Physical Sciences and Mathematics Commons^™

Schrödinger, 4, David Peak

Schrodinger

The sanitized hydrogen atom: separating the variables

Separation of variables in the Schrödinger Equation for the hydrogen problem requires expressing Ψ as a product, Ψ(r,θ,φ,t) = R(r)Θ(θ )Φ(φ)T(t) , substituting into the partial differential equation [(5) in Sc3], and then dividing by Ψ. As in the square well problems, the separation constant for the t part of the separation is the particle’s eigen-energy, E.