Physical Sciences and Mathematics Commons^™

Pollutant Forecasting Using Neural Network-Based Temporal Models, Richard Pike

Masters Theses & Specialist Projects

The Jing-Jin-Ji region of China is a highly industrialized and populated area of the country. Its periodic high pollution and smog includes particles smaller than 2.5 μm, known as PM2.5, linked to many respiratory and cardiovascular illnesses. PM2.5 concentration around Jing-Jin-Ji has exceeded China’s urban air quality safety threshold for over 20% of all days in 2017 through 2020.

The quantity of ground weather stations that measure the concentrations of these pollutants, and their valuable data, is unfortunately small. By employing many machine learning strategies, many researchers have focused on interpolating finer spatial grids of PM2.5, or hindcasting PM2.5. However, …

Bioactivity And Structural Properties Of Hydroxyapatite On Ti6a|4v And Si(100) Surfaces By Pulsed Laser Deposition, Salizhan Kylchbekov

Masters Theses & Specialist Projects

Although biomedical implant technology is very advanced, there are still caveats in terms of biocompatibility properties because metals are inert to biological processes such as osseointegration, cell growth, and cell adhesion. This results in statistically significant complications and opens rooms for improvements. Among many techniques to improve this problem, coating the metal surface with biologically functional materials has resulted in the best performances. Hydroxyapatite (HAP), Ca_₁₀(PO_₄)_₆(OH)_₂, is the most stable form of calcium phosphates in human body environment and is functional in key processes such as ion exchange, osteoblast (bone cells) formation, …

Hydrological Dynamics Of Surface-Groundwater Interactions Between Major Springs Of Mammoth Cave And The Green River, Kentucky, Usa, Matthew Cecil

Masters Theses & Specialist Projects

Mammoth Cave is an iconic example of the cave and karst systems that underlie over 50% of the United States and provide around 13% of the world’s population with water resources. These environmental features are vulnerable to drought, pollution, and human impacts. The complex hydrological regime of the Mammoth Cave system has been studied in the past, but there are improvements and updates that can be made to the past research. The dynamics of the surface-groundwater system, particularly reversals of the Green River and how it backfloods into the cave, are some examples. Echo River and River Styx Springs provide …

Source Code Plagiarism Detection Using Jplag & Stack Overflow Data, Sudheer Yetthapu

Masters Theses & Specialist Projects

Advancements in computer technology and internet services have led to the availability of vast amounts of information like videos, articles, research papers, and code samples. Free online information will increase the possibility of plagiarism and collusion among students. People can commit plagiarism in both text and code [1], as tools used to detect plagiarism between texts and between codes are distinct. Traditionally plagiarism in code is detected using manual inspection, which is a tedious process and misses to compare code from previous submissions and external sources. To overcome this issue, systems that can automatically detect plagiarism in code were developed …

Robust Sensor Design For The Novel Reduced Models Of The Mead-Marcus Sandwich Beam Equation, Ahmet Aydin

Masters Theses & Specialist Projects

Novel space-discretized Finite Differences-based model reductions are proposed for the partial differential equations (PDE) model of a multi-layer Mead-Marcus-type beam with (i) hinged-hinged and (ii) clamped-free boundary conditions. The PDE model describes transverse vibrations for a sandwich beam whose alternating outer elastic layers constrain viscoelastic core layers, which allow transverse shear. The major goal of this project is to design a single boundary sensor, placed at the tip of the beam, to control the overall dynamics on the beam.

For (i), it is first shown that the PDE model is exactly observable by the so-called nonharmonic Fourier series approach. However, …

K-Means Clustering Using Gravity Distance, Ajinkya Vishwas Indulkar

Masters Theses & Specialist Projects

Clustering is an important topic in data modeling. K-means Clustering is a well-known partitional clustering algorithm, where a dataset is separated into groups sharing similar properties. Clustering an unbalanced dataset is a challenging problem in data modeling, where some group has a much larger number of data points than others. When a K-means clustering algorithm with Euclidean distance is applied to such data, the algorithm fails to form good clusters. The standard K-means tends to split data into smaller clusters during a clustering process evenly.

We propose a new K-means clustering algorithm to overcome the disadvantage by introducing a different …

Manufacturing: The Qualitative Study Of A Transition To A Green Facility, Brandon David Staves

Masters Theses & Specialist Projects

This qualitative study focused on answering three core questions: How have facilities reduce pollutions in regards to the quality of air, water, land, light and noise? Which Types of pollution reduction projects are more or less successful to implement? What types of pollution are facilities focusing on and why? The results of the 15 companies surveyed show a variety of projects that facilities have used to reduce pollution, it also shows that cost is a major factor in the unsuccessful projects, and that facilities are actively focused on reducing Air, Land, and Water pollution. While the data shows a variety …

Statistical Study Of The Effect Of Implementing An Airveyor System On The Warpage Of Injection Molded Closures, Charles Wesley Bozarth

Masters Theses & Specialist Projects

Berry Global in Bowling Green, Kentucky produces predominantly polypropylene container closures. One variant, the 83mm lined jar closure, is produced by first being injection molded, placed in work-in-progress (WIP) hold for 24 hours to cool, and then finished through the auxiliary liner operation into a final product. While this process is an effective method to produce a quality large-diameter closure and allows the polypropylene adequate time to cool without warping out of shape, the 24-hour WIP time and the manpower needed to accomplish this can negatively impact several business metrics as well as employee safety.

The purpose of this thesis …

Morphology And Structure Of Pb Thin Films Grown On Si (111) By Pulsed Laser Deposition, Bektur Abdisatarov

Masters Theses & Specialist Projects

Pulsed laser deposition (PLD) is a versatile thin film deposition technique in which high powered laser beam interacts with a target material inside an ultrahigh vacuum chamber. Highly energetic particles such as electrons, atoms, protons, and ions generate a plasma plume that directed towards a substrate material where recondenses form a thin film. PLD is an effective and reliable method to create varieties of thin films such as metal, polymer, and ceramic for many technologically essential applications.

In this study, thin Pb films were grown by pulsed laser deposition on Si (111) at various laser fluences, pulse wavelengths, deposition times, …

A Comparative Study Of Recommendation Systems, Ashwini Lokesh

Masters Theses & Specialist Projects

Recommendation Systems or Recommender Systems have become widely popular due to surge of information at present time and consumer centric environment. Researchers have looked into a wide range of recommendation systems leveraging a wide range of algorithms. This study investigates three popular recommendation systems in existence, Collaborative Filtering, Content-Based Filtering, and Hybrid recommendation system. The famous MovieLens dataset was utilized for the purpose of this study. The evaluation looked into both quantitative and qualitative aspects of the recommendation systems. We found that from both the perspectives, the hybrid recommendation system performs comparatively better than standalone Collaborative Filtering or Content-Based Filtering …

Maquiladoras In Central America: An Analysis Of Workforce Schedule, Productivity And Fatigue., Jose L. Barahona

Masters Theses & Specialist Projects

Textile factories or Maquiladoras are very abundant and predominant in Central American economies. However, they all do not have the same standardized work schedule or routines. Most of the Maquiladoras only follow schedules and regulations established by the current labor laws without taking into consideration many variables within their organization that could affect their overall performance. As a result, the purpose of the study is to analyze the current working structure of a textile Maquiladora and determine the most suitable schedule that will abide with the current working structure but also increase production levels, employee morale and decrease employee fatigue. …

Exploring The Effect Of Different Numbers Of Convolutional Filters And Training Loops On The Performance Of Alphazero, Jared Prince

Masters Theses & Specialist Projects

In this work, the algorithm used by AlphaZero is adapted for dots and boxes, a two-player game. This algorithm is explored using different numbers of convolutional filters and training loops, in order to better understand the effect these parameters have on the learning of the player. Different board sizes are also tested to compare these parameters in relation to game complexity. AlphaZero originated as a Go player using an algorithm which combines Monte Carlo tree search and convolutional neural networks. This novel approach, integrating a reinforcement learning method previously applied to Go (MCTS) with a supervised learning method (neural networks) …

Monitoring And Evaluating The Influences Of Class V Injection Wells On Urban Karst Hydrology, James Adam Shelley

Masters Theses & Specialist Projects

The response of a karst aquifer to storm events is often faster and more severe than that of a non-karst aquifer. This distinction is often problematic for planners and municipalities, because karst flooding does not typically occur along perennial water courses; thus, traditional flood management strategies are usually ineffective. The City of Bowling Green (CoBG), Kentucky is a representative example of an area plagued by karst flooding. The CoBG, is an urban karst area (UKA), that uses Class V Injection Wells to lessen the severity of flooding. The overall effectiveness, siting, and flooding impact of Injection Wells in UKA’s is …

Molecular Assembly Of Monolayer-Protected Gold Nanoparticles And Their Chemical, Thermal, And Ultrasonic Stabilities, Steven Ray Isaacs

Masters Theses & Specialist Projects

Gold monolayer-protected nanoclusters (MPCs) with average diameters of 1-5 nm protected by alkane- and arenethiolates were synthesized. Mixed-monolayer protected nanoparticles (MMPCs) were prepared by functionalizing hexanethiolate-protected MPCs with either 11-mercaptoundecanoic acid (MUA-MMPC), 11-mercaptoundecanol (MUO-MMPC), or 4-aminothiophenol (ATP-MMPC) using ligand place exchange. Presentation of various chemical reagents such as nucleophile, acid, or base and change in physical environment through ultrasonic and thermal irradiation resulted in changes to particles and their physical properties. Thermogravimetric analysis (TGA) was used to measure maximum temperature of the derivated thermogravimetric peaks (Tmax,DTG) as a means of comparing temperature dependence of mass loss. The absorption spectrum within …

Application Of Huffman Data Compression Algorithm In Hashing Computation, Lakshmi Narasimha Devulapalli Venkata,

Masters Theses & Specialist Projects

Cryptography is the art of protecting information by encrypting the original message into an unreadable format. A cryptographic hash function is a hash function which takes an arbitrary length of the text message as input and converts that text into a fixed length of encrypted characters which is infeasible to invert. The values returned by the hash function are called as the message digest or simply hash values. Because of its versatility, hash functions are used in many applications such as message authentication, digital signatures, and password hashing [Thomsen and Knudsen, 2005].

The purpose of this study is to apply …

Controllability And Observability Of The Discrete Fractional Linear State-Space Model, Duc M. Nguyen

Masters Theses & Specialist Projects

This thesis aims to investigate the controllability and observability of the discrete fractional linear time-invariant state-space model. First, we will establish key concepts and properties which are the tools necessary for our task. In the third chapter, we will discuss the discrete state-space model and set up the criteria for these two properties. Then, in the fourth chapter, we will attempt to apply these criteria to the discrete fractional model. The general flow of our objectives is as follows: we start with the first-order linear difference equation, move on to the discrete system, then the fractional difference equation, and finally …

Nano/Submicro-Structured Iron Cobalt Oxides Based Materials For Energy Storage Application, Hongyan Gao

Masters Theses & Specialist Projects

Supercapacitors, as promising energy storage devices, have been of interest for their long lifespan compared to secondary batteries, high capacitance and excellent reliability compared to conventional dielectric capacitors. Transition metal oxides can be applied as the electrode materials for pseudocapacitors and offer a much higher specific capacitance. Co3O4 is one of the most investigated transition metal oxides for supercapacitor. Besides simple monometallic oxides, bimetallic transition oxides have recently drawn growing attention in electrochemical energy storage. They present many unique properties such as achievable oxidation states, high electrical conductivities because of the coexistence of two different cations in a single crystal …

Synthesis,Structure And Properties Of Ruthenium Polypyridyl Metalloligand Based Metal-Organic Frameworks, Mamatha Polapally

Masters Theses & Specialist Projects

Metal-organic frameworks (MOFs) have been extensively studied because of their amazing applications in gas storage, purification, photocatalysis, chemical sensing, and imaging techniques. Ruthenium polypyridyl complexes have been broadly considered as photosensitizers for the conversion of solar energy and photoelectronic materials. With this aspect, we have synthesized three new ruthenium polypyridyl based MOFs ([Ru(H2bpc)Cu(bpc)(Hbpc)2(H2O)]·5H2O (1), [Ru(H2bpc)(Fe(bpc)(Hbpc)2(H2O)2]·6H2O (2) and [Ru(H2bpc)Ni(bpc)(Hbpc)2(H2O)2]·6H2O (3)) from ruthenium(III) chloride, bpc (2,2’- bipyridine-4,4’-dicarboxylic acid) ligand, and 3d M(II) metal ions (M(II)= Cu(II), Fe(II), Ni(II)). These MOFs were synthesized under hydro or solvothermal conditions by using water, ethanol or methanol as solvents. The crystal structures of the new compounds …

An Expedited, Regiospecific Para-Bromination Of Activated Aryls, Kathryn E. Dudley

Masters Theses & Specialist Projects

Electrophilic Aromatic Substitution (EAS) is one of the most frequently used aryl substitution methods. Aside from the fact that most EAS reactions require an acid and an oxidizer to proceed, the reactions involving activated aryls typically produce a mixture of ortho- and para- products as well as an ortho-/para- disubstituted product. Regiospecificity in aromatic substitution is key in the production of many compounds in a variety of disciplines. Since EAS is one of the most often used substitution methods, it is extremely important to develop an efficient method for regiospecific substitutions. Previous research developed a method of ortho-substitution by using …

Synthesis, Characterization, And Properties Of Graphene-Based Hybrids With Cobalt Oxides For Electrochemical Energy Storage And Electrocatalytic Glucose Sensing, Sara C. Botero Carrizosa

Masters Theses & Specialist Projects

A library of graphene-based hybrid materials was synthesized as novel hybrid electrochemical electrodes for electrochemical energy conversion and storage devices and electrocatalytical sensing namely enzymeless glucose sensing. The materials used were supercapacitive graphene-family nanomaterials (multilayer graphene-MLG; graphene oxide-GO, chemically reduced GO-rGO and electrochemical reduced GOErGO) and pseudocapacitive nanostructured transition metal oxides including cobalt oxide polymorphs (CoO and Co3O4) and cobalt nanoparticles (CoNP). These were combined through physisorption, electrodeposition, and hydrothermal syntheses approaches. This project was carried out to enhance electrochemical performance and to develop electrocatalytic platforms by tailoring structural properties and desired interfaces. Particularly, electrodeposition and hydrothermal synthesis facilitate chemically-bridged …

Environmentally Friendly Synthesis Of Transition Metalorganic Hybrid Nanocomposites, Aubrey N. Penn

Masters Theses & Specialist Projects

Research on metal nanoparticles (MNPs) synthesis and their applications for optoelectronic devices has been a recent interest in the fields of nanoscience and nanotechnology Photovoltaics are one of such systems in which MNPs have shown to be quite useful, due to unique physical, optical, magnetic, and electronic properties, including the metal nanoparticles synthesized in this research.

Owing to the challenges with the most common physical and chemical methods of preparing MNPs, including the use of high temperatures, toxic reducing agents, and environmentally hazardous organic solvents, there is a critical need for a benign synthesis procedure for MNPs. In this work, …

Metal-Organic Hybrid Nanocomposites For Energy Harvesting Applications, Thulitha Madawa Abeywickrama

Masters Theses & Specialist Projects

Various synthetic methods have been developed to produce metal nanostructures including copper and iron nanostructures. Modification of nanoparticle surface to enhance their characteristic properties through surface functionalization with organic ligands ranging from small molecules to polymeric materials including organic semiconducting polymers is a key interest in nanoscience. However, most of the synthetic methods developed in the past depend widely on non-aqueous solvents, toxic reducing agents, and high temperature and high-pressure conditions. Therefore, to produce metal nanostructures and their nanocomposites with a simpler and greener method is indeed necessary and desirable for their nano-scale applications. Hence the objective of this thesis …

Vertical Implementation Of Cloud For Education (V.I.C.E.), Travis S. Brummett

Masters Theses & Specialist Projects

There are several different implementations of open source cloud software that organizations can utilize when deploying their own private cloud. Some possible solutions are OpenNebula, Nimbus, and Eucalyptus. These are Infrastructure-as-a-Service (IaaS) cloud implementations that ultimately gives users virtual machines to undefined job types. A typical IaaS cloud is composed of a front-end cloud controller node, a cluster controller node for controlling compute nodes, a virtual machine image repository node, and many persistent storage nodes and compute nodes. These architectures are built for ease of scalability and availability.

Interestingly, the potential of such architectures could have in the educational field …

Investigation Of Carbon Nanomaterials Embedded In A Cementitious Matrix, Clarissa A. Roe

Masters Theses & Specialist Projects

The objective of this thesis was to investigate whether the addition of carbon nanofibers had an effect on the splitting tensile strength of Hydro-Stone gypsum concrete. The carbon nanofibers used were single-walled carbon nanotubes (SWNT), buckminsterfullerene (C60), and graphene oxide (GO). Evidence of the nanofibers interacting with gypsum crystals in a connective manner was identified in both 1 mm thick concrete discs and concrete columns possessing a height of 2 in and a diameter of 1 in. Before imaging, the columns were subjected to a splitting tensile strength test. The results illustrate that while there is a general decrease in …

In The Face Of Anticipation: Decision Making Under Visible Uncertainty As Present In The Safest-With-Sight Problem, Bryan A. Knowles

Masters Theses & Specialist Projects

Pathfinding, as a process of selecting a fixed route, has long been studied in

Computer Science and Mathematics. Decision making, as a similar, but intrinsically different, process of determining a control policy, is much less studied. Here, I propose a problem that appears to be of the first class, which would suggest that it is easily solvable with a modern machine, but that would be too easy, it turns out. By allowing a pathfinding to anticipate and respond to information, without setting restrictions

on the \structure" of this anticipation, selecting the \best step" appears to be an intractable problem.

After …

Pedestrian Detection Using Basic Polyline: A Geometric Framework For Pedestrian Detection, Liang Gongbo

Masters Theses & Specialist Projects

Pedestrian detection has been an active research area for computer vision in recently years. It has many applications that could improve our lives, such as video surveillance security, auto-driving assistance systems, etc. The approaches of pedestrian detection could be roughly categorized into two categories, shape-based approaches and appearance-based approaches. In the literature, most of approaches are appearance-based. Shape-based approaches are usually integrated with an appearance-based approach to speed up a detection process.

In this thesis, I propose a shape-based pedestrian detection framework using the geometric features of human to detect pedestrians. This framework includes three main steps. Give a static …

Visible-Light-Responsible Co-Catalysts Enhanced By Graphene For Solar Energy Harvesting, Chen Ying

Masters Theses & Specialist Projects

This study focuses on the visible light response of hetero-structures of TiO2-graphene- MoS2 for solar energy harvestings. The commercial P25 TiO2 nano-particles, and selfprepared layered reduced graphene oxides (RG) and MoS2 were assembled for the targeted hetero-structure materials as visible-light responsible solar harvesting cocatalysts. The hydrothermal method was applied for nano-material synthesis, the reduction of graphene oxides, and bonding formation. Multiple characterization methods (SEM-TEM, XRD, XPS, UV-VIS, PL, FT-IR, TGA) have been applied to understand the electron-hole pair separation and recombination, and performance tuning in their visible-light photo-catalysis rhodamine B (Rh.B) degradations process

Compared to TiO2, an obvious red shift …

Distributed Approach For Peptide Identification, Naga V K Abhinav Vedanbhatla

Masters Theses & Specialist Projects

A crucial step in protein identification is peptide identification. The Peptide Spectrum Match (PSM) information set is enormous. Hence, it is a time-consuming procedure to work on a single machine. PSMs are situated by a cross connection, a factual score, or a probability that the match between the trial and speculative is right and original. This procedure takes quite a while to execute. So, there is demand for enhancement of the performance to handle extensive peptide information sets. Development of appropriate distributed frameworks are expected to lessen the processing time.

The designed framework uses a peptide handling algorithm named C-Ranker, …

The Cadet Training Program Versus The Student Certification Program: A Study Of It- Support Training Programs At Western Kentucky University, Michael Courtney Moore

Masters Theses & Specialist Projects

Technology is a critical component of modern-day success. Advancements in technology have improved communication between individuals and companies. Technological advancements have allowed students to earn college degrees online. People who habitually use technology expect a high level of performance and support. As new technologies are implemented, such as complex web services or new operating systems, the dependence for information technology (IT) support grows in demand. Even learning curves can be cumbersome without proper assistance from IT professionals. Companies and institutions must accommodate user needs by implementing fast, efficient, and friendly support. In order to offer optimal customer support, representatives must …

Synthesis Of Rhenium And Manganese Pyridazoal Complexes, Jesse Evans

Masters Theses & Specialist Projects

Pyridazines are a heterocyclic aromatic compound containing a characteristic N-N bond that are utilized in many fields, including medicine and electronics. It is this latter field that Dr. Snyder's research group is focused upon. Organometallic compounds are a better conducting material than the current inorganic compounds used in electronics due to better conductance of electricity, lower production cost, and the ability to be formed into thin films. With this in mind, Dr. Snyder's research group has set out to synthesize organometallic compounds for this purpose. Following procedures set forth by Snyder etc, and altered to form an off-metal route, we …