Open Access. Powered by Scholars. Published by Universities.®

Physical Sciences and Mathematics Commons

Open Access. Powered by Scholars. Published by Universities.®

Articles 1 - 4 of 4

Full-Text Articles in Physical Sciences and Mathematics

Observation Of An Oxygen Isotope Effect In Yba2Cu3O7, Kevin J. Leary, Hans Conrad Zur Loye, Steven W. Keller, Tanya A. Faltens, William K. Ham, James N. Michaels, Angelica M. Stacy Sep 1987

Observation Of An Oxygen Isotope Effect In Yba2Cu3O7, Kevin J. Leary, Hans Conrad Zur Loye, Steven W. Keller, Tanya A. Faltens, William K. Ham, James N. Michaels, Angelica M. Stacy

Faculty Publications

A small decrease in Tc of 0.3 K to 0.5 K is observed when as much as 90% of the 16O in YBa2Cu3O7 is substituted with18O. This result is consistent with our observation that there is an oxygen isotope effect in La1.85Sr0.15CuO4, but in contrast with previous reports that there is no isotope effect for YBa2Cu3O7. This new result suggests that phonons play an important role in the electron-pairing mechanism in YBa2Cu3O7.


Observation Of An Isotope Shift In The Superconducting Transition Temperature Of La1.85Sr0.15Cuo4, Tanya A. Faltens, William K. Ham, Steven W. Keller, Kevin J. Leary, James N. Michaels, Angelica M. Stacy, Hans Conrad Zur Loye, Donald E. Morris, T W. Barbee Iii, Marvin L. Cohen, Cohen S. Hoen, A Zettl Aug 1987

Observation Of An Isotope Shift In The Superconducting Transition Temperature Of La1.85Sr0.15Cuo4, Tanya A. Faltens, William K. Ham, Steven W. Keller, Kevin J. Leary, James N. Michaels, Angelica M. Stacy, Hans Conrad Zur Loye, Donald E. Morris, T W. Barbee Iii, Marvin L. Cohen, Cohen S. Hoen, A Zettl

Faculty Publications

An oxygen isotope shift is observed in superconducting La1.85Sr0.15CuO4 when 18O is substituted partially for 16O; the superconducting transition temperature Tc is lowered by 0.3 to 1.0 K in different samples. We examine these results using conventioanl phonon-mediated BCS theory and conclude that, for La1.85Sr0.15CuO4, phonons play an important role in the pairing mechanism.


Search For Isotope Effect In Superconducting Y-Ba-Cu-O, L C. Bourne, M F. Crommie, A Zettl, Hans Conrad Zur Loye, S W. Keller, K L. Leary, Angelica M. Stacy, K J. Chang, Marvin L. Cohen, Donald E. Morris Jun 1987

Search For Isotope Effect In Superconducting Y-Ba-Cu-O, L C. Bourne, M F. Crommie, A Zettl, Hans Conrad Zur Loye, S W. Keller, K L. Leary, Angelica M. Stacy, K J. Chang, Marvin L. Cohen, Donald E. Morris

Faculty Publications

An isotope effect has been searched for in the high-Tc, superconductor YBa2Cu307 —b through substitution of 180 for 16O. No shift in the superconducting transition temperature T, is observed by electrical resistivity or magnetic susceptibility measurements. We discuss the implications of this result for mechanisms of superconductivity in the high-T, oxides.


Effect Of Phosphate On The Kinetics And Specificity Of Glycation Of Protein, Nancy G. Watkins, Carolyn I. Neglia-Fisher, Daniel G. Dyer, Suzanne R. Thorpe, John W. Baynes May 1987

Effect Of Phosphate On The Kinetics And Specificity Of Glycation Of Protein, Nancy G. Watkins, Carolyn I. Neglia-Fisher, Daniel G. Dyer, Suzanne R. Thorpe, John W. Baynes

Faculty Publications

The glycation (nonenzymatic glycosylation) of several proteins was studied in various buffiner os rder to assess the effects of buffering ions on the kinetics and specificity of glycation of protein. Incubation of RNase with glucose in phosphate buffer resulted in inactivation of the enzyme because of preferential modification of lysine residues ino r near the activsei te. In contrast, in the cationic buffers, 3-(N-morpholino)propanesulfonic acid and 3-(N-tris(hydroxymethyl)rnethylamino)- 2-hydroxypropanesulfonica cid, the kineticso f glycation of RNase were decreased 2- to 3-fold, there was a decrease in glycation of active site versus peripheral lysines, and the enzyme was resistant to inactivation by …