Physical Sciences and Mathematics Commons^™

Pollutant Forecasting Using Neural Network-Based Temporal Models, Richard Pike

Masters Theses & Specialist Projects

The Jing-Jin-Ji region of China is a highly industrialized and populated area of the country. Its periodic high pollution and smog includes particles smaller than 2.5 μm, known as PM2.5, linked to many respiratory and cardiovascular illnesses. PM2.5 concentration around Jing-Jin-Ji has exceeded China’s urban air quality safety threshold for over 20% of all days in 2017 through 2020.

The quantity of ground weather stations that measure the concentrations of these pollutants, and their valuable data, is unfortunately small. By employing many machine learning strategies, many researchers have focused on interpolating finer spatial grids of PM2.5, or hindcasting PM2.5. However, …

Hydrological Dynamics Of Surface-Groundwater Interactions Between Major Springs Of Mammoth Cave And The Green River, Kentucky, Usa, Matthew Cecil

Masters Theses & Specialist Projects

Mammoth Cave is an iconic example of the cave and karst systems that underlie over 50% of the United States and provide around 13% of the world’s population with water resources. These environmental features are vulnerable to drought, pollution, and human impacts. The complex hydrological regime of the Mammoth Cave system has been studied in the past, but there are improvements and updates that can be made to the past research. The dynamics of the surface-groundwater system, particularly reversals of the Green River and how it backfloods into the cave, are some examples. Echo River and River Styx Springs provide …

Carbon Cycling And Critical Zone Dynamics In An Urbanized Karst Groundwater System, Amy Hourigan

Masters Theses & Specialist Projects

Increasing atmospheric CO₂ concentrations are correlated to rising global temperatures. Investigating the cumulative global carbon cycling processes is important to understand and quantify the global carbon cycle. By investigating basic geochemical parameters, EpCO₂, DIC, and δ¹³C_DIC, at four sites along Lost River Cave (LRC), in Bowling Green, Kentucky, concentrations, fluxes and sources of C dissolved in groundwater were determined. Urban karst groundwater systems, compared to more natural karst landscapes, typically exhibit widespread impervious, heat-absorbing surfaces, urban heat island effects, and increased anthropogenic groundwater inputs and localized CO₂ emissions. Carbonate hydrogeochemical …

An Integrated Gis & Flood Vulnerability Index Approach To Evaluating Risk & Environmental Equity In Urban Karst Communities, Chloe Cooper

Masters Theses & Specialist Projects

This study examines how the usage of an integrated GIS (Geographic Information Systems), flood vulnerability assessment, and management approaches can aid in hazard response planning in karst groundwater systems, particularly in urban environments. In order to also better understand the impacts of flood events on socially vulnerable groups, this research was focused on historically excluded communities. Additionally, place-based vulnerabilities were primarily assessed based upon three main factors in the vulnerability framework and how these components intersect: social, environmental conditions, and economic. By understanding which areas of the City of Bowling Green, an iconic urban karst area, are most vulnerable and …

Developing And Applying An Integrated Spatial Karst Evaluation And Management Priority Tool: Case Study In Tongass National Forest, Alaska, Usa, Christian Decelle

Masters Theses & Specialist Projects

Karst terrains are complex landscapes that are sensitive to human disturbance. Human activities have polluted and impacted many of these terrains around the world. To preserve these unique landscapes, many karst regions are protected and designated as national parks, geologic special areas, or UNESCO Biosphere Reserves. Despite the widespread general protection of karst landscapes globally, a review of each area’s management plan reveals there is no standardized method of cave and karst management or evaluation of karst impacts.

The non-standardization of karst management strategies may be due to the gap that exists between the needs of karst land managers and …

Manufacturing: The Qualitative Study Of A Transition To A Green Facility, Brandon David Staves

Masters Theses & Specialist Projects

This qualitative study focused on answering three core questions: How have facilities reduce pollutions in regards to the quality of air, water, land, light and noise? Which Types of pollution reduction projects are more or less successful to implement? What types of pollution are facilities focusing on and why? The results of the 15 companies surveyed show a variety of projects that facilities have used to reduce pollution, it also shows that cost is a major factor in the unsuccessful projects, and that facilities are actively focused on reducing Air, Land, and Water pollution. While the data shows a variety …

An Adaptive Hazard Planning And Mitigation Framework For Responding To Urban Contamination In Karst Aquifer Systems, James Edward Troxell

Masters Theses & Specialist Projects

Environmental hazards in karst regions are damaging and often go unnoticed until an issue has escalated to a point of affecting life or property. The field of emergency and environmental contamination response lacks planning or preparedness focused on remediating groundwater contamination in karst systems. A lack of preplanning before an incident can lead to confusion, delayed response, and the inability to remediate the contaminant. Due to the rapid movement of contaminants through urban karst groundwater aquifers, an efficient response plan that leverages localized data in a GIS should be developed and maintained in order to adequately respond. The objective of …

Revisiting Hudson County Water Co. V. Mccarter: Realism, The Public Trust Doctrine, And Environmental Conservation In The Lochner Era, Steven Huffman

Masters Theses & Specialist Projects

Legal histories of the Gilded Age and Progressive Era tend to focus inordinately on economic regulation within a doctrinal framework in which private rights, equal protection, and “substantive” due process guided judicial decision-making. Consequently, the overarching economic context in prevailing legal historiography obscures an important yet oft-overlooked development in the linkage between public rights, natural resource trusteeship, and the early-twentieth-century environmental conservation movement. This development is inextricably tied to the evolution of water law in the late nineteenth century and the expansion of the American commercial republic. A normative understanding of public water rights during this period is confined to …

Reimagining The Duck Stamp, Hunting Licensure And Public Land Preservation, Alec Wayne Boyd-Devine

Masters Theses & Specialist Projects

The American Migratory Bird Hunting and Conservation Stamp, or Duck Stamp, is a form of licensure issued by the Federal Government for waterfowl hunters. Why do physical stamps act as licensure to hunt waterfowl on both public and private land in the United States? How did the stamp become the key that grants access to resources that supposedly should be owned by the public? The duck stamp has been well-documented in conservation communities as a resource which has made significant positive impacts on the environment. The increase of anti-hunting sentiments in our society combined with fewer hunters per capita may …

Application Of Excitation-Emission Matrices To Fluorescent Dye Tracing Of Groundwater Flow, Cayla M. Baughn

Masters Theses & Specialist Projects

Fluorescent dye tracing of groundwater is a technique employed particularly in carbonate rock karst regions to examine karst hydrology by mapping underground flow paths. It is important to understand the hydrology of karst environments because solutionally-enlarged conduits may allow the rapid influx of contaminants into the groundwater system. Fluorescent dye tracing involves the injection of a fluorescent dye into an appropriate injection site (sinking streams, sinkholes, or even through soil flushed with water) and is followed by sampling at sites where the dye may be recovered (typically springs). Various methods exist by which sampling may occur, but all methods ultimately …

Synthesis Of Cds/Zns Core/Shell Semiconductor Nanoparticles, Austin Skyler Antle

Masters Theses & Specialist Projects

Core/shell semiconductor nanoparticles are of great interest as photocatalysts due to their large surface area per volume and tunable band gaps. The synthesis of core/shell semiconductor nanoparticles has traditionally involved the use of binding ligands to ensure the particles do not aggregate. These binding ligands lower the surface area of the nanoparticles though, reducing their overall efficiency. Ionic liquids have been found to be capable of acting as both solvents and stabilizing agents for synthesis of catalysts with highly active surfaces. Our experiments focus on the synthesis of CdS/ZnS core/shell nanoparticles with the ionic liquid 1-butyl-3-methylimidazolium methyl sulfate, [BMIM][MeSO4], acting …

Mercury And Other Trace Metal Analysis In Bat Guano, Amanda Lee Houchens

Masters Theses & Specialist Projects

Heavy metal pollution in the environment pose risks to ecosystems and the populations that reside in them. Mercury, lead, and cadmium negatively impact humans by way of neurological disorders, various cancers, and damage the reproductive organs, kidneys, and lungs. Bats have been studied as a bioindicator species to identify possibly elevated levels of these metals in the environment. Previous studies have identified correlation between metal concentrations within bat tissues and fur. Many bat species are endangered or at risk due to white-nose syndrome so collection of tissues and fur for analysis can impose stress on bat colonies. This study investigates …

The Enhancement Of Climate Change Science Communication And Understanding Through Glacier Tourism, Natalie Jean Kincheloe

Masters Theses & Specialist Projects

The natural environment provides the opportunity for educators to teach the general public about scientific topics that are misunderstood. Arctic tourism has increased as accessibility to these regions has improved. Informal learning is a valuable yet extremely understudied phenomenon within the tourism industry. Iceland is a country that lies in the North Atlantic and has experienced a significant increase in foreign visitors over the past decade. Of the natural features in Iceland, glaciers have become a top attraction for visitors. Since thousands of visitors participate in guided glacier tours annually in Iceland, an opportunity to couple glacier tourism with informal …

An Urban Karst Aquifer Resource Evaluation And Monitoring Toolbox, Rachel Anne Kaiser

Masters Theses & Specialist Projects

In urban karst areas, such as the City of Bowling Green, Kentucky and the Tampa Bay Metropolitan Area, groundwater quality faces a variety of threats. The development of residential, commercial, and industrial landuse types allows for a wide variety of groundwater pollutants to enter the karst groundwater systems. Various different models and indices have attempted evaluative approaches to identify issues in urban karst areas, but the methods vary by location and lack a focus on urban karst groundwater quality. There also exists a lack of a data-driven approach that is able to capture short- and long-term changes in threats to …

Lithological Character And Sequence Stratigraphy Of The Ste. Genevieve Limestone In Western Kentucky, Zachary Dalton Creech

Masters Theses & Specialist Projects

The Ste. Genevieve Limestone is a Mississippian-aged, carbonate-dominated stratigraphic unit that is a prominent hydrocarbon producer in the Illinois Basin, and is widely distributed in states such as Missouri, Kentucky, Indiana, and Illinois. There has been relatively limited study focused on characterizing the Ste. Genevieve Limestone in terms of lithofacies, stacking patterns, and sequence stratigraphic context via analysis of roadcut exposures of the unit in western Kentucky.

The focus of this study is to use lithologic data collected from roadcuts and draft these data into cross sections for presentation of detailed stratigraphic columns that are locally correlative. Seven roadcuts were …

A Tourism Impact Index For Water-Based Natural Attractions Field-Tested In Subarctic And Maritime Climates, Jason Fox

Masters Theses & Specialist Projects

Tourism in cold and cool-climate regions is largely characterized by recreational and sightseeing activities at water-based natural attractions such as beaches, coastal cliffs, and waterfalls. While the economic benefits of the tourism industry can contribute to a sustainable future for these regions, the environmental implications of a hastilydeveloped industry cannot be ignored given that cold-climate and cool-climate landscapes are at risk of rapid environmental change from a warming climate and other environmental concerns. This study consisted of the development of the Tourism Impact Index for Water-Based Natural Sites, the first of its kind, and its application and refinement in the …

Development Of A Karst Tourism Management Index To Assess Tourism-Driven Degradation Of Protected Karst Sites, Keith R. Semler

Masters Theses & Specialist Projects

The intent of this research was to create and evaluate a karst tourism management index (KTMI). This index is intended to be a new management tool designed to quantify environmental disturbances caused specifically by tourism activities in karst regions, particularly show caves and springs. In an effort to assess the effectiveness of the index as a management tool in karst terrains, after development, the index was applied to six case study sites. A review of the management policies at each study site was conducted with the use of standard policy critique methods and semistructured interviews with managers at the study …

Analysis Of 2017 Multi-Agency Field Campaign Data For Wintertime Surface Pollution In The Cache Valley Of Utah, Gerardo Diaz Jr.

Masters Theses & Specialist Projects

Atmospheric motions resulting from rising airborne parcels help to scatter emissions, including PM, away from their sources, decreasing local pollution levels. However this pattern shifts during the wintertime, as cold air damming and inversion layers create stable conditions that limit the vertical transport of air masses. Both point and area sources of emissions currently dot the western United States and are responsible for the production of the vast majority of agricultural pollution in the region. At the same time, population-growth has resulted in an ever-increasing amount of urbansource emissions. The entrapment of PM, which are produced when a wide array …

Monitoring And Evaluating The Influences Of Class V Injection Wells On Urban Karst Hydrology, James Adam Shelley

Masters Theses & Specialist Projects

The response of a karst aquifer to storm events is often faster and more severe than that of a non-karst aquifer. This distinction is often problematic for planners and municipalities, because karst flooding does not typically occur along perennial water courses; thus, traditional flood management strategies are usually ineffective. The City of Bowling Green (CoBG), Kentucky is a representative example of an area plagued by karst flooding. The CoBG, is an urban karst area (UKA), that uses Class V Injection Wells to lessen the severity of flooding. The overall effectiveness, siting, and flooding impact of Injection Wells in UKA’s is …

Indirect Greenhouse Gas Dynamics In Karst Groundwater Systems Under Agricultural Land Use, Stacy Wayne Antle

Masters Theses & Specialist Projects

Greenhouse gases (GHGs) are a major global environmental concern, because their concentrations have continuously increased over the past few centuries, due to global population growth, fossil fuel dependency, and the Industrial Revolution. Since these gases are naturally occurring phenomena, they will never be completely eliminated. Efforts to reduce them span numerous scientific attempts, with minimal improvements in reducing their atmospheric concentrations. In agricultural land practices, greenhouse gases are common byproducts that affect the atmosphere and, potentially, the groundwater where livestock and fertilizers are key contributors. Little is known about the fate of such greenhouse gases in dissolved form, known as …

Land-Use Impacts On The Hydrology Of The Hidden River Groundwater Subbasin, Horse Cave, Hart County, Kentucky, Cesalea N. Osborne

Masters Theses & Specialist Projects

No abstract provided.

Using Mobile Eye-Tracking To Inform The Development Of Mass Tourism In Iceland Towards The Principles Of Ecotourism, James Tyler Graham

Masters Theses & Specialist Projects

Since the late 20th century, nature-based tourism, an alternative to mass tourism with a focus on natural environments, has steadily grown in popularity. Nature-based tourism areas are considered a platform for informal education and exemplify principles of environmental stewardship and conservation. Iceland, an island nation in the North Atlantic, is one area of the world that has seen dramatic growth in its nature-based tourism industry in recent years; tourists are drawn to Iceland in numbers five times the total population of the Country. The pressures of economic development have resulted in the continued promotion of Icelandic tourism, and, subsequently, the …

An Evaluation Of Deterrent Methods Utilized To Prevent Crop Raiding By African Elephants (Loxodonta Africana) In The Kasigau Wildlife Corridor, Kenya, Rebecca Lynn Von Hagen

Masters Theses & Specialist Projects

Escalating human elephant conflict (HEC) continues to be a contributing factor

towards elephant decline, and crop raiding is the most common form of negative

human-elephant interactions. For communities that cannot reverse or prevent crop

raiding, it is necessary to contain HEC events through deterrent measures. Few

deterrent measures exist that combine practicality and affordability while also

preventing habituation by elephants. This project focused on comparing the efficacy of

deterrent methods to assess which was the most successful at preventing elephants

from entering crops in the farming community of Sasenyi, Kenya. In this paired-control

study, four deterrent methods were evaluated: acacia …

Policy Communication And The Influence Of Agricultural Communities On Karst Landscapes: A Case Study In Phong Nha-Kẻ Bàng National Park, Vietnam, Elizabeth Willenbrink

Masters Theses & Specialist Projects

Karst landscapes are vulnerable to human influence, especially agricultural practices. The interconnectedness between surface activities and subsurface environments make karst landscapes particularly susceptible to soil erosion and water contamination. The likelihood of these two phenomena happening increases when agricultural intensification, irrigation, or fertilizer application occurs. This situation arises frequently in Vietnam, where 18% of the country is karst terrain and 60% of the population depends on agriculture for their livelihoods (Farming First 2009). In order to mitigate the negative consequences of agriculture on karst landscapes, effective implementation of policy to regulate human activities and increased communication of these policies to …

Carbon Flux And Weathering Processes In Icelandic Glacial-Fed Rivers, Allison Quiroga

Masters Theses & Specialist Projects

An investigation into the carbon dynamics and weathering processes occurring in Icelandic glacial-fed streams was conducted during the spring to summer seasonal transition in June of 2017. Four major outlet rives were sampled from the glaciers of Gígjökull, Steinsholtsjökull, Sólheimajökull, and Falljökull. Markarfljót, the major river that Gígjökull, Steinsholtsjökull, and many other glaciers drain into, was also sampled. Longitudinal sampling occurred at all sites to capture downstream trends in the hydrogeochemistry and carbon dynamics. Distinct differences in geochemistry between glacier surface meltwater, sub-glacial waters, pro-glacial lake water, and post-mixed downstream samples were evident in the data. Glacier surface streams were …

Landscape Genetics Of The California Tiger Salamander: Inferences From Multiple Methods, Samantha Gabrielle Thomas

Masters Theses & Specialist Projects

Landscape genetics is a rapidly growing field of study that compares patterns of gene flow among populations with habitat heterogeneity across a landscape to infer the interaction between dispersal of individuals and their physical environment. Empirical data generated from a landscape genetics study can inform conservation and management strategies, making the field increasing popular. However, concerns have arisen in the literature that the field is expanding faster than the analytic framework that supports it. Multiple methods for generating estimates of the association among habitat types and dispersal (i.e., least-cost paths and resistance surfaces) have been proposed, and there is a …

Examination Of Leed Certified Building’S Electricity Usage, Nasim Amiri

Masters Theses & Specialist Projects

The number of buildings seeking LEED certification has been growing steadily over the past few years. In this study, three academic buildings which were designed and built to LEED certification standards were targeted in Bowling Green, Kentucky. Their electricity consumption and cost effectiveness were examined and compared with predesigned LEED efficiency models of those three buildings. This research directly examined cost effectiveness of LEED buildings in terms of electricity usage. Three case studies were completed to find the initial and on-going electricity costs of LEED buildings and to verify the LEED standard results. LEED aspects of these buildings were discussed …

One-Step Laser-Induced Hydrogen Generation From Coal Powders In Water, Dovletgeldi Seyitliyev

Masters Theses & Specialist Projects

This study presents a simple way of obtaining hydrogen gas (H2) from various ranks of coal, coke, and graphite using nanosecond laser pulses. Powder samples of coal and graphite with and without water were irradiated with 1064 nm and 532 nm pulses from an Nd: YAG laser for 45 minutes under air and argon atmospheres. It was observed that 532 nm laser pulses were more effective than 1064 nm pulses in gas generation and both were nonlinearly correlated with respect to the laser energy density. Mainly hydrogen (H2) and carbon monoxide (CO) were observed. The H2 to CO ratio shows …

Measuring Inorganic Carbon Fluxes From Carbonate Mineral Weathering From Large River Basins: The Ohio River Basin, Autumn B. Singer

Masters Theses & Specialist Projects

Rising atmospheric CO2 concentrations have motivated efforts to better quantify reservoirs and fluxes of Earth’s carbon. Of these fluxes from the atmosphere, one that has received relatively little attention is the atmospheric carbon sink associated with carbonate mineral dissolution. Osterhoudt (2014) and Salley (2016) explored new normalization techniques to improve and standardize a process for measuring this flux over large river basins. The present research extends this work to the 490,600 km2 Ohio River drainage basin and 11 subbasins. The study estimated the DIC flux leaving these basins between October 1, 2013, and September 30, 2014, based on secondary hydrogeochemical, …

Dispersion Of Ammonia From Concentrated Animal Feeding Operations, Austin D. Wardall

Masters Theses & Specialist Projects

The purpose of this research is to investigate the dispersion of ammonia (NH3) from three Concentrated Animal Feeding Operations (CAFOs) in western Kentucky, as well as to investigate the Weather Research and Forecasting – Chemistry (WRF-Chem) model’s sensitivity response to initial NH3 concentrations under both wet conditions (significant precipitation) and dry conditions (no precipitation). As expected, pollutant concentrations generally were significantly higher near their points of origin and generally declined away from the sources. Contrary to expectations, ammonia tended to rise through the planetary boundary layer (PBL) regardless of atmospheric conditions. Results showed modeled NH3 pollution levels at the surface …