Physical Sciences and Mathematics Commons^™

Validation Of Weak Form Thermal Analysis Algorithms Supporting Thermal Signature Generation, Elton Lewis Freeman

Masters Theses

Extremization of a weak form for the continuum energy conservation principle differential equation naturally implements fluid convection and radiation as flux Robin boundary conditions associated with unsteady heat transfer. Combining a spatial semi-discretization via finite element trial space basis functions with time-accurate integration generates a totally node-based algebraic statement for computing. Closure for gray body radiation is a newly derived node-based radiosity formulation generating piecewise discontinuous solutions, while that for natural-forced-mixed convection heat transfer is extracted from the literature. Algorithm performance, mathematically predicted by asymptotic convergence theory, is subsequently validated with data obtained in 24 hour diurnal field experiments for …

Equipment Qualification Of Ion Mobility Spectrometry And Method Development And Validation For Pharmaceutical Equipment Cleaning Validation, Amy Lee Heiser

Masters Theses

Ion mobility spectrometry (IMS) instrumentation has been identified as a suitable technology for the detection and reporting of drug product and detergent residues from pharmaceutical manufacturing equipment. Ion mobility is not a new technology, but is entering the field of cleaning validation because of tightened requirements from the US Food and Drug Administration (FDA).

The purpose of this thesis is to outline a practical implementation of the analytical technique, Ion Mobility Spectrometry in a cleaning validation program. Ion Mobility Spectrometry (IMS) is fast and specific for the analysis of small organic molecules and has been gaining popularity in the pharmaceutical …

Faunal Distribution And Relative Abundance In A Silurian (Wenlock) Pinnacle Reef Complex - Ray Reef, Macomb County, Michigan, Jennifer L. Trout

Masters Theses

Niagaran (Silurian) reefs are important sources of hydrocarbons in the Michigan Basin. In addition, some of these reservoirs have been used for gas storage and may be potential CO2 sequestration sites.

Despite extensive research on Niagaran reefs, most studies concerning faunal abundance and distribution have been qualitative studies conducted by paleontologists with an emphasis on taxonomy, paleoecology, and evolution.

This study is the first quantitative study of relative abundance and general distribution of fauna throughout a single Wenlock reef located in the southern trend of the Michigan Basin. This study will build on previous work done by WMU students and …

Privacy And Security Issues In Iot Healthcare Applications For The Disabled Users A Survey, Wassnaa Al-Mawee

Masters Theses

Aging of the population resulted in new challenges for the society and healthcare systems. Ambient Assisted Living (AAL) that depends on Internet of Things (IoT) provides assistance to the disabled people and supports their vital daily life activities. Affordability of and accessibility to AAL and the usage of IoT starts revolutionizing healthcare services. This Thesis is a survey of the privacy and security issues in IoT healthcare applications for the disabled users. Introduction includes definitions of privacy and security terms, and discusses their relationship. Then, it presents an overview of the IoT, including its architecture and components. Next, the Thesis …

Stratigraphic Framework For Deposits Of The Saginaw Lobe, Barry And Calhoun Counties, Michigan, Usa, Stephanie K. Ewald

Masters Theses

Between 2006 and 2012, twelve rotasonic borings were drilled in Barry and Calhoun Counties, south central Michigan, as part of several Great Lakes Geological Mapping Coalition projects. Natural gamma ray logs were collected at every location and a detailed description and textural analysis was completed for seven of these cores. Five of the seven analyzed cores reached bedrock. Six of the seven borings were drilled north of the Kalamazoo Moraine of the Saginaw Lobe, which was constructed during retreat of the lobe after the Late Glacial Maximum. Five borings, drilled in tunnel valleys, indicate an increase in depth of tunnel …

Characterizing The Internal Architecture Of Upper Bone Spring Limestone Turbidites And Mass-Transport Deposits (Mtds) Utilizing High-Resolution Image Log Technology, Jason J. Asmus

Masters Theses

Characterization of reservoir scale (less than 1 meter thick) turbidites and mass-transport deposits (MTDs) using conventional subsurface data is complex, due to millimeter-centimeter scale architectural heterogeneity exhibited by these deposits.

Limited studies of the Bone Spring carbonate turbidites and MTDs within the Delaware Basin subsurface emphasized the use of conventional wire-line log and seismic data to evaluate reservoir potential of such strata. As a result, limited resolution offered by these data sets do not allow for accurate characterization of reservoir, and sub-reservoir scale, architectural and compositional variations.

The present investigation integrates high-resolution (centimeter scale) electrical borehole image logs with conventional …

The Effects Of Replacing Dispersed Trash And Recycling Bins With Integrated Waste Receptacles On The Accuracy Of Waste Sorting In An Academic Building, Katherine J. Binder

Masters Theses

Numerous researchers and theorists have attempted to explain the existence of the gap between the possession of environmental knowledge and awareness and the display of pro-environmental behavior (Glasser, 2007; Kollmuss & Agyeman, 2002). Behavior analysis is uniquely aligned to contribute to this discussion through its emphasis on the role of controlling variables in behavior change. A growing number of behavioral research studies address the challenges of group-contingencies in an effort to solve real-world gaps (Lehman & Geller, 2004). This study was designed as a continuation of the line of behavioral research designed to increase recycling rates and also as an …

Physics Faculty Use Of Example Solutions In Teaching Introductory Physics, William O. Mamudi

Masters Theses

This study investigates how physics faculty perceive and use features of example problem solutions. Thirty physics instructors from diverse institutions participated in semi-structured interviews. In addition to open-ended questions, three example problem solution artifacts were used to focus on specific solution features. Data were analyzed to identify instructors’ goals for the use of example solutions and whether their goals were consistent with the solution features that they valued and used. The study concludes that many faculty have three major goals: keeping students cognitively involved, helping students become better problem solvers, and supporting students in learning physics. The study also found …

Direct Analysis Of Hops By Leaf Spray And Paper Spray Mass Spectrometry, Kari Blain

Masters Theses

The objective of this research is to develop a new and innovative method of hops analysis, which is much faster than standard testing methods, as well as reduce the amount of consumables and solvent used. A detailed discussion on the development of an ambient ionization mass spectrometry method called paper spray (PS-MS) and leaf spray (LS-MS) mass spectrometry will be presented. This research investigates the use of PS-MS and LS-MS techniques to determine the α- and β- acids present in hops. PS-MS and LS-MS provide a fast way to analyze hops samples by delivering data as rapidly as a UV-Vis …

Evaluation Of Tagging Techniques Gamma-Decay Probabilities Using The Surrogate Method, Timothy Lee Reed

Masters Theses

A detailed analysis of the statistical and discrete [gamma]-decay tagging techniques was conducted using the absolute surrogate and surrogate ratio method (SRM) to obtain the 92Mo(n,[gamma]) cross section in an equivalent neutron energy range of 80 to 880 keV. Excited 93Mo and 95Mo nuclei were populated using (d,p) reactions on 92Mo and 94Mo targets, respectively. The absolute surrogate 92Mo(n,[gamma]) cross sections disagreed with evaluated neutron capture cross section data by as much as a factor of 4 using the statistical tagging approach, whereas the discrete [gamma]-decay tag absolute surrogate cross section disagreed with the evaluated neutron capture cross section by …

Azimuthal Seismic First-Arrival Tomography As A Proxy For Hydraulically Conductive Subsurface Fracture Networks, Matthew Brooks Edmunds

Masters Theses

The Oak Ridge Field Research Center (ORFRC) was established by the Environmental Sciences Division (ESD) at the Oak Ridge National Laboratory (ORNL) in Oak Ridge, TN, in order to study the various biogeochemical processes involved in the remediation as well as natural attenuation of a large contaminant plume that is extant in the vicinity of the ORIFRC. A part of this work has been to characterize the movement of this groundwater/contaminant plume with the use of azimuthal seismic first-arrival tomography (ASFT).

Within the general area of the ORIFRC, a 0-2 m layer of generally isotropic anthropogenic fill and unconsolidated soil …

Synthesis Of Palladium-Based Electrocatalysis—From Pure Metal To Bimetallic Nanoparticles, Haijun Gao

Masters Theses

This thesis focuses on synthesis and characterization of palladium-based nanoparticles. Background information of the research in this thesis is provided in Chapter 1. Preparation and characterization of pure palladium nanoparticles are presented in Chapter 2. A fast and convenient method to prepare ultra small Pd nanoparticles via Pluronic P123 reduction is discussed in detail. Impregnation method and poly method are also studied in this chapter. Chapter 3 reports the studies of these methods to prepare ultra small bimetallic (bimetallic means a mixture of two metals) palladium-based nanoparticles. Oleylamine-mediated method used Pd nanoparticles prepared via P123 reduction as precursor. Ultra small …

Effects Of Prescribed Fire And Habitat On Golden-Winged Warbler (Vermivora Chrysoptera) Abundance And Nest Survival In The Cumberland Mountains Of Tennessee, Katie Lee Percy

Masters Theses

Golden-winged Warbler (Vermivora chrysoptera) populations in Appalachia have declined precipitously over the past 45 years. The primary objective of my study was to monitor the response of Golden-winged Warblers to prescribed fire treatments on reclaimed coal mines in the North Cumberland Wildlife Management Area, Tennessee. Presence-absence surveys were conducted on eight mountain-top study sites and nest searching/monitoring was conducted on two additional sites, 2009-2011. I expanded on previous research of Golden-winged Warbler territory and nest-site selection by determining differences within main effects between used and unused territory plots, as well as used and unused nest-sites. Of my two …

Public Land In A Changing Climate: Planning For An Uncertain Future, Kathleen Marie Hauser

Masters Theses

This thesis investigates the ways in which institutions and actors consider climate change, and how the inclusion of diverse perspectives and challenges in the planning process shapes climate change governance. In particular, I asked how the participants, place-specific contexts, and decision-making processes affect environmental decision-making in Alaska’s National Parks. I discuss the literature on geographical perspectives on climate change, environmental and climate change governance, how uncertainty and risk affect decision-making in the context of climate change, and the history of land use management in the United States. This project incorporates qualitative methods to research the Climate Change Scenario Planning project …

On The Spherical Symmetry Of Perfect-Fluid Stellar Models In General Relativity, Joshua M Brewer

Masters Theses

It is well known in Newtonian theory that static self-gravitating perfect fluids in a vacuum are necessarily spherically symmetric. The necessity of spherical symmetry of perfect-fluid static spacetimes with constant density in general relativity is shown.

Contextualizing The Tipton-Haynes State Historic Site (40wg59): Understanding Landscape Change At An Upland South Farmstead., Daniel Whitaker Howard Brock

Masters Theses

This thesis focuses on a contextual archaeological approach to investigate the historic landscape of the Tipton-Haynes State Historic Site. Tipton-Haynes is a late eighteenth- through twentieth-century upland south farmstead located in Johnson City, TN. Home to two prominent Tennessee families and occupied until acquired by the state in the 1960s, the site has experienced many alterations to the landscape over time. The analysis presented views the landscape as material culture investigated through a multidisciplinary approach including historic research, architectural survey, geophysical survey, dendrochronology, and archaeology. To make sense of the complex nature of the Tipton-Haynes site, multiple methods were used …

Co2 Injection Into A Deep Saline Aquifer: Porosity Measurements, Numerical Modeling, And Costs Associated With Uncertainty Of Petrophysical Parameters, Michael John Gragg

Masters Theses

Anthropogenic levels of atmospheric greenhouse gases, particularly carbon dioxide (CO₂) have increased rapidly over the last several decades and coincide with rising temperatures globally. One possible solution is to capture CO₂ before it is released into the atmosphere by large point sources, such as fossil fuel power plants. Once captured, the CO₂ can be condensed and transported to a storage facility. Of the available options for storage of condensed CO₂, geologic sequestration in deep saline aquifers is considered the most viable option.

Porosity measurements were obtained for nearly 100 core samples of the Knox …

Testing A Novel Technique To Improve Aluminum-26 Accelerator Mass Spectrometry Measurements For Earth Science Applications, Meghan Sarah Janzen

Masters Theses

The measurement of cosmogenic ²⁶Al [aluminum-26] in geological samples by accelerator mass spectrometry (AMS) is typically conducted on Al₂O₃ [aluminum oxide] targets. However, Al₂O₃ is not an ideal source material because it does not form a prolific beam of Al^- [negative atomic aluminum ions] required for measuring low-levels of ²⁶Al. This thesis presents the performance of AlN [aluminum nitride], AlF₃ [aluminum fluoride] and mixed AlN + Al₂O₃ as novel alternative source materials for the analysis of ²⁶Al. A negative ion cesium sputtering source at the Holifield …

Synthesis, Characterization, And Functionalization Of 2-Vinyl-4,4-Dimethylazlactone Brushes To Create Bio-Inspired Materials, Camille Marie Kite

Masters Theses

Functional materials built from polymer scaffolds inspire many potential uses, including as biomaterial surfaces or sensors. In situ functionalization using well-defined polymer “brushes” made by tethering polymer chains to a surface by one of their ends is explored. Specifically, poly(2-vinyl-4,4-dimethylazlactone) (PVDMA) chains, which contain a reactive azlactone ring at each repeat unit, are tethered to a surface to create brushes and these films are functionalized using a variety of small molecules, primarily amines or peptides. Relationships between polymer brush thickness, size of the functionalizing molecule, solution concentration, reaction time, and extent of functionalization were determined through measurements of brush thickness …

On Decision Making: Bayesian And Stochastic Optimization Approaches, Yang Shen

Masters Theses

Decision analysis provides a framework for searching an optimal solution under uncertainties and potential risks. This thesis focuses on two problems arising in transportation engineering and computer sciences, respectively.

First, it is considered a centralized controller which imposes actions on a number of interacting subsystems. Employing an appropriate Markov Decision Process framework, we establish that the Pareto optimal solution of each subsystem will be optimal for the entire system. Synthetic data have been taken into account for verifying this claim.

Next, we focus on a supercomputing problem utilizing a hierarchical Bayesian model. We estimate an optimal solution in order to …

Power Management For Cloud-Scale Data Centers, Yanwei Zhang

Masters Theses

Recent years have seen the rapid growth of large and geographically distributed data centers deployed by Internet service operators to support various services such as cloud computing. Consequently, high electricity bills, as well as negative environmental implications (e.g., CO2 emission and global warming) come along. In this thesis, we first propose a novel electricity bill capping algorithm that not only minimizes the electricity cost, but also enforces a cost budget on the monthly bill for cloud-scale data centers that impact the power markets. Our solution first explicitly models the impacts of the power demands induced by cloud-scale data centers on …

Optimizing Maize Planting Date, Plant Population, And Fertilizer Application Rates For Lesotho Subsistence Farmers, Matthew Ryan Bruns

Masters Theses

Due to perpetually low yields, smallholder farmers throughout Southern Africa plow increasingly large plots of land in an attempt to increase their household food security. However, extensive agriculture further depresses yields because expensive inputs are spread over a larger area, provides little soil cover, and results in high soil erosion rates. To address these challenges, farmers in the Kingdom of Lesotho are beginning to adopt conservation agriculture (CA) systems. Under CA and conventional tillage systems the optimum plant population, planting date, and fertilizer rates are unknown. The effects of field preparation, planting date, weed control strategies, plant populations, and nitrogen …

The Dissemination And Effective Use Of Physics Education Research In Undergraduate Instruction, Trevor Stefanick

Masters Theses

Based on the results of a national survey of physics faculty, a set of interviews was conducted of 70 physics faculty from a diverse set of institutions. The interviews included questions about the dissemination and effective use of curricula and instructional strategies based on Physics Education Research (PER), focused to obtain recommendations to the PER community that might help to spread the use of these PER-based materials. Approximately half of the interviews (those with faculty who indicated knowledge about or use of Peer Instruction) have been previously analyzed. This project is the analysis of the 38 interviews that were conducted …

Synthesis Of 1,1-Dialkyhydrazines And Their Hydroxyl Radical Degradation In Aqueous Environments, Benjamin F. Strong

Masters Theses

Determination of hydroxyl radical rate constants are essential to ensure adequate degradation of contaminants in wastewater. Hydrazines are an important class of organic contaminants and are the focus of this research. Ten 1,1-dialkylhydrazines are synthesized by the zinc reduction of the corresponding N-nitrosamines. Their hydroxyl radical rate constants are determined using the linear accelerator at the Notre Dame Radiation Laboratory at pH 4, 7, and 10.

Their rate constants are found to depend on the protonation state of the molecule. At pH 4 the molecules are fully protonated and hydrogen atom abstraction is favored from the alkyl chains. At …

Reservoir Characterization And Enhanced Oil Recovery Potential In Middle Devonian Dundee Limestone Reservoirs, Michigan Basin, Usa, Abrahim Abduslam

Masters Theses

Middle Devonian Rogers City and subjacent Dundee Limestone formations have combined oil production in excess of 375 MMBO. In general, hydrocarbon production occurs in two distinct reservoir types: 1) bottom water drive, fractured dolomite reservoirs in the Rogers City and 2) gas expansion drive, depositional facies controlled limestone reservoirs of the Dundee.

The main objective of this study is to evaluate the enhanced oil recovery (EOR) potential in Dundee Limestone reservoirs on the basis of detailed geological reservoir characterization in several fields in the Michigan Basin. Seven main depositional facies were identified from core studies in six fields. Three of …

Investigating The Evolution Of Two Southern Appalachian Terrane Boundaries And A Plutonic Complex: Tectonic Implications Of Structural, Geochemical, And Geochronologic Studies In The Central Georgia Inner Piedmont, Christopher William Howard

Masters Theses

Detailed geologic mapping in the central Georgia Inner Piedmont has revealed a plutonic complex in the Cat Square terrane (CST) between the Brindle Creek and Towaliga faults ~80 km SE of Atlanta. The complex has an area ~235 km² and is composed of two distinct mappable granitoids. The High Falls Granite (HFG) is a Siluro-Devonian (424-380 Ma) porphyritic granite with characteristic blocky microcline megacrysts. The Indian Springs Granite (ISG, 313-299 Ma) has an equigranular, fine- to medium-grained texture. Some foliation in the HFG is concordant with regional trends, but a relict magmatic or secondary tectonic foliation was also observed …

Higher-Order Corrections In Effective Theory Of Deformed Nuclei, Jialin Zhang

Masters Theses

The low-energy excitation bands of open-shell heavy nuclei have been accounted for by collective motion of the constituting nucleons. Macroscopically, heavy nuclei can be looked upon as deformed rotors undergoing surface vibration and rotation. Traditionally, deformed nuclei are described within the Bohr-Mottelson geometric model or the interacting boson model. An effective theory that exploits spontaneous symmetry breaking has recently been developed for axially deformed nuclei. It describes the rotational and vibrational degrees of freedom in terms of Nambu-Goldstone bosons and quadrupole phonons respectively, with a power counting based on their different energy scales. A systematic way to construct the rotationally …

Studies Of Regolithic Vestan Samples: Brecciated Eucrites And Howardites, Sheryl A. Singerling

Masters Theses

Brecciated eucrites and howardites represent samples of the regolith of asteroid 4 Vesta. As such, they are a valuable source of data for understanding the products of surface alteration. Two different processes are investigated here: impact mixing of comminuted rocks to produce regolith samples, and formation of glasses in the regolith.

Chapter 1 describes four newly discovered eucrite breccias: three presumably paired meteorites, all named NWA 6105, and NWA 6106. For each meteorite, major- and minor-element compositions of minerals were determined using the electron microprobe. Pyroxene Fe-Mn co-variations and bulk-rock oxygen isotope compositions confirm their classification as eucrites. Variations in …

Utility Of 1,2,4-Triazoles As Catalysts For Orr In Fuel Cells, Chinmay Nagesh Dabke

Masters Theses

The Oxygen Reduction Reaction (ORR) taking place at the cathode of a fuel cell is catalyzed by Platinum due to its high activity and good stability in the acidic polymer electrolyte membrane fuel cell (PEMFC) environment. Due to its prohibitive cost and limited reserves, it is not practical to use Pt as the catalyst for mass commercialization. By taking inspiration from nature, we have devised a series of catalysts which will help in replacing Platinum at the cathode in commercial fuel cells. To gauge the activity of various ligands, metal salts and carbon surfaces, adsorbed experiments were carried out and …

Design And Synthesis Of Boronic Acid-Based Sensors For Microarray Analysis And Fret-Detection To Study Carbohydrates, Yilin Wang

Masters Theses

Carbohydrates play significant roles in various biological and pathological processes such as cancer metastasis and inflammation. They participate in various signaling pathways and are able to bind to a litany of biological receptors such as proteins and viruses. Biologists have known for decades that the structure of glycans changes with the onset of cancer and inflammation. Due to these important activities, carbohydrate sensing has long been a focus of research. One example of such a carbohydrate sensor is boronic acid-based sensors. Boronic acid-based sensors are of particular interest due to their selectivity for 1,2- or 1,3-diols. A variety of techniques …