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Full-Text Articles in Physical Sciences and Mathematics
Mechanisms And Dynamics Of The Metastable Decay In Ar-2(+), J. Fedor, K. Gluch, R. Parajuli, S. Matt-Leubner, Olof E. Echt, P. Scheier, T. D. Mark
Mechanisms And Dynamics Of The Metastable Decay In Ar-2(+), J. Fedor, K. Gluch, R. Parajuli, S. Matt-Leubner, Olof E. Echt, P. Scheier, T. D. Mark
Physics & Astronomy
A detailed experimental as well as theoretical investigation of the properties of the metastable dissociation Ar-2(+)-->Ar++Ar is presented. The mass-analyzed ion kinetic energy (MIKE) scan technique has been performed using a three sector field mass spectrometer. The possible mechanisms of the metastability of Ar-2(+) have been examined and the observed decay process is assigned to the II(1/2)(u)-->I(1/2)(g) bound to continuum radiative transition, in agreement with earlier work. The calculation of the theoretical shape of the kinetic energy release distribution of fragment ions allowed us to construct the theoretical MIKE peak and compare it with the raw experimental data. …
High-Resolution Kinetic Energy Release Distributions And Dissociation Energies For Fullerene Ions C(N)(+), 42 <= N <= 90, K. Gluch, S. Matt-Leubner, Olof E. Echt, B. Concina, P. Scheier, T. D. Mark
High-Resolution Kinetic Energy Release Distributions And Dissociation Energies For Fullerene Ions C(N)(+), 42 <= N <= 90, K. Gluch, S. Matt-Leubner, Olof E. Echt, B. Concina, P. Scheier, T. D. Mark
Physics & Astronomy
We have measured the kinetic energy released in the unimolecular dissociation of fullerene ions, C(n)(+)-->C(n-2)(+)+C(2), for sizes 42less than or equal tonless than or equal to90. A three-sector-field mass spectrometer equipped with two electric sectors has been used in order to ensure that contributions from isotopomers of different masses do not distort the experimental kinetic energy release distributions. We apply the concept of microcanonical temperature to derive from these data the dissociation energies of fullerene cations. They are converted to dissociation energies of neutral fullerenes with help of published adiabatic ionization energies. The results are compared with literature values. …
High Resolution Measurements Of Kinetic Energy Release Distributions Of Neon, Argon, And Krypton Cluster Ions Using A Three Sector Field Mass Spectrometer, K. Gluch, S. Matt-Leubner, L. Michalak, Olof E. Echt, A. Stamatovic, P. Scheier, T. D. Mark
High Resolution Measurements Of Kinetic Energy Release Distributions Of Neon, Argon, And Krypton Cluster Ions Using A Three Sector Field Mass Spectrometer, K. Gluch, S. Matt-Leubner, L. Michalak, Olof E. Echt, A. Stamatovic, P. Scheier, T. D. Mark
Physics & Astronomy
Using a newly constructed three sector field mass spectrometer (resulting in a BE1E2 field configuration) we have measured the kinetic energy release distributions of neon, argon, and krypton cluster ions. In the present study we used the first two sectors, B and E1, constituting a high resolution mass spectrometer, to select the parent ions in terms of mass, charge, and energy, and studied the decay of those ions in the third field free region. Due to the improved mass resolution we were able to extend earlier studies carried out with a two sector field machine, where an upper size limit …