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UNLV Theses, Dissertations, Professional Papers, and Capstones

Theses/Dissertations

2010

Adsorption

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Full-Text Articles in Physical Sciences and Mathematics

Rare Earth Element Transport In The Yucca Mountain Region, Liqiong Zhang Dec 2010

Rare Earth Element Transport In The Yucca Mountain Region, Liqiong Zhang

UNLV Theses, Dissertations, Professional Papers, and Capstones

In sync with environmental pollution of solutes in nature, from source, process to consequence, geochemical processes (leaching and sorption) and hydraulic transportation of the rare earth elements (REEs) have been investigated at Yucca Mountain (YM), Nevada. This research includes the leaching behavior of trace elements (including REEs) from aquifer rocks, the surface complexation reactions of REEs in synthetic groundwater, and transportation of reactive REEs in the local-scale groundwater system of YM. This dissertation includes three projects. These studies indicate that surface complexation reactions may retard the transportation of REEs along groundwater paths in YM, which suggests a similar behavior of …


Theoretical And Computational Study Of Time Dependent Scattering On A 2d Surface, Michael Sohn Apr 2010

Theoretical And Computational Study Of Time Dependent Scattering On A 2d Surface, Michael Sohn

UNLV Theses, Dissertations, Professional Papers, and Capstones

The quantum mechanical treatment of the elastic scattring of atoms from a crystal surface provides valuable information, such as surface properties and gas-surface interaction potentials. However, since it is based on the stationary state solution, it does not provide the details of the scattering process in the neighborhood of the surface, especially when atoms are physically adsorbed. In this thesis, the time evolution of the scattering process is treated in 2D with a model potential, V(x, z) = -|g|δ(z) + λδ(z)cos(2πx/a), using the Gaussian wave packet approach. The focus is on the case where the Gaussian wave packet makes a …