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Ultraviolet Photoinitiated On-Fiber Copolymerization Of Ionic Liquid Sorbent Coatings For Headspace And Direct Immersion Solid-Phase Microextraction, Tien D. Ho, Honglian Yu, William T.S. Cole, Jared L. Anderson
Ultraviolet Photoinitiated On-Fiber Copolymerization Of Ionic Liquid Sorbent Coatings For Headspace And Direct Immersion Solid-Phase Microextraction, Tien D. Ho, Honglian Yu, William T.S. Cole, Jared L. Anderson
Jared L. Anderson
A high-throughput method for the production of solid-phase microextraction (SPME) sorbent coatings via ultraviolet (UV) photoinitiated copolymerization of ionic liquid (IL) monomers on a fused silica support is described. The copolymerization of monocationic and dicationic IL cross-linkers was performed “on-fiber” using UV initiated free radical polymerization. Mixtures composed of various amounts of the IL cross-linker, UV initiator (DAROCUR 1173), and IL monomer were dip-coated onto an etched and derivatized fused silica support and placed in a high-capacity UV reactor. The method requires no organic dispersive solvent and is much more rapid compared to traditional methods in which polymeric ionic liquid …
Ionic Liquids Containing The Tris(Pentafluoroethyl)Trifluorophosphate Anion: A New Class Of Highly Selective And Ultra Hydrophobic Solvents For The Extraction Of Polycyclic Aromatic Hydrocarbons Using Single Drop Microextraction, Cong Yao, William R. Pitner, Jared L. Anderson
Ionic Liquids Containing The Tris(Pentafluoroethyl)Trifluorophosphate Anion: A New Class Of Highly Selective And Ultra Hydrophobic Solvents For The Extraction Of Polycyclic Aromatic Hydrocarbons Using Single Drop Microextraction, Cong Yao, William R. Pitner, Jared L. Anderson
Jared L. Anderson
A new class of ionic liquids (ILs) containing the tris(pentafluoroethyl)trifluorophosphate (FAP) anion are paired with imidazolium, phosphonium, and pyrrolidinium cations and used as extraction solvents in direct immersion single drop microextraction (SDME) studies coupled to high performance liquid chromatography (HPLC). The selectivity and sensitivity of the extraction method can be tuned and manipulated by varying the cationic component of the IL, thereby providing larger enrichment factors for a variety of analytes, including polycyclic aromatic hydrocarbons (PAHs). Compared to other hydrophobic ILs containing the hexafluorophosphate (PF6−) and bis[(trifluoromethyl)sulfonyl]imide (NTf2−) anions, FAP-based ILs are significantly more hydrophobic and hydrolytically stable permitting them …