Physical Sciences and Mathematics Commons^™

Investigating Gulf Coast Aquifer System: Stratigraphy Reconstruction, Inverse Modeling, And Groundwater Stress Assessment, Shuo Yang

LSU Doctoral Dissertations

The Mississippi Embayment aquifer system (MEAS) and the Coastal Lowlands aquifer system (CLAS) provide substantial groundwater resources for human activities in the U.S. Gulf Coastal Plain. However, the overexploitation has led to groundwater depletion in the MEAS and the CLAS, threatening sustainable groundwater use. Such concern highlights the crucial need for an advanced understanding of stratigraphy and groundwater in these aquifer systems, which is essential for effective regional groundwater management. This dissertation presents a comprehensive investigation of MEAS and CLAS in the Louisiana and southwestern Mississippi region, encompassing three fundamental dimensions: stratigraphy reconstruction, groundwater modeling, and groundwater stress assessments. A …

Sedimentary Processes And Instability On The Mississippi River Delta Front Near The Wreck Of The Ss Virginia, Nathan Figueredo

LSU Doctoral Dissertations

Multi-cores and piston cores were collected seaward of the Mississippi River Delta’s Southwest Pass at ~80 m water depth in 2017 to better understand sedimentary characteristics and processes on the Mississippi River Delta Front (MRDF) in the vicinity of the SS Virginia shipwreck, and to support marine archeological research. Core analyses were performed to inform our understanding of the dynamics of sediment motion in the study area through radionuclide activity (²¹⁰Pb and ¹³⁷Cs), volume frequency of grain size, bulk density, and fabric (X-Radiography). Sediment accumulation rates (SAR), calculated from multi-core ²¹⁰Pb activity are 0.22 - 0.29 …

Visual Analytics And Modeling Of Materials Property Data, Diwas Bhattarai

LSU Doctoral Dissertations

Due to significant advancements in experimental and computational techniques, materials data are abundant. To facilitate data-driven research, it calls for a system for managing and sharing data and supporting a set of tools for effective data analysis and modeling. Generally, a given material property M can be considered as a multivariate data problem. The dimensions of M are the values of the property itself, the conditions (pressure P, temperature T, and multi-component composition X) that control the concerned property, and relevant metadata I (source, date).

Here we present a comprehensive database considering both experimental and computational sources …

Hydrogeologic Investigation Of A Covered Karst Terrain, Joseph Peter Honings

LSU Doctoral Dissertations

Increasing demand for water for agricultural use within the Dougherty Plain of the Southeastern United States has depleted surface water bodies. In karstic landscapes, such as the Dougherty Plain in southwest Georgia where the linkages between surface and ground waters are close, there is a need to understand the physical characteristics of the subsurface that allow these close linkages. Having a better understanding of the subsurface characteristics will aid numerical modeling efforts that underpin policy decisions and economic analyses. Two common features on this karstic landscape are draws and geographically isolated wetlands. Using LiDAR, aerial imagery, and ground-penetrating radar, this …

Competitive Sorption And Transport Of Heavy Metals In Soil And Mn Oxide-Coated Sand, Joshua Tyler Padilla

LSU Doctoral Dissertations

This study investigated the competitive sorption of Ni, Pb, and Zn as well as synergistic interactions between Ni and phosphate (P) in soils and Mn oxide-coated sand. During stirred-flow experiments, the sorption of heavy metal cations by Olivier soil was mutually reduced when applied simultaneously. When applied consecutively, the cation of higher affinity was able to displace the cation of lower affinity from the soil surface, however, no evidence for the reverse case was observed. A novel general exchange kinetics model was able to correctly describe such displacement. Competition between Ni and Zn mutually increased mobility in Olivier and Windsor …

A Numerical Investigation Of Flood And Sediment Dynamics Over The Coastal Watersheds During Hurricane Events, Dongxiao Yin

LSU Doctoral Dissertations

Landfalling tropical cyclones can cause catastrophic floods and sediment disturbance over the coastal watersheds. This study aims to unravel the contribution of different processes to hurricane-induced flooding, to assess the uncertainties in flood modelling and forecasting, and to advance the techniques in sediment simulation over coastal watersheds during hurricanes.

First, I examined the hydrometeorology and hydrology of Hurricane Florence (2018) induced inland flooding. My results suggest that the slow motion in combination with the “L-shaped” path was the most distinctive feature of the hurricane that incurred catastrophic and widespread rainfall and flooding over the Cape Fear River Basin (CFRB).

Second, …

Floodplain Forests Vegetation Dynamics Driven By Water Deficits Across Scales, Nga Thanh Nguyen

LSU Doctoral Dissertations

Restoration of floodplain ecosystems relies on identifying the most crucial hydrologic process which has been altered by human and climate. Flooding is a well-known dominant hydrologic process for floodplain ecosystems, but surprisingly little is known about drought's role in structuring ecosystems. In addition, several issues remained uncertain, such as the nature of drought within floodplains and the sensitivity of floodplain species-specific growth to climate. These gaps of understanding have in common in missing observations of mechanistic pathways of vegetation response to water deficits at multiple scales in time and space.Generally, this research contributed to floodplain management by expanding our understanding …

Palynology And Paleoclimatology Of The Chicxulub Impact Crater In The Early Paleogene, Vann Smith

LSU Doctoral Dissertations

At the end of the Cretaceous Period, a large bolide impacted the Earth and formed the Chicxulub impact crater in the Yucatán Peninsula, Mexico. In 2016, International Ocean Discovery Program (IODP) Expedition 364 Site M0077 drilled into the buried peak ring of the crater, recovering a marine Paleocene to early Eocene post-impact section deposited on top of the impact breccia. Palynological analysis of 195 samples from the post-impact section has yielded the first pre-Holocene vegetational record from inside the Chicxulub impact crater and the first palynological record of the recovery of life following the end-Cretaceous mass extinction from inside the …

Computer Simulations Of Diffusional Isotope Effects And Dynamical Properties Of Silicate Melts, Haiyang Luo

LSU Doctoral Dissertations

Silicate melts have served as transport agents in the chemical and thermal evolution of Earth. Diffusional isotope effect in silicate melts is the key to interpret isotope variations in lots of geological samples. Isotopic mass dependence of diffusion is commonly expressed as (Di/Dj)=(mj/mi)^β, where Di and Dj are diffusion coefficients of two isotopes whose masses are mi and mj. However, how the dimensionless empirical parameter β depends on temperature, pressure, and composition remains poorly constrained. Viscosity and electrical conductivity are two fundamental dynamical properties of silicate melts needed to constrain melt distribution in Earth's interior but remain unclear for most …

Simulation Of Compound Flood Events In Low-Gradient Coastal Watershed, Felix Luis Santiago-Collazo

LSU Doctoral Dissertations

Low-gradient coastal watersheds are susceptible to flooding caused by various flows such as rainfall, tides, and storm surge. Compound flooding occurs when at least two of these mechanisms happen simultaneously or in close succession. Different inundation models, observed data, and/or a combination of these are coupled through varying techniques involving one-way, loosely, tightly, or fully coupled approaches to assess compound flooding. This study presents a one-dimensional (1-D), fully coupled compound inundation model based on the Shallow Water equations. This model approach simultaneously simulates the free water surface variations in the ocean domain (i.e., tide and storm surge modeling), rainfall-runoff in …

Characterizing The Northern Hemisphere Circumpolar Vortex Through Space And Time, Nazla Bushra

LSU Doctoral Dissertations

This hemispheric-scale, steering atmospheric circulation represented by the circumpolar vortices (CPVs) are the middle- and upper-tropospheric wind belts circumnavigating the poles. Variability in the CPV area, shape, and position are important topics in geoenvironmental sciences because of the many links to environmental features. However, a means of characterizing the CPV has remained elusive. The goal of this research is to (i) identify the Northern Hemisphere CPV (NHCPV) and its morphometric characteristics, (ii) understand the daily characteristics of NHCPV area and circularity over time, (iii) identify and analyze spatiotemporal variability in the NHCPV’s centroid, and (iv) analyze how CPV features relate …

Modeling Hydraulic Fracturing Initiation And Propagation In Porous Rock Formationsl, Chang Huang

LSU Doctoral Dissertations

Hydraulic fracturing has long been introduced to the oil and gas industry since the early nineteenth century for both reservoir characterization and reservoir stimulation. Despite the progress made in the last two decades, many challenges still have not been tackled regarding not only the propagation problem but also the initiation problem due to its complexity. The dissertation is divided into two stages, i.e., before and after fracture initiation. The first stage of the research aimed at improving the accuracy in solving the poro-mechanical response of wellbore during fluid injection before a tensile fracture occurs, which is crucial to determine the …

Hydro-Morphodynamics Of Sandy Coastal Embayments, Shamim Murshid

LSU Doctoral Dissertations

This dissertation investigates the hydro-morphodynamics of two major components of a sandy coastal environment: tidal inlets and embayment shorelines. In the first study, I focused on the evolution of inlet geometry by compiling and analyzing a database with 226 inlets worldwide with a special attention given to their width to depth ratio (or aspect ratio). I found that the aspect ratio has a weak dependency on tidal range and wave height, and they lie in different ranges for three types of tidal inlets: engineered, natural single-thread, and natural compound. I also developed a 2D hydro-morphodynamic model of an idealized barrier-inlet …

Application Of Compound-Specific Stable Isotopes And Molecular Biomarkers To Paleoclimatic And Paleoecological Reconstructions, Mingqiu Hou

LSU Doctoral Dissertations

Compound-specific stable isotope analysis and biomarker-based paleothermometry have been increasingly applied to for paleoclimate and paleoecology studies. The first project aims to reconstruct the paleoclimate in the Qaidam Basin during the last glacial period. Qaidam Basin in the Northern Tibetan Plateau is a critical eolian factory located at a unique geographic location that links the Westerlies and the Asian summer monsoons. However, how the interactions of two climatic systems influence the paleohydrology that in turn impacts the eolian production in the Qaidam Basin has been seldom explored. Our compound-specific hydrogen isotope and U^K ₃₇ temperature data found that the …

The Medium-Term And Event-Scale Tropical Cyclone-Driven Morphodynamics Of A Vulnerable Barrier System With Emphasis On The Role Of Backbarrier Wetlands, Cody Lee Johnson I

LSU Doctoral Dissertations

Coastal mainland barriers and barrier islands provide the first line of defense against oceanic and meteorological forces. Coastal morphological change, which may degrade these barrier's defensive capabilities, occurs over a range of time scales, from geological epochs (>1000 years) to hours and seconds. Coastal morphological change at a vulnerable, but economically strategic, barrier system---the Caminada-Moreau Headlands, Louisiana---is investigated in terms of tropical cyclone impacts and their effects over a 15 year LIDAR survey time series. Analysis of the barrier's three-dimensional morphodynamics at medium-term (decadal) time scales reveals that, while subaerial volume was approximately conserved through time, the impact of …

Characterization Of Shallow Subsurface Hydrology In Large Fine-Grained Floodplains, Mary Grace Lemon

LSU Doctoral Dissertations

Floodplains are hydrologically dynamic, receiving water from overbank events, hyporheic flows, local precipitation, and regional groundwater sources. These sources are variously important contributors to the heterogeneous floodplain water pool that includes matrix water in soil micropores, mobile water in soil macropores, groundwater below the rooting zone, ephemeral to seasonal surface storage, and permanent surface water features such as oxbow lakes, sloughs, and other secondary channels. All sources may be ecologically relevant for floodplain vegetation, but the exact roles of each source in both controlling soil water and shallow groundwater recharge and in controlling floodplain water drainage are not well understood, …

Sediment Transport And Geomorphological Evolution In The Transgressive Ship Shoal, Louisiana: Insights From Geophysical Observation, Modeling, And Machine Learning Studies, Haoran Liu

LSU Doctoral Dissertations

Ship Shoal has been a high-priority target sand resource for dredging activities to restore the eroding barrier islands in Louisiana, USA. Many studies have been performed in Ship Shoal in recent decades, but our knowledge of temporal and spatial variations of sediment transport and post-dredge morphology is still limited. The objectives of this dissertation are to explore the sediment infilling process, the spatial and temporal evolution of the morphology of dredge pits near and on Ship Shoal by using multiple methods. Scientific methods used in this study include (a) geophysical observation using bathymetry, side-scan and subbottom technique, (b) sediment transport …

Investigating Geochemical Processes Of Fluid-Rock Interactions On Materials Related To Energy And Environment, Zelong Zhang

LSU Doctoral Dissertations

Understanding the potential processes of radionuclides released from nuclear waste forms is essential to the safe disposal and containment of nuclear waste. Iodoapatite, a potential waste form for radioiodine, was chosen as a model system to examine the impact by common aqueous anions on iodine release processes. Four semi-dynamic leaching tests were performed using 0.1 mol/L NaCl, Na₂CO₃, Na₃PO₄, and Na₂SO₄ solutions respectively under 90 °C, 1 bar, fixed S/V ratio 5/m (sample surface area to solution volume), and with 24-hour replacement of the leaching solutions. Solution analysis and …

Benthic Nitrogen Dynamics In Response To Deltaic Succession, Anthropogenic Fertilization And Hurricane Events In An Emerging Coastal Deltaic Floodplain Within The Mississippi River Delta Plain, Song Li

LSU Doctoral Dissertations

Increasing concentrations of nitrogenous fertilizer (NO₃^-) in rivers have potentially altered benthic nitrogen (N) cycling in coastal deltaic floodplains at the continental margins of major rivers. Here I evaluated the N removal capacity of a newly emergent coastal deltaic floodplain [Wax Lake Delta (WLD)] within the Mississippi River Delta Plain using continuous flow-through incubations. I investigated the response of benthic N dynamics in WLD to deltaic succession, anthropogenic fertilization and hurricane events. The estimated annual NO₃^- removal of 896 Mg N yr^-1 in WLD accounts for 10 to 27% of total NO₃^{- …}

Physical And Biological Factors Controlling The Fate Of Nitrate In A Louisiana Coastal Deltaic Floodplain, Alexandra Christensen

LSU Doctoral Dissertations

The Mississippi River Delta is threatened by a growing pressure to support large human populations in the United States both with food production, navigation systems, and urban development in the Mississippi River Basin. Nitrate-nitrogen load in the Mississippi River, up to 100 Tg N yr^-1 from agricultural and urban runoff, leads to phytoplankton blooms and hypoxia across the Louisiana continental shelf, creating dead zones of low dissolved oxygen threatening a significant commercial fishery. Along the coast and river corridors, floodplain ecosystems have the capacity to retain and remove nitrate. This dissertation explores the role of productive, actively growing coastal …

The Long-Term Outlook Of The Mississippi-Atchafalaya Bifurcation: A Convergence Of Engineering, Economics, And Deltaic Evolution, Thomas Mitchell Andrus

LSU Doctoral Dissertations

The most recent and currently active delta lobe of the Mississippi River (MR) is the Atchafalaya-Wax Lake lobe, which was initiated approximately 400 years ago as a result of MR stream capture by the Atchafalaya River (AR). This capture process accelerated in the early to mid-1900s but further progress was prevented by construction and operation of the Old River Control Structure (ORCS) Complex. Many recent studies indicate that MR system below the ORCS is on a retreating geologic trajectory due to contributing factors such as sea level rise, subsidence, faulting, and declining hydraulic stream power. Diversions along the Lower MR …

Element Transport In A River-Lake Continuum Across Forest-Dominated Landscapes: A Case Study In Central Louisiana, Zhen Xu

LSU Doctoral Dissertations

Studying the biogeochemical connectivity between rivers and lakes can help us understand their ecological and environmental impacts within a drainage basin, which is especially true for forest watersheds that play a vital role in provisioning freshwater services to ecosystems and downstream communities. This dissertation research consists of three interconnected studies with the overarching goal of discerning the connectivity of elements in a river-lake continuum across forest-dominated landscapes. These studies utilized water samples and in situ measurements collected from the Little River-Catahoula Lake continuum in the subtropical Louisiana, USA at monthly intervals during 2015-2016 and 1978-2008 historical water quality, hydrological and …

Ecogeomorphic Evolution Of Muddy Coastlines: How Biota On A Range Of Scales, From Microscopic Biofilms To Landscape-Scale Vegetation Zonation Patterns, Interact With Physical Processes, Kendall Cole

LSU Doctoral Dissertations

Coastal wetland ecosystems are inherently interdisciplinary; in these spaces, the physical forces of wind and water meet to interact with stabilizing and fortifying vegetation and biota, as well as mud. The combination of these factors build and sustain wetland ecosystems and without the complex feedbacks, they would cease to exist. In this dissertation, I present three studies that focus on ecogeomorphic interactions within coastal wetlands on a range of scales, from microscopic to the entire landscape and highlight the importance of these interactions when predicting future coastal change. The first study examined how biofilms, matrixes of photosynthetic diatoms and their …

Assessment Of Soil Protein And Refractory Soil Organic Matter Across Two Chronosequences Of Newly Developing Marshes In Coastal Louisiana, Usa, Stuart Alexander Mcclellan

LSU Doctoral Dissertations

The impacts of sea-level rise and hydrologic manipulation are threatening the stability of coastal marshes throughout the world, thereby increasing the potential for re-mineralization of soil organic matter (SOM) in these systems. Such threats have prompted marsh restoration efforts, particularly in coastal Louisiana, yet it is unclear how the slowly decomposing (refractory) and quickly decomposing (labile) fractions of SOM may be differentially affected by different approaches to marsh restoration. Additionally, otherwise labile compounds may accumulate in the soil via a range of protective mechanisms, including rapid burial and association with organic compounds that are thought to enhance soil aggregation, such …

Field Investigation On Point Bar Dynamics And Planform Evolution In Meandering Rivers, Taylor Rowley

LSU Doctoral Dissertations

Point bars are prominent features in meandering rivers, yet our understanding of the complex interactions among channel morphology, three-dimensional flow structure, and depositional processes associated with modern and active point bars remains incomplete. Thus, the goal of this research is to characterize the morphology, three-dimensional flow structure, and depositional packages associated with point bars along a series of bends with different curvature and channel planform through detailed field measurements and relate to previous literature and current conceptual models.

Chapter 3 investigates the morphology of point bars by comparing estimates of channel curvature to channel and point bar characteristics including width, …

Exploring Planetary Surfaces With Remote Sensing, Donald R. Hood

LSU Doctoral Dissertations

Aside from Earth, Mars is the most well-explored planetary body in our solar system. Much has been learned about its geologic past including a history of volcanism, ice ages, and potentially long-lasting liquid water. Much of this knowledge of Mars comes from remote observations of the surface and atmosphere from Mars-orbiting satellites. Such remote observations remain the only way to examine the entirety of Mars’ surface as rovers and landers can only examine small areas. The chapters of this work cover three projects that explore the surface of Mars through a variety of remote sensing methods.

In chapter 1, Gamma-ray …

Neogene Chemical Weathering And Provenance Records Of The Western Himalaya Preserved In The Arabian Sea, Peng Zhou

LSU Doctoral Dissertations

Some tectonic models for the Himalaya emphasize the importance of surface processes in controlling the structural evolution. To investigate this tectonic–climatic interactions, and the weathering and erosion of the western Himalaya, International Ocean Discovery Program (IODP) Expedition 355 drilled two sites (site U1456 and U1457) in Laxmi Basin, which located in the Eastern Arabian Sea. In my research project, I plan to use a series of geochemical and geochronological methods on the sediment samples from the cores of these two sites, and sediments from an industrial borehole Indus Marine A-1, which near the Indus river mouth, to reconstruct a climatic …

Development Of A Tunable Platform For The Study Of Geomacromolecular Matrices Using Controlled Radical Polymerization, Arjun Pandey

LSU Doctoral Dissertations

Soil is an important environmental component, and the study of soil processes have many practical implications such as improvement in agriculture, mitigation of climate change etc. The widespread use of Agricultural Chemicals (ACs) in modern agriculture has resulted in adverse effects in environment and human health mostly through contamination into food and water sources. Study of fate, bioavailability, and transport of ACs involves molecular level understanding of their interactions with soil. This can be challenging due to complex and heterogeneous nature of soil. One common approach used is the correlation of macroscopic properties of soil, (e.g. sorption) with empirical parameters …

Investigation Of Subsurface Stratigraphy And Groundwater Dynamics In The Mississippi River Delta, An Li

LSU Doctoral Dissertations

The Mississippi River Delta (MRD) is socioeconomically important to the state of Louisiana and the United States. Various types of land-water system data have been collected in the MRD. However, very few efforts have been made to utilize these datasets in modeling regional stratigraphy and groundwater dynamics in the MRD, especially for the upper 50 m of the depth. In this interval of depth, the Mississippi River and surrounding interdistributary bays intensively interact with the groundwater system. The lack of knowledge in regional stratigraphy and groundwater dynamics hinder an understanding of how hydrogeological setting affects processes such as surface-groundwater interaction, …

A Numerical Investigation Of Sediment Dynamics In The Northern Gulf Of Mexico In Connection With Hurricanes, Fluid Mud, Climate Change, And Biogeochemical Cycling, Zhengchen Zang

LSU Doctoral Dissertations

Sediment transport and deposition in marginal seas is jointly controlled by many factors including hydrodynamics, fluvial inputs, and the characteristics of sediment particles. This dissertation study employs the coupled ocean-atmosphere-wave-and-sediment transport modeling system (COAWST) to investigate the mechanism of sediment transport in the northern Gulf of Mexico (nGoM) on different temporal scales, as well as its interaction with biogeochemical processes.

First of all, a three-way coupled (atmosphere-wave-ocean) hurricane model reproduced the hydro- and sediment dynamics during hurricane Gustav (2008). Intensive alongshore and offshore currents were simulated on the eastern/western sectors of hurricane track, respectively. High suspended sediment concentration (SSC) was …