Physical Sciences and Mathematics Commons^™

Landscape/Atmosphere Interactions And Carbon-Dioxide Dynamics In The Great Onyx Groundwater Basin, Mammoth Cave National Park, Kentucky, Meghan Raines

Masters Theses & Specialist Projects

An increase in atmospheric CO2 since the Industrial Revolution has altered rates of global climate change and has motivated a need to better quantify the flux of carbon between Earth’s reservoirs. Attempts to quantify the exchange of atmospheric carbon between sources and sinks have led to an increasing interest in the terrestrial landscape, including the continental carbon sink associated with carbonate-mineral dissolution. This research sought to better inform an understanding of karst landscapes and their relationship with global climate change through carbon cycling. The study utilized high-resolution data collection of pH, temperature, and specific conductance of waters in the Cascade …

A Predictive Flood Model For Urban Karst Groundwater Systems, Trayson Lawler

Masters Theses & Specialist Projects

Urban karst environments are often plagued by groundwater flooding, which occurs when water rises from the subsurface to the surface through the underlying caves and other karst features. The heterogeneity and interconnectedness of karst systems often makes them very unpredictable, especially during intense storm events; urbanization exacerbates the problem with the addition of many impervious surfaces. Residents in such areas are frequently disturbed and financially burdened by the effects of karst groundwater flooding. The Federal Emergency Management Agency (FEMA) offers limited protection to citizens living near flood-prone areas as they primarily focus on the areas near surface bodies of water. …

Factors Influencing Tree Growth In A Bottomland Hardwood Along The Green River In Kentucky, Caleb Miller

Masters Theses & Specialist Projects

In bottomland hardwood forests, large fluctuations in moisture availability can lead to stress from both flooded and drought conditions. These forests can have a complex species composition with different water use and drought strategies. The bottomlands in which these species co-occur can have a complex spatial distribution of alluvial sediments due to the meandering and migration of river or stream channels, which may impact the hydrology, nutrient dynamics, and productivity. At Western Kentucky University's Green River Preserve, approximately 9 ha of bottomland hardwood forest were planted in 2006. Although these hardwoods have received equal amounts of sunlight, rainfall, and wind, …

Investigating Epikarst Recharge Dynamics Under Agricultural Landuse Using Hydrometeorological And Isotopic Tracers, Austin Shane Deering

Masters Theses & Specialist Projects

Epikarst systems have complex recharge – discharge processes in telogenetic karst systems, including highly variable storage, flowpaths, and mixing dynamics. This research aimed to characterize the epikarst zone using hydrogen and oxygen isotopic tracers of these processes within south-central Kentucky’s Crumps Cave system located in the Pennyroyal Sinkhole Plain. Data and statistical analyses were applied to highresolution rainfall (RF), lysimeter (10 cm, 20 cm, 30 cm depths), and an epikarst Waterfall 1 (WF1) isotope data collected on a weekly basis between 2011-2018. These data were coupled with WF1 discharge measurements and weather station data collected at Crumps Cave Preserve during …

Hydrogeochemical Characterization And Speleogenesis Of Sistema Huautla In Oaxaca, Mexico, Fernando Hernandez

Masters Theses & Specialist Projects

Sierra Mazateca, Mexico is home to Sistema Huautla, the deepest cave in the Western hemisphere with 1,560 meters of depth and 90 kilometers of passage, including 26 entrances distributed in a high-relief, karstified terrain, within the Sistema Huautla Karst Groundwater Basin. Exploration of the cave has generated research questions about its evolution and geomorphology given the different vadose and phreatic zones impacted by tectonic and incision processes. Dye traces during this study of Cueva de La Peña Colorada confirmed it is a fossil resurgence of the cave system. An additional cave, Cueva Elysium, was connected hydrologically in 2019, expanding the …

Quantifying Tekeze River Canyon Incision On The Ethiopian Plateau From Low-Temperature Apatite Thermochronology, Jacob Thomas Grigsby

Masters Theses & Specialist Projects

The Ethiopian Plateau in East Africa features dynamic topography, deep river incision (~1.5 km), active tectonics, continental rifting, volcanic terrain and ~2 km of plateau uplift. Situated on the northwestern part of the Ethiopian Plateau, the Tekeze River is one of the two major rivers associated with incising and documenting the recent geologic history of the uplifted plateau landscape. The consequential Tekeze River incision into the uplifted Ethiopian Plateau is associated with the arrival and impingement of the Afar mantle plume as evidenced by the presence of thick sheets of Cenozoic flood basalts (~30 Ma). However, the Cenozoic to present-day …

Application Of 3d Salt Modeling: An Example From The Northeastern Gulf Of Mexico, Adam Mattson

Masters Theses & Specialist Projects

Salt tectonics has important implications for hydrocarbon exploration in saltbearing basins since salt deformation can directly or indirectly form hydrocarbon traps, influence hydrocarbon migration, and can control deepwater depositional systems. In various basins around the globe, extensive research has been conducted on initiation of salt mobilization, subsequent deformation, and eventual cessation, mostly from subsurface two-dimensional (2D) sections. However, 3D seismic data has dominated the petroleum industry for the last 30 years. Despite the plethora of 3D seismic data acquired in salt-bearing basins, there has been hardly any published work on the 3D geometries of complex salt bodies. 3D salt mapping …

Influence Of Spring Flow Reversals On Cave Dissolution In A Telogenetic Karst Aquifer, Mammoth Cave, Ky, Chelsey Kipper

Masters Theses & Specialist Projects

An often overlooked connection between karst groundwater systems and surface water is spring flow reversal, the flow of river water into karst springs caused by changes in hydraulic gradient. Karst aquifers are subject to the intrusion of river water when the hydraulic head of a base level river is higher than the hydraulic head of a base level spring. When this occurs, the flow out of the spring reverses, allowing river water to enter base level conduits. River water thus becomes a source of recharge into karst basins, transporting both valuable nutrients and harmful contaminants into karst aquifers. The rapid …

The Effectiveness Of Mobile Eye-Tracking To Enhance Guided Show Cave Experiences, Jenna Michele Hammond

Masters Theses & Specialist Projects

Karst terrains are landscapes with a distinctive hydrology and set of landforms that arise from a combination of high bedrock solubility and well-developed secondary (fracture) porosity. Karst areas are easily polluted due to the rapid transport of unfiltered percolating water through the systems. While many individuals are able to identify karst landforms such as sinkholes and caves, an understanding of the interconnectedness of the surface and subsurface in karst landscapes, as well as the vulnerability of karst areas to degradation, is often limited. Show caves, which are caves made accessible to visitation by humans through built infrastructure, can serve as …

Lithological Character And Sequence Stratigraphy Of The Ste. Genevieve Limestone In Western Kentucky, Zachary Dalton Creech

Masters Theses & Specialist Projects

The Ste. Genevieve Limestone is a Mississippian-aged, carbonate-dominated stratigraphic unit that is a prominent hydrocarbon producer in the Illinois Basin, and is widely distributed in states such as Missouri, Kentucky, Indiana, and Illinois. There has been relatively limited study focused on characterizing the Ste. Genevieve Limestone in terms of lithofacies, stacking patterns, and sequence stratigraphic context via analysis of roadcut exposures of the unit in western Kentucky.

The focus of this study is to use lithologic data collected from roadcuts and draft these data into cross sections for presentation of detailed stratigraphic columns that are locally correlative. Seven roadcuts were …

Indirect Greenhouse Gas Dynamics In Karst Groundwater Systems Under Agricultural Land Use, Stacy Wayne Antle

Masters Theses & Specialist Projects

Greenhouse gases (GHGs) are a major global environmental concern, because their concentrations have continuously increased over the past few centuries, due to global population growth, fossil fuel dependency, and the Industrial Revolution. Since these gases are naturally occurring phenomena, they will never be completely eliminated. Efforts to reduce them span numerous scientific attempts, with minimal improvements in reducing their atmospheric concentrations. In agricultural land practices, greenhouse gases are common byproducts that affect the atmosphere and, potentially, the groundwater where livestock and fertilizers are key contributors. Little is known about the fate of such greenhouse gases in dissolved form, known as …

Controls On Speleogenesis In The Upper-Mississippian Pennington Formation On The Western Cumberland Plateau Escarpment, Hali Steinmann

Masters Theses & Specialist Projects

Much of the pioneering work on caves of the Cumberland Plateau (province spanning Tennessee, Kentucky, Alabama, and Georgia) has been stratigraphically located within the Mississippian Bangor and Monteagle Limestones, wherein some of the region’s largest and most spectacular caves occur. Of interest to the understanding of this karst landscape, but severely underrepresented in the literature thereof, are caves and karst features in a heterogeneous sequence of clastics and carbonates known collectively as the Pennington Formation (Upper Mississippian). This work consisted of a regional study of Pennington caves on the western Cumberland Plateau escarpment (Alabama and Tennessee), and a case study …

Mass-Transport Deposits In The Northern Gulf Of Mexico And Their Implications For Hydrocarbon Exploration, Michael Raymond Arthur

Masters Theses & Specialist Projects

This study investigates Mio-Pliocene mass-transport deposits (MTDs) in an understudied, hydrocarbon-rich region of the northeastern Gulf of Mexico. The research utilizes a high-quality 3D seismic dataset with an area of 635 km2, along with wireline logs and biostratigraphic data. With the help of quantitative seismic geomorphology techniques, detailed mapping of MTDs suggests a complex erosional and depositional history. Deposition of a MTD unit resulted in a 180 m topographic high that substantially influenced the distribution and morphology of subsequent MTDs, specifically the bifurcation of later mass-transport flows. This bifurcation contributed to the generation of a non-shielded erosional remnant with an …

Land-Use Impacts On The Hydrology Of The Hidden River Groundwater Subbasin, Horse Cave, Hart County, Kentucky, Cesalea N. Osborne

Masters Theses & Specialist Projects

No abstract provided.

Unroofing History Of The Northwestern Ethiopian Plateau: Insights From Low-Temperature Apatite Thermochronology, Shelby Bowden

Masters Theses & Specialist Projects

The geology of Ethiopia is dominated by the Ethiopian Plateau that is similar in elevation to, but aerially larger than, the Colorado Plateau. Several rivers have incised through the plateau, creating gorges that reach up to 1.5 km in depth. The plateau uplifted to its current elevation and was subsequently incised sometime after the Oligocene flood basalt event that signaled the arrival of the African Superplume below Kenya and Ethiopia. Due to its size and extent, published climate modeling has indicated that Late Cenozoic plateau formation could have been a driving force in the East African Cenozoic climate changes. Although …

Epikarst Hydrogeochemical Changes In Telogenetic Karst Systems In South-Central Kentucky, Leah Jackson

Masters Theses & Specialist Projects

Telogenetic epikarst carbon sourcing and transport processes and the associated hydrogeochemical responses are often complex and dynamic. Among the processes involved in epikarst development is a highly variable storage and flow relationship that is often influenced by the type, rate, and amount of dissolution kinetics involved. Diffusion rates of CO2 in the epikarst zone may drive hydrogeochemical changes that influence carbonate dissolution processes and conduit formation. Most epikarst examinations of these defining factors ignore regional-scale investigations in favor of characterizing more localized processes. This study aims to address that discrepancy through a comparative analysis of two telogenetic epikarst systems under …

Evidence For Late Pliocene Deglacial Megafloods From Giant Sediment Waves In The Northern Gulf Of Mexico, Zexuan Wang

Masters Theses & Specialist Projects

Laurentide Ice Sheet outburst floods to the Gulf of Mexico have been mainly documented based on deep-sea cores, especially the megafloods, only during the last several interglacial episodes in the late Pleistocene. The paleoclimatic significance of giant sedimentary structures developed under unconfined Froude-supercritical turbidity currents in subaqueous settings is considerably under-examined. This research extensively documents >20-km-wide and 200-m-thick Plio-Pleistocene giant sediment waves for the first time on the northern Gulf of Mexico continental slope using 3D seismic data, which show waveform morphology in unprecedented detail. The results suggest that such large-scale bedforms were formed under sheet-like unconfined Froudesupercritical turbidity currents …

Measuring Inorganic Carbon Fluxes From Carbonate Mineral Weathering From Large River Basins: The Ohio River Basin, Autumn B. Singer

Masters Theses & Specialist Projects

Rising atmospheric CO2 concentrations have motivated efforts to better quantify reservoirs and fluxes of Earth’s carbon. Of these fluxes from the atmosphere, one that has received relatively little attention is the atmospheric carbon sink associated with carbonate mineral dissolution. Osterhoudt (2014) and Salley (2016) explored new normalization techniques to improve and standardize a process for measuring this flux over large river basins. The present research extends this work to the 490,600 km2 Ohio River drainage basin and 11 subbasins. The study estimated the DIC flux leaving these basins between October 1, 2013, and September 30, 2014, based on secondary hydrogeochemical, …

Synoptic Atmospheric Conditions, Land Cover, And Equivalent Temperature Variations In Kentucky, Dorothy Yemaa Na-Yemeh

Masters Theses & Specialist Projects

Research has demonstrated that equivalent temperature (T_E), which incorporates both the surface air temperature (T) and moist heat content associated with atmospheric moisture, is a better indicator of overall heat content. This thesis follows up on a study that used T_E to determine the impacts of land use/land cover and air masses on the atmospheric heat content over Kentucky during the growing season (April-September). The study, which used data from the Kentucky Mesonet, reveals that moist weather types dominate the growing season and, as expected, differences between T and T_E are smaller under dry atmospheric conditions …

Assessing Seasonal And Spatial Variability In The Hydrogeochemistry Of Glacial Meltwater In Iceland, Anisha Tuladhar

Masters Theses & Specialist Projects

A detailed comparative geochemical characterization of three different types of Iceland glacial systems was conducted during June, August, and October, 2016. The study was carried out at a total of 11 outlet glacier rivers flowing from the icecaps Vatnajökull, Eyjafjallajökull, and Mýrdalsjökull. A total of 75 grab samples were collected (25 for each sampling period). The hydrogeochemical variations of Icelandic glacial meltwater are influenced by volcanic activity, temporal changes, and geographical location, which differed between the sampling sites within the glaciers and icecaps. Lower pH range, and comparatively higher and variable specific conductivity, SO4, S and F is linked to …

In Situ Ion Exchange In A Micro-Porous Transition Metal Silicate Framework, Jason M. Lively

Masters Theses & Specialist Projects

Ion selectivity of minerals has traditionally been utilized in industry as a catalyst, metal separation, and environmental reclamation/sequestration tool. There is an increased interest in understanding ion selectivity mechanisms of micro-porous minerals and mineral-like structures and how they can be applied in various industries: environmental and, potentially, pharmaceutical. This study seeks to understand the ion exchange mechanisms in micro-porous zirconosilicates using time-resolved Raman spectroscopy and X-ray diffraction. The thesis material was exchanged with H+, Na+, K+, and Cs+ in order to better understand structural changes as well as the influence of the H+-bonding during the exchange process. It is hypothesized …

Evaluating The Influences Of Karst Hydrogeology On Freshwater Harmful Algal Blooms In Kentucky Lakes, Robert T. Schaefer

Masters Theses & Specialist Projects

A problem exists in Nolin River Lake and Rough River Lake in Kentucky, due to the increasing prevalence of cyanobacterial-based harmful algal blooms (CyanoHABs) and the threats they pose to local communities. These lakes were developed as artificial reservoirs from embankment. Further complicating the issue, the lakes are located within a heavily karstified region and there exists no plan or method currently for monitoring or managing CyanoHABs in a karst region with regard to groundwater inputs to the lake systems or their tributaries. A mixture of techniques and analysis methods was used to determine the best way to monitor and …

Devonian Hydrocarbon Production In South Central Kentucky: A Gis Study, Andrew David Reeder

Masters Theses & Specialist Projects

Historically, Devonian Corniferous hydrocarbon production in south-central Kentucky has been a major contributor to the total hydrocarbon resources within Butler, Edmonson, and Warren counties. The Corniferous adds to the already large hydrocarbon totals produced from the Illinois Basin; however, this hydrocarbon contribution does not come without major pitfalls and inconsistencies. The south-central Kentucky Devonian Corniferous rocks comprise a diverse and complex hydrocarbon system made up of multiple migration pathways, trapping mechanisms, and seals. The multiple Corniferous units all derive production from the same source rock: the New Albany Shale.

A Geographic Information System (GIS) containing data on surface elevations, structure …

Linking In-Situ Data With Remote Sensing To Analyze Tropical Glacier Stability And Retreat In The Cordillera Blanca, Peru, Chandler H. Santos

Masters Theses & Specialist Projects

Glaciers are a major source of freshwater around the world, but they are melting at an increased rate due to atmospheric warming resulting from anthropogenic climate change. In addition to temperature increases, light-absorbing particulates on glaciers also are contributing to glacial melt. This research examines how black carbon, released into the air through partial combustion of biofuels, is affecting the surface albedo of glaciers. I also delineate possible sources of black carbon in the Cordillera Blanca region of Peru. Ground data were collected each year from 2011 to 2013 during the local dry season. Effective black carbon (eBC) values were …

Karst Landscape Influence On The Planetary Boundary Layer Atmosphere, Zachary S. Sullivan

Masters Theses & Specialist Projects

Karst landscapes cover approximately 20% of the ice-free land area worldwide. The soluble nature of the bedrock within a karst landscape allows for the formation of caverns, joints, fissures, sinkholes, and underground streams, which affect the hydrological behavior of the region. Currently, the Noah Land-Surface Model (Noah- LSM), coupled with the Weather Research and Forecasting (WRF) model, does not provide a representation of the physical behavior of a karst terrain. Previous research has attempted to model karst behavior through soil moisture and land cover/land use changes to determine the influence this unique landscape may have on atmospheric phenomenon. This highlights …

The Role Of Diagenesis In Reservoir Development Of The Big Clifty (Jackson) Sandstone In South-Central Kentucky, Kort H. Butler

Masters Theses & Specialist Projects

The Big Clifty is a Chesterian-age Mississippian sandstone member of the Golconda Formation that extends from south-central Kentucky into adjacent Illinois and Indiana. Asphaltic deposits and conventional petroleum plays are distributed along the Pennyrile Fault System and Plateau in the southeastern portion of the Illinois basin. In south-central Kentucky anomalous oil-saturation geometries are observed in cored sections of the Big Clifty from wells in Warren and Butler counties along the margin of the Pennyrile Plateau. Petrographic study of the cores has revealed several diagenetic processes that have contributed to, or are directly responsible for, the anomalous oil saturation geometries and …

Petrographic Controls On Weathering Of The Haney Limestone, Steven M. Devine

Masters Theses & Specialist Projects

Although karst processes in south central Kentucky have been studied extensively, the Haney Limestone Member of the Golconda Formation has not been studied in detail in contrast to limestones stratigraphically below it that are thicker. In addition, the relationship between petrographic features of the Haney Limestone and the formation of caves and karst features has not been studied extensively compared to lithographic, petrographic, or structural variables

Petrographic data were collected using core and surface exposures across the study area of south central Kentucky from northern Logan and Warren counties up toward the Rough Creek Graben region, and stratigraphic columns were …

Reservoir Study And Facies Analysis Of The Big Clifty Sandstone In South Central Kentucky, Tyler S. Bodine

Masters Theses & Specialist Projects

The Big Clifty (Jackson) Sandstone Member of the Golconda Formation is the most important of the Mississippian (Chesterian) heavy-oil reservoirs in the southeastern Illinois Basin. Heavy oil reservoirs, or asphalt rock deposits, have been studied extensively in south central and western Kentucky, and ~2 billion barrels of original oil in place (OOIP) have been proposed to occur in the Big Clifty Sandstone. Despite high OOIP estimates, heterogeneities in the reservoir negatively impact the production of heavy oil deposits. Heterogeneities related to depositional facies changes are poorly understood in the Big Clifty Sandstone of Kentucky, where it has been mostly described …

An Investigation Of Groundwater Flow In The Vicinity Of Patoka Dam, Indiana, Lee Anne Bledsoe

Masters Theses & Specialist Projects

Several dams throughout the United States have been built on karst terrains, where soluble limestone bedrock has been dissolved to form features such as caves, sinkholes, and underground rivers. In such karst regions, subsurface hydrology can play an integral role in the condition, operation, and safety of dams and should be considered during risk assessment. Patoka Dam, near Jasper, Indiana, is situated on a well-developed karst landscape/aquifer system, faces significant potential challenges, and recently underwent risk assessment. A groundwater flow investigation using multiple fluorescent tracer tests, analysis of water-table elevations, isopach mapping of the Glen Dean Limestone, and spring hydrograph …

Station Exposure And Resulting Bias In Temperature Observations: A Comparison Of He Kentucky Mesonet And Asos Data, James Kyle Thompson

Masters Theses & Specialist Projects

Station siting, exposure, instrumentation, and time of observations influence longterm climatic records. This thesis compared and analyzed temperature data from four Kentucky Mesonet stations located in Fayette (LXGN), Franklin (LSML), Clark (WNCH), and Bullitt (CRMT) counties to two nearby Automated Surface Observation Systems (ASOS) stations in Kentucky. The ASOS stations are located at Louisville International Airport (Standiford Field - KSDF) and at Lexington Airport (Blue Grass Field - KLEX). The null hypothesis states that there is no significant difference in temperature measurements between the two types of stations. To quantify the differences in temperature measurements, geoprofiles and the following statistical …