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Full-Text Articles in Physical Sciences and Mathematics
Fabrication Of All-Inorganic Nanocrystal Solids Through Matrix Encapsulation Of Nanocrystal Arrays, Erich Kinder, Pavel Moroz, Geoffrey Diederich, Alexa Johnson, Maria Kirsanova, Alexander Nemchinov, Timothy O’Connor, Dan Roth, Mikhail Zamkov
Fabrication Of All-Inorganic Nanocrystal Solids Through Matrix Encapsulation Of Nanocrystal Arrays, Erich Kinder, Pavel Moroz, Geoffrey Diederich, Alexa Johnson, Maria Kirsanova, Alexander Nemchinov, Timothy O’Connor, Dan Roth, Mikhail Zamkov
Physics and Astronomy Faculty Publications
A general strategy for low-temperature processing of colloidal nanocrystals into all-inorganic films is reported. The present methodology goes beyond the traditional ligand-interlinking scheme and relies on encapsulation of morphologically defined nanocrystal arrays into a matrix of a wide-band gap semiconductor, which preserves optoelectronic properties of individual nanoparticles while rendering the nanocrystal film photoconductive. Fabricated solids exhibit excellent thermal stability, which is attributed to the heteroepitaxial structure of nanocrystal matrix interfaces, and show compelling light-harvesting performance in prototype solar cells.
The Role Of Hole Localization In Sacrificial Hydrogen Production By Semiconductor-Metal Heterostructured Nanocrystals, Krishna P. Acharya, Rony S. Khnayzer, Timothy O’Connor, Geoffrey Diederich, Maria Kirsanova, Anna Klinkova, Daniel Roth, Erich Kinder, Martene Imboden, Mikhail Zamkov
The Role Of Hole Localization In Sacrificial Hydrogen Production By Semiconductor-Metal Heterostructured Nanocrystals, Krishna P. Acharya, Rony S. Khnayzer, Timothy O’Connor, Geoffrey Diederich, Maria Kirsanova, Anna Klinkova, Daniel Roth, Erich Kinder, Martene Imboden, Mikhail Zamkov
Physics and Astronomy Faculty Publications
The effect of hole localization on photocatalytic activity of Pt-tipped semiconductor nanocrystals is investigated. By tuning the energy balance at the semiconductor-ligand interface, we demonstrate that hydrogen production on Pt sites is efficient only when electron-donating molecules are used for stabilizing semiconductor surfaces. These surfactants play an important role in enabling an efficient and stable reduction of water by heterostructured nanocrystals as they fill vacancies in the valence band of the semiconductor domain, preventing its degradation. In particular, we show that the energy of oxidizing holes can be efficiently transferred to a ligand moiety, leaving the semiconductor domain intact. This …