Physical Sciences and Mathematics Commons^™

Micro-Topological Effects On Redox-Sensitive Nutrient Availability Of Manganese, Iron, Sulfur, And Phosphorus, Lindsey C. Ruhl

Graduate College Dissertations and Theses

The working hypothesis for this study was that small elevation differences in field depressions affect the availability of redox active nutrients because the bottom of the depression remains waterlogged and in reducing conditions longer than the edge of the depression. Mn, Fe, S and P availabilities were investigated in a field depression with a 20 meter radius and 0.5 meter depth on a flood-prone, organic vegetable farm. One depression (Depression 1) was sampled seven times during three field seasons (May 2012-June 2014). The last two dates included sampling in an additional three depressions to allow a comparison among depressions on …

Lake Trout Spawning Site Use In Lake Champlain & The Development Of The Binomial Rolling Residence Test, Victoria M. Pinheiro

Graduate College Dissertations and Theses

Lake trout populations were extirpated from the lower four Great Lakes by 1960 and from Lake Champlain by 1900. The decline of lake trout populations fueled a wave of restoration-based research that spanned the Great Lakes and filled in many of the gaps in our knowledge of lake trout behavior and ecology. However, remarkably little is known about lake trout spawning behavior, even less about sex-specific differences in spawning site use. Lake trout use specific spawning sites, and may return to the same site year after year. More males are caught on spawning sites than females and are present at …

Exchange Mechanisms In Macroscopic Ordered Organic Magnetic Semiconductors, Naveen Rawat

Graduate College Dissertations and Theses

Small molecule organic semiconductors such as phthalocyanines and their derivatives represent a very interesting alternative to inorganic semiconductor materials for the development of flexible electronic devices such as organic thin field effect transistors, organic Light Emitting Diodes and photo-voltaic cells. Phthalocyanine molecules can easily accommodate a variety of metal atoms as well in the central core of the molecule, resulting in wide range of magnetic properties. Exploration of optical properties of organic crystalline semiconductors thin films is challenging due to sub-micron grain sizes and the presence of numerous structural defects, disorder and grain boundaries. However, this can be overcome by …

The Role Of Motivation And Curriculum In Shaping Pro-Sustainable Attitudes And Behaviors In Students, Kathleen Bamford

Graduate College Dissertations and Theses

Sustainability is an area of growing pertinence as our future and the future of our planet depends on its acceptance and application. Determining patterns in pro-sustainable attitudes and behaviors, and revealing motivations behind these behaviors have important implications for the future of sustainability education. The primary objective of this study is to discover the relationships between educational experience and sustainability attitudes and behaviors in elementary school students. A secondary objective is to determine the motivation behind pro-sustainability behaviors and to establish the role this plays in educational programs. The study utilizes mixed methodology through two modes of data collection: 1. …

New Insights For The Future Of Lake Champlain: Practical Approaches And Useful Tools For Grappling With Uncertainty And Weighing Trade-Offs In Watershed Management., Philip Halteman

Graduate College Dissertations and Theses

The effective management of non-point source nutrient pollution continues to prove elusive. Though the scientific literature is unequivocal that all anthropogenic land uses contribute to non-point source (NPS) pollution, variable levels of contribution over time and across location and complex relationships between cost and effect make finding technologically effective management solutions difficult. In addition, these solutions are implemented in a world of scarce resources, diverse and often competing concerns and values, and intense public scrutiny. Clearly, making the best possible decision about how to manage NPS pollution under these conditions is not simple. My overarching goal was to develop and …

Monitor: Automation Tools For Landscape-Scale Acoustic Monitoring, Jonathan Edward Katz

Graduate College Dissertations and Theses

Climate change coupled with land-use change will likely alter habitats and affect state parameters of the animal populations that dwell in them. Affected parameters are anticipated to include site occupancy and abundance, population range, and phenophase cycles (e.g., arrival dates on breeding grounds for migrant bird species). Detecting these changes will require monitoring many sites for many years, a process that is well suited for an automated system. We developed and tested monitoR, an R package that is designed for long-term, multi-taxa automated passive acoustic monitoring programs. monitoR correctly identified presence for black-throated green warbler and ovenbird in 64% and …

Reverse Engineering The Human Brain: An Evolutionary Computation Approach To The Analysis Of Fmri, Nicholas Allgaier

Graduate College Dissertations and Theses

The field of neuroimaging has truly become data rich, and as such, novel analytical methods capable of gleaning meaningful information from large stores of imaging data are in high demand. Those methods that might also be applicable on the level of individual subjects, and thus potentially useful clinically, are of special interest. In this dissertation we introduce just such a method, called nonlinear functional mapping (NFM), and demonstrate its application in the analysis of resting state fMRI (functional Magnetic Resonance Imaging) from a 242-subject subset of the IMAGEN project, a European study of risk-taking behavior in adolescents that includes longitudinal …

Discourse As Social Process In Outdoor Recreation And Natural Resource Management: Arguing, Constructing, And Performing, Monika Marie Derrien

Graduate College Dissertations and Theses

This dissertation examines the language-based, discursive processes through which meanings and experiences are socially constituted in outdoor recreation and natural resource environments. Language use and discourse are seen as interactive, constructive processes, approached through the theoretical perspectives of argumentation, social constructionism, and performance.

Three qualitative studies, based in data collected at Acadia National Park and forest-related sites throughout Vermont, comprise this dissertation. The first study uses rhetorical analysis to examine the ways National Park Service managers and community leaders argue for the meanings and management of dark night skies in and around Acadia. The second study examines how national park …

How Wildlife Information, Recreation Involvement And Demographic Characteristics Influence Public Acceptability Of Development, Jessica Espenshade

Graduate College Dissertations and Theses

Increasing development like roads and houses will alter the future landscape of Vermont. Development provides important resources for people and society, but also results in consequences for wildlife and opportunities for recreation. Managing development requires information on the public's acceptability of development and how acceptability is shaped by information on various consequences. In this study, I examined three questions: 1) What is the public's acceptability of development? 2) Does wildlife information influence public acceptability of development and 3) Is the maximum amount of acceptable development influenced by views about wildlife, involvement in recreation, and demographic factors? I surveyed 9,000 households …

An Embodied Approach To Evolving Robust Visual Classifiers, Karol Zieba

Graduate College Dissertations and Theses

From the very creation of the term by Czech writer Karel Capek in 1921, a "robot" has been synonymous with an artificial agent possessing a powerful body and cogitating mind. While the fields of Artificial Intelligence (AI) and Robotics have made progress into the creation of such an android, the goal of a cogitating robot remains firmly outside the reach of our technological capabilities. Cognition has proved to be far more complex than early AI practitioners envisioned. Current methods in Machine Learning have achieved remarkable successes in image categorization through the use of deep learning. However, when presented with novel …

Investigation Of A Ring Fragmentation Reaction For The Synthesis Of Tethered Aldehyde Ynones And Medium Sized Cyclic Ynones And Ynolides, Ali Bayir

Graduate College Dissertations and Theses

The fragmentation of γ-silyloxy-β-hydroxy-α-diazoesters to provide tethered aldehyde ynoates was discovered and developed in Prof. Brewer's laboratory. This reaction is a Lewis acid mediated heterolytic cleavage of the Cβ-γ bond of a γ-silyloxy-β-hydroxy-α-diazocarbonyl functional group array contained in a ring compound.

This dissertation describes a further study of this ring fragmentation reaction and application of this fragmentation to the preparation of synthetically useful organic molecules. The purpose of this dissertation work was three fold. The first objective was to extend this ring fragmentation reaction to the synthesis of tethered aldehyde ynones by fragmenting various γ-silyloxy-β-hydroxy-α-diazo ketone compounds. The second objective …

Early Adoption Dynamics Of Private Sustainability Governance Initiatives: A Case Study Of The Marine Cultured-Pearl Industry, Julie Nash

Graduate College Dissertations and Theses

We are witnessing a time of unprecedented human impact on the natural environment. Coral reefs, one of the most biologically diverse and productive ecosystems, are at the forefront of enduring these human impacts. Despite widespread recognition of coral reef degradation, counter measures have not reached a scale to offset the threat. The magnitude of this and other environmental issues call for a deeper understanding of the role the private sector can play in sustainable development.

In response to environmental pressures and the shortcomings of global-scale governance, private sustainability governance initiatives have developed. In the last decade, these initiatives have flourished, …

Get Real: An Examination Of The Real Food Challenge At The University Of Vermont, Jennifer Porter

Graduate College Dissertations and Theses

The Real Food Challenge (RFC) is a national student movement that is trying to harness student power to shift $1 billion'roughly 20% of college and university food budgets across the country towards local, ecologically sound, fair, and humane food sources, what they call "real" food, by 2020. The University of Vermont (UVM) was the fifth university in the country to sign the Real Food Campus Commitment, pledging to shift at least 20% of its own food budget towards "real" food by 2020. The purpose of this thesis is to evaluate the implementation of the Real Food Campus Commitment at UVM. …

Numerical Simulations Of Reacting Flow In An Inductively Coupled Plasma Torch, Maximilian Dougherty

Graduate College Dissertations and Theses

In the design of a thermal protection system for atmospheric entry, aerothermal heating presents a major impediment to efficient heat shield design. Recombination of atomic species in the boundary layer results in highly exothermic surface-catalyzed recombination reactions and an increase in the heat flux experienced at the surface. The degree to which these reactions increase the surface heat flux is partly a function of the heat shield material. Characterization of the catalytic behavior of these materials takes place in experimental facilities, however there is a dearth of detailed computational models for the fluid dynamic and chemical behavior of such facilities. …

The Molecular Evolution Of Non-Coding Dna And Population Ecology Of The Spiny Softshell Turtle (Apalone Spinifera) In Lake Champlain, Lucas Edward Bernacki

Graduate College Dissertations and Theses

ABSTRACT

Spiny softshell turtles (Apalone spinifera) occur at the northwest limit of their range in Lake Champlain. This species, although widespread across North America, is listed as threatened in Vermont due to habitat destruction and disturbances of anthropogenic origin. The population of spiny softshell turtles in Lake Champlain is isolated from other North American populations and is considered as an independent management unit. Efforts to obtain information on the biology of spiny softshell turtles in Lake Champlain precede 1936 with conservation measures being initiated in 1987.

Methods of studying spiny softshell turtles in Lake Champlain have included direct …

Management By Crisis: Land Trust Conservation Engagement And Methods In Vermont, Louise Sopher Lintilhac

Graduate College Dissertations and Theses

Planning a future for the landscapes we live in can be a daunting challenge for many communities in Vermont. Conservation initiatives affect the quality of life for all community members and can be difficult if not impossible to change in the event of poor planning. Through examining stakeholder relationships with land trusts I have explored the complexities of planning processes used by land trusts in Vermont for conservation initiatives

The study involved one statewide land trust, the Vermont Land Trust, and two community land trusts, the Stowe Land Trust and the Duxbury Land Trust. I used qualitative methods including document …

Using Stable Isotope Analysis To Estimate Black Bear (Ursus Americanus) Diet In Vermont, Eliese Antona Dykstra

Graduate College Dissertations and Theses

The black bear (Ursus americanus) is an iconic species with cultural, economic and ecological importance in Vermont, USA. Bears exhibit a highly variable diet, and few studies have described bear diet in the state. Information on diet may provide insight into foraging behavior, thus allowing managers to better assess patterns of human-bear conflict. My objectives were to estimate the relative contribution of food items to bear diet and how factors including sex, habitat, food availability, and nuisance status describe patterns of consumption. I collected samples from bears and major food groups including C3 plants, white-tailed deer (Odocoileus virginianus), corn (Zea …

Ordering And Reordering: Using Heffter Arrays To Biembed Complete Graphs, Amelia Mattern

Graduate College Dissertations and Theses

In this paper we extend the study of Heffter arrays and the biembedding of graphs on orientable surfaces first discussed by Archdeacon in 2014. We begin with the definitions of Heffter systems, Heffter arrays, and their relationship to orientable biembeddings through current graphs. We then focus on two specific cases. We first prove the existence of embeddings for every K_(6n+1) with every edge on a face of size 3 and a face of size n. We next present partial results for biembedding K_(10n+1) with every edge on a face of size 5 and a face of size n. Finally, we …

The Interplay Between Deformation And Metamorphism During Strain Localization In The Lower Crust: Insights From Fiordland, New Zealand, Kathryn Elise Dianiska

Graduate College Dissertations and Theses

In this thesis, I present field, microstructural, and Electron Backscatter Diffraction (EBSD) analyses of rock fabrics from high strain zones in exposures of lower crustal Cretaceous plutons at Breaksea Entrance, Fiordland, New Zealand. The interplay between deformation and metamorphism occurs across multiple scales at the root of a continental arc. I show a series of steps in which retrogressive metamorphism is linked to the accommodation of deformation.

I define three main phases of deformation and metamorphism at Breaksea Entrance. The first phase (D1) involved emplacement of dioritic to gabbroic plutons at depths up to 60 km. The second phase (D2) …

Subsistence Under The Canopy: Agroecology, Livelihoods And Food Sovereignty Among Coffee Communities In Chiapas, Mexico, Margarita Fernandez

Graduate College Dissertations and Theses

One of the most pressing challenges facing the world today is how to sustainably feed a growing population while conserving the ecosystem services we depend on. Coffee landscapes are an important site for research on agrifood systems because they reflect global-scale dynamics surrounding conservation and livelihood development. Within them, we find both what is broken in our global agrifood system, as well as the grassroots struggles that strive to change the system by building socio-ecologically resilient, sustainable livelihoods. Research shows that smallholder shade coffee farmers steward high biodiversity and provide essential ecosystem services. At the same time, studies in the …

Using The Past As The Key To The Present: Informing Coastal Resource Management With Geologic Records, Benjamin D. Dejong

Graduate College Dissertations and Theses

Rising sea levels present an ongoing threat to communities and resources around the Chesapeake Bay, east coast, USA, where tide gauges indicate that the relative rise of sea level is approximately twice the rate of average, eustatic sea-level rise. This has significantly compromised the health and viability of salt marsh habitat on the Eastern Shore during the 20th century, and the biologists who are charged with managing coastal resources in the coming decades need to understand the nature and causes of high rates of regional sea-level rise to develop suitable adaptation plans.

Dated geologic deposits and geophysical models suggest that …

Earthworm Presence In Northern Forests: Impact On Distribution Of Soil Carbon Within Aggregate Fractions, Meghan Elizabeth Knowles

Graduate College Dissertations and Theses

Growing concerns over climate change is driving research aimed at determining ways of retaining soil carbon (C) within managed northeastern forests. Earthworms are exotic to the state of Vermont and the current extent of earthworm community presence in the state's forests, as well as the long term impact these communities will have on soil C storage, is still unknown. Current research suggests that earthworms have conflicting effects on the C cycle of soils, simultaneously enhancing mineralization through soil mixing, while protecting C through the stabilization of microaggregate (mA) structures. The mA soil fraction represents a pool of physically stable structures …

The Impact Of Engagement With Community Supported Agriculture On Human Attitude Towards The Sustainable Food Movement, Ariana Margarita Cano

Graduate College Dissertations and Theses

With a total of 164 community supported agriculture programs (CSA), Vermont is leading the "locavore" movement in the United States, ranked number one in the country with the most CSAs and Food Hubs per capita. ("Locavore Index," 2013)

CSAs have a large positive impact on reducing carbon emissions, advancing local economic growth, and promoting healthy lifestyles of consumers. The purpose of this study is to explore the overall experience of individuals in comparison to their current social norm, individual attitudes, identity, and intentions of change, and understand any change overtime in their individual attitude and behavior.

Attitude change was measured …

Sustainable Agriculture In Vermont: Economics Of Climate Change Best Management Practices And The Complexity Of Consumer Perceptions Of Raw Milk, Alexander Paul Helling

Graduate College Dissertations and Theses

Changing weather patterns, the declining social fabric of rural communities, and economic uncertainty increasingly pose challenges to Vermont communities. The socially and environmentally embedded production practices within sustainable agriculture present a potential solution to these problems. In order to make the most of the potential benefits of these practices society must maximize their adoption. This requires an understanding of both farmer adoption of these practices and consumer perceptions of the resulting food products. This thesis contributes two original articles on sustainable agriculture through the analysis of factors driving both farmer adoption and consumer perceptions of products and practices often thought …

Using Mutli Criteria Decision Analysis To Develop Sustainability Assessment Tools: Biomass Supply Chains, Deandra Marie Perruccio

Graduate College Dissertations and Theses

Energy access remains a significant challenge in nations lacking access to resources and strong infrastructure systems, creating barriers to economic development and to increased standards of living. Small scale biomass gasification energy (BGE) systems have been developed to meet energy needs in rural areas, creating synergies between agricultural and agro-forestry systems through utilization of biomass feedstock for energy generation. The sustainability of such systems requires sophisticated planning and coordination of the biomass supply chain.

The goal of this thesis is to investigate and improve structural and process related characteristics of sustainability assessments for small scale bio-energy systems, specifically focusing on …

Biological Indicators Of Compost-Mediated Disease Suppression Against The Soilborne Plant Pathogen Rhizoctonia Solani, Lynn Fang

Graduate College Dissertations and Theses

Compost can suppress soilborne plant pathogens that cause significant damage on globally important food crops. However, reports of plant pathogen suppression are inconsistent likely because there are no established standards for feedstock material, application rate, and maturity age upon application. Excellent results can be achieved in greenhouse trials, but field applications are much less reliable. Disease suppression occurs through the activity of biocontrol organisms (direct antagonism), and general microbial competition. Biocontrol species are hypothesized to colonize the pile during the curing phase, but single species may not be as important as microbial consortia. Substrate composition during maturation may give rise …

The Interaction Mechanisms Of A Screw Dislocation With A Defective Coherent Twin Boundary In Copper, Qiongjiali Fang

Graduate College Dissertations and Theses

Σ3{111} coherent twin boundary (CTB) in face-centered-cubic (FCC) metals and alloys have been regarded as an efficient way to simultaneously increase strength and ductility at the nanoscale. Extensive study of dislocation-CTB interaction has been carried out by a combination of computer simulations, experiments and continuum theory. Most of them, however, are based on the perfect CTB assumption. A recent study [Wang YM, Sansoz F, LaGrange T, et al. Defective twin boundaries in nanotwinned metals. Nat Mater. 2013;12(8):697-702.] has revealed the existence of intrinsic kink-like defects in CTBs of nanotwinned copper through nanodiffraction mapping technique, and has confirmed the effect of …

Effects Of Pcb Contamination On The Environment And The Cultural Integrity Of The St. Regis Mohawk Tribe In The Mohawk Nation Of Akwesasne, Kim Ellen Mcrae

Graduate College Dissertations and Theses

The following research project examines the effects of polychlorinated biphenyls (PCBs) on the environment and the cultural integrity of the St. Regis Mohawk tribe in the Mohawk Nation of Akwesasne. This indigenous community has been subjected to widespread long-term industrial pollution from nearby toxic hazardous waste facilities and Superfund sites.

The Mohawk Nation of Akwesasne has the distinction of being the only tribe whose officially recognized territory straddles the border between the United States and Canada. Using qualitative methodologies, coupled with an interdisciplinary framework, this study successfully engages with Akwesasne community members to explore such issues as bottom-up approaches to …

Pedagogical Praxis Models In Sustainability Education: A Focus On Food Systems And Environment, Karen Lynn Nordstrom

Graduate College Dissertations and Theses

As societies embrace notions of sustainability, there is an increasing interest in how to best educate students about these concepts. The field of sustainability education (SE) is an approach that has been developed to address this concern. SE frameworks seek to integrate into curricular contents and formats within campus learning environments, in order to systematically improve upon approaches and services developed to support student learning and development. My research offers insight into the relationships between the philosophical principles and praxes of sustainability education, with the aim to inform educators on how best to prepare students to address complex sustainability issues. …

The Status Of Stonecats (Noturus Flavus) In The Laplatte And Missisquoi Rivers, Vermont, Elizabeth Puchala

Graduate College Dissertations and Theses

Stonecats (Noturus flavus, Rafinesque 1818) are designated as a Vermont state-listed endangered species because their known distribution is limited to two systems, the LaPlatte and Missisquoi rivers. The restricted distribution and lack of knowledge on abundance in either river is cause for concern in the continued survival of these populations. Based on the capture numbers and large size range of individuals, we predicted that the population in the LaPlatte River, which provides quality benthic habitat, is stable. However, the Missisquoi River population has the potential for increased intermittent mortalities from two sources, lampricide (3-trifluoromethyl-4-nitrophenol) treatment every four years and dewatering …