarctica and from the Eastern Ghats, South India. Their compositions conform to the general formula for this group, viz. A(4)BC(2)D(2)Si(4)O(22) where, in the analysed specimens A = (rare-earth elements (REE), Ca, Y, Th), B = Fe(2+) Mg, C = (Al, Mg, Ti, Fe(2+), Fe(3+), Zr) and D = Ti and plot within the perrierite field oftlic total Fe (as FeO) (wt.%) vs. CaO (wt.%) discriminator diagram of Macdonald and Belkin (2002). In contrast to most chevkinite-group …