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Full-Text Articles in Physical Sciences and Mathematics
Thermal Correction To The Molar Polarizability Of A Boltzmann Gas, Ulrich D. Jentschura, Mariusz Puchalski, Peter J. Mohr
Thermal Correction To The Molar Polarizability Of A Boltzmann Gas, Ulrich D. Jentschura, Mariusz Puchalski, Peter J. Mohr
Physics Faculty Research & Creative Works
Metrology in atomic physics has been crucial for a number of advanced determinations of fundamental constants. In addition to very precise frequency measurements, the molar polarizability of an atomic gas has recently also been measured very accurately. Part of the motivation for the measurements is due to ongoing efforts to redefine the International System of Units (SI), for which an accurate value of the Boltzmann constant is needed. Here we calculate the dominant shift of the molar polarizability in an atomic gas due to thermal effects. It is given by the relativistic correction to the dipole interaction, which emerges when …
Blackbody-Radiation Correction To The Polarizability Of Helium, Mariusz Puchalski, Ulrich D. Jentschura, Peter J. Mohr
Blackbody-Radiation Correction To The Polarizability Of Helium, Mariusz Puchalski, Ulrich D. Jentschura, Peter J. Mohr
Physics Faculty Research & Creative Works
The correction to the polarizability of helium due to blackbody radiation is calculated near room temperature. A precise theoretical determination of the blackbody radiation correction to the polarizability of helium is essential for dielectric gas thermometry and for the determination of the Boltzmann constant. We find that the correction, for not too high temperature, is roughly proportional to a modified hyperpolarizability (two-color hyperpolarizability), which is different from the ordinary hyperpolarizability of helium. Our explicit calculations provide a definite numerical result for the effect and indicate that the effect of blackbody radiation can be excluded as a limiting factor for dielectric …