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OES Theses and Dissertations

Theses/Dissertations

2003

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Full-Text Articles in Physical Sciences and Mathematics

Dissolved Humic Substances: Characterization Of Their Sorption Onto Iron Hydroxide Aluminum Hydroxide Kaolinite And Smectite, Sarah E. Diebel Oct 2003

Dissolved Humic Substances: Characterization Of Their Sorption Onto Iron Hydroxide Aluminum Hydroxide Kaolinite And Smectite, Sarah E. Diebel

OES Theses and Dissertations

Humic (HA) and fulvic (FA) acids participate in many geochemical processes and the mechanisms of their sorption to colloidal surfaces are numerous, indicating these substances are complex and heterogeneous. The current study focuses on the interactions of the Fe hydroxide (FE), Al hydroxide, Kaolinite (KA) and Smectite (SM) and these naturally occurring organic acids using Fourier Transform Infrared Spectroscopy (FTIR) and DOC analysis at pH 4. FTIR was used for the initial functional group characterization, as well as the comparison of before and after adsorption spectra of the HA and FA. DOC examined the amounts of HA and FA adsorbed …

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Wind-Induced Exchange In Semi-Enclosed Basins, Rosario Sanay Oct 2003

Wind-Induced Exchange In Semi-Enclosed Basins, Rosario Sanay

OES Theses and Dissertations

The wind-induced circulation over laterally varying bathymetry was investigated in homogeneous and in stratified systems using the three-dimensional Regional Ocean Model (ROMS). For homogeneous systems, the focus was to describe the influence of the earth's rotation on the lateral distribution of the flow with particular emphasis on the transverse circulation. Along-basin wind-stress with no rotation caused a circulation dominated by an axially symmetric transverse structure consisting of downwind flow over the shoals and upwind flow in the channel along the whole domain. Transverse circulation was important only at the head of the system where the water sank and reversed direction …

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