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Full-Text Articles in Physical Sciences and Mathematics

Phonon Density Of States Of Iron Solid Solutions At Ambient And High Pressures Using Nuclear Inelastic X-Ray Scattering (Nrixs), Samantha L. Combs, Elizabeth A. Tanis, Malcolm Nicol Aug 2008

Phonon Density Of States Of Iron Solid Solutions At Ambient And High Pressures Using Nuclear Inelastic X-Ray Scattering (Nrixs), Samantha L. Combs, Elizabeth A. Tanis, Malcolm Nicol

Undergraduate Research Opportunities Program (UROP)

Nuclear resonant inelastic x-ray scattering (NRIXS) of synchrotron radiation uses the energy transferred during the inelastic nuclear absorption of photons to determine phonon density of states for solid Mössbauer isotopes. This type of experiment can be conducted at ambient and high pressures with the use of a diamond anvil cell (DAC) and a rhenium gasket. Here, we are concerned with the phonon DOS of α-FePt 10% at pressures up to 30 GPa, as well as FeAl 4.3%, 6.4%, and 27.1% at ambient pressures. The iron samples used are doped in order to increase the pressure at which the alpha to …


Structural Studies Of Crsi2 At High Pressures And Temperatures, Weldu Gabrimicael, Ravhi S. Kumar, Andrew Cornelius Aug 2008

Structural Studies Of Crsi2 At High Pressures And Temperatures, Weldu Gabrimicael, Ravhi S. Kumar, Andrew Cornelius

Undergraduate Research Opportunities Program (UROP)

It is of extreme importance to develop new potential energy sources to reduce dependence on fossil fuels. As a result of this, the study of thermoelectric materials, capable of changing heat into electrical energy, has become a field of great interest regarding fundamental properties. To help better understand these materials, facilities for the measurement of relevant properties at high pressure have been developed, but lack the ability to characterize the materials at high temperature and pressure. Therefore, this project has the goal of developing a heater arrangement to be used in conjunction with the high pressure capabilities already developed to …


The Search For Ferroelectric Domain Structures In Carbohydrate Glasses Using Atomic Force Microscopy, Louis S. Prahl, David P. Shelton Aug 2008

The Search For Ferroelectric Domain Structures In Carbohydrate Glasses Using Atomic Force Microscopy, Louis S. Prahl, David P. Shelton

Undergraduate Research Opportunities Program (UROP)

D-glucose was studied as a possible candidate for ferroelectric domain imaging using an Atomic Force Microscope (AFM). The large dipole moment of carbohydrates is such that they may show localized ferroelectric domain formation in liquid phase. Samples were heated at their melting point on glass slides and then left to cool to room temperature in a desiccator. Differential Thermal Analysis (DTA) was used to test the effectiveness of this method, and it was found that the oven preparation created samples with 41% crystallinity, where both a glass transition and sharp melting peak were observed. DTA was again used to find …


Raman Studies Of 1,3,5,7 Cyclooctatetraene At High Pressure, Martin Galley, Ed Romano, Sergey Tkachev, Michael Pravica Aug 2008

Raman Studies Of 1,3,5,7 Cyclooctatetraene At High Pressure, Martin Galley, Ed Romano, Sergey Tkachev, Michael Pravica

Undergraduate Research Opportunities Program (UROP)

We performed Raman spectroscopic studies of 1,3,5,7-cyclooctatetraene at elevated pressures up to 10 GPa with the aim of examining possible planarization of the molecule and further studying two prior-discovered phases of the solid with pressure. The Raman excitation source was a Krypton-ion laser operating at 674.1 nm (give wavelength).

1,3,5,7 Cyclooctatetraene has an octagonal formation however it is not aromatic or anti-aromatic (not a subject to the 4n+2 Huckel’s rule) [1]. As a result, its adopts a somewhat reactive tub shape. Upon the addition or removal of one to two electrons under ambient conditions, the molecule planarizes and becomes aromatic …


Spatially Resolved Optical Absorption Spectrometry And Single Crystal Diffraction On Metamict Materials, Alison Savage, Oliver Tschauner, Sergey Tkachev Aug 2008

Spatially Resolved Optical Absorption Spectrometry And Single Crystal Diffraction On Metamict Materials, Alison Savage, Oliver Tschauner, Sergey Tkachev

Undergraduate Research Opportunities Program (UROP)

A major goal in developing storage medium for radioactive waste is the identification of chemically suitable and durable material for storage in repositories (Lumpkin 2006). Radiation damage induces enhanced chemical diffusion and structural breakdown of the host materials, which can lead to contamination of the surrounding environment. During this project four different naturally occurring materials which are common carriers of thorium and uranium were examined : gadolinite, perrierite, allanite, and pyrochlore of which the first three are silicates and pyrochlore being an oxide. Their spectra and absorptions bands were examined to identify prominent features due to radiation damage. The goal …


Nuclear Energy, Steve Kraft Apr 2008

Nuclear Energy, Steve Kraft

Native American Forum on Nuclear Issues

Abstract:

-Why Nuclear Energy?

-The lesson of the last 20 years in U.S. electricity policy:

– Diversified fuel and technology portfolio is essential

– All fuels and technologies (nuclear, coal, natural gas, renewables, efficiency) have a legitimate role

-The challenge for the future:

– Preserving/restoring diversified portfolio

– Ensuring resource adequacy, particularly in competitive markets

-Expanded use of nuclear energy is part of the answer

– Integrated used fuel management supports nuclear competitiveness