Physical Sciences and Mathematics Commons^™

The Fate Of Carbonate Rocks During Hypervelocity Impacts: Case Studies From Three Impact Structures On Earth, Nicolas D. Garroni

Electronic Thesis and Dissertation Repository

Approximately 28% of all hypervelocity impact structures discovered on Earth exist in a carbonate-dominated target sequence. Despite decades of research, how carbonate rocks and minerals react to shock metamorphism is still poorly understood. In this contribution, three impact structures on Earth were studied to determine the effects of shock metamorphism on carbonate minerals: Chicxulub, Crooked Creek and Jebel Waqf as Suwwan.

At Chicxulub, carbonates from the impact-melt bearing breccia of drill core, M0077A were characterized petrographically and geochemically. Calcite was the only carbonate mineral present and is abundant throughout the impact breccia in five distinct varieties: limestone clasts …

Oxygen Speciation In Potassium Silicate And Potassium Aluminosilicate Glasses: Insights From X-Ray Photoelectron Spectroscopy, Ryan Sawyer

Electronic Thesis and Dissertation Repository

In a geological context, glasses are useful analogues for silicate melts as they are more readily studied in the laboratory using a wide range of techniques that are impractical for molten liquids. Understanding the structure of binary silicate glasses can help us understand more about the magmatic processes that affect terrestrial planetary bodies.

Potassium silicate glasses ranging in composition from 10 mol% to 35 mol% K₂O were studied using X-ray Photoelectron Spectroscopy (XPS). From high resolution O 1s XPS spectra, Bridging Oxygen (BO) mole fractions were calculated and compared with those of previous ²⁹Si MAS NMR studies. …

White Micas As A Tool For Tracking Pegmatite Evolution And Its Use In Li Exploration. A Case Study Of Wekusko Lake, Manitoba, Canada., David N. Benn

Electronic Thesis and Dissertation Repository

The Wekusko Lake pegmatite field is part of the Green Bay Group of pegmatites located near Snow Lake, Manitoba, Canada. Within this field, there are at least 13 spodumene-bearing pegmatites of varying degrees of mineralization. The abundance of white micas and the chemical affinity to incorporate Li and other trace elements into its crystalline structure makes white micas an ideal indicator mineral. The evolution of a melt can be tracked using trace elements in white mica. The K/Rb ratio vs Cs is used to determine a link between increasing evolution and increased Li contents of both the white mica and …

Stable Carbon And Oxygen Isotopes Of Early Silurian Pentameride Brachiopods From Québec, Ontario, And Nunavut, And Paleoenvironmental Implications, Jordan N. Siewnarine

Electronic Thesis and Dissertation Repository

Analysis of low-Mg calcite brachiopod shells for δ¹⁸O and δ¹³C signatures provide quantitative independent geochemical data for paleoenvironmental interpretations. We analyzed 59 brachiopod shells from lower Silurian carbonate rocks of Anticosti Island, the Hudson Bay Lowlands and Niagara regions for spaciotemporal isotopic trends for the early Silurian. Screening tests using scanning electron microscopy, cathodoluminescence and trace element analysis demonstrate exceptional preservation, suggesting retention of primary isotopic values.

δ¹³C and δ¹⁸O values of shells range from 0.2‰ to 2.9‰ and -6.9‰ to -4.3‰ (VPDB), respectively. Temporally, increases in δ¹³C and δ …

Investigation Of Sulphide-Poor Gold Mineralization At The Deep A Zone, Kiena Complex, Québec, Stephanie A. Kobylinski

Electronic Thesis and Dissertation Repository

The Kiena Complex is located halfway between Malartic and Val d’Or in Québec, within the Abitibi Greenstone belt in the Superior Province. This study examined mineralization at the Kiena Complex using detailed core logging, geochemical analysis of wall rock, petrography, EPMA, and gold deportment studies. The analysis and interpretations indicate that the unique sulphide-poor gold-rich quartz veins of the Deep A Zone at the Kiena Complex contain 500 μm²) are located at the contact of quartz and corroded albite grains, and fine gold grains (5-500 μm²) are hosted within the corroded albite.

Effects Of Glutamine Deamidation On The Oxygen Isotope Compositions Of Bone Collagen, Curtis W. Russell

Electronic Thesis and Dissertation Repository

The oxygen (O) isotope composition of mammalian collagen has the potential to provide information about the drinking water and hence geographic location and climate during the life of modern and ancient animals. An accurate and reproducible O-isotope analysis of collagen, however, has been elusive. Here, the O-isotope compositions of collagen from cortical bone of four megaherbivores were compared using two extraction procedures: the traditional Longin (HCl) method and the less commonly employed EDTA method. Preservation of O-isotope compositions was evaluated by measuring collagen peptide-chain masses, specifically the glutamine deamidation level (GDL). The EDTA method yielded collagen with a GDL of …

In Situ Study Of Geological Fluid Inclusions Using 23na Nuclear Magnetic Resonance Spectroscopy, Stephen Pilar

Electronic Thesis and Dissertation Repository

²³Na Magic Angle Spinning Solid State Nuclear Magnetic Resonance (MAS SS NMR) spectroscopy has been used to study natural geological samples of halite, fluorite, and quartz to evaluate the efficacy of NMR spectroscopy for in situ fluid inclusion analysis. NaCl calibration standards yielded a strong linear correlation (R²=0.9919) for salinity, albeit only over a ~1 ppm breadth of chemical shift. Fluid inclusions were successfully identified in all three types of minerals studied using MAS NMR. Chemical analysis with Inductively Coupled Plasma -- Mass Spectrometry (ICP-MS) was employed to quantify elemental contaminants in halite samples. Powder X-Ray Diffraction …

Organic Geochemistry, Organic Petrography And Basin Modelling Of The Upper Cretaceous Second White Specks And Upper Belle Fourche Alloformations In The Western Canada Foreland Basin, Mailyng Angelica Aviles

Electronic Thesis and Dissertation Repository

The Second White Specks is an unconventional shale play in the Western Canada Foreland Basin, endowed with over 450 billion barrels of light oil in place. Inconsistent production performance, however, has hindered its economic viability as a resource play. One potential explanation for erratic production behavior, on local and regional scales, is heterogeneous distribution of retained oil charge in the source rock. This study focuses on the analysis of geochemical properties and thermal history of the organic matter to assess lateral variability in generated hydrocarbon in the Second White Specks.

The methodology comprised characterization of the organic matter integrating organic …

Hydrothermal Alteration Footprint Of The Monument Bay Project, Manitoba, Canada, Juliana Casali

Electronic Thesis and Dissertation Repository

The Monument Bay (MB) project is a greenstone hosted gold deposit, located in NE Manitoba. Previous studies show significant gold grades in the area. This research aims to characterize and delineate the mineralogical and geochemical characteristics of the hydrothermal footprint and mineralization of MB. Combined synchrotron X-ray fluorescence, synchrotron X-ray diffraction, petrography, and electron microprobe techniques were used to support this study. Results indicate sericite and carbonate are the main hydrothermal alteration minerals with homogeneity in their mineralogical, textural, and geochemical characteristics across the deposit. Also, a strong relationship between Au, sericite alteration, and arsenopyrite grains is observed associating the …

Geometallurgy And Gold Mineralization Of The Monument Bay Project, Stull Lake Greenstone Belt, Manitoba, Canada, Chunyi Hao

Electronic Thesis and Dissertation Repository

The Monument Bay Project is located in the Archean Stull Lake Greenstone Belt, in Northern Manitoba, Canada. This thesis focuses on the geometallurgy and gold mineralization of the Monument Bay Deposit in order to better understand the multiple gold mineralizing events and provide a pathfinder to gold mineralization. Traditional microscopy is used in combination with geochemical and mineralogical analytical techniques (Electron Probe Microanalysis (EPMA) and Energy-dispersive X-ray Spectroscopy (EDS)/(WDS) element map) and synchrotron geochemical techniques (synchrotron X-ray Diffraction (SR-XRD), synchrotron micro X-ray fluorescence (SR-µXRF) mapping, X-ray Absorption Near-edge Structure (XANES) Spectroscopy). Metallic gold (Au⁰) exists as free gold …

Reconstructing Carbon Dynamics Of Alpine And Temperate Zone Lakes Using Stable Isotopic Analysis, Rebecca M. Doyle

Electronic Thesis and Dissertation Repository

Lake sediments integrate signals from the catchment, atmosphere and water column, offering a unique window through which to view changes in the carbon cycle. Carbon dynamics in lakes are changing due to nitrogen loading and anthropogenic climate warming (ACW), threatening the water quality of lakes. This thesis identifies how the carbon dynamics of lakes have responded to anthropogenically-driven forcings by comparing pre- and post- AD 1850 records preserved in lake sediments. First, the carbon dynamics of Barry Lake (Ontario, Canada), a low-elevation temperate lake, are investigated. Effective moisture (the net of water inputs and evaporation) is reconstructed using the carbon …

Impact Of Interlayer Cation Composition And Strongly Bound Water On Smectite ẟ²H, As Determined By A Modified Tcea Method, Nadine J. Kanik

Electronic Thesis and Dissertation Repository

Interlayer cation composition and cation hydration enthalpy can potentially affect the excess hydrogen-yield and δ²H of smectitic clays. Complexities arise from condensed atmospheric water adsorbed on the clay, as it constitutes a potential additional source of hydrogen when attempting to measure the δ²H of structural OH groups. To approach this problem, the δ²H of different cation-saturated, dried forms of six Clay Minerals Society Source Clay smectites were measured. A modified sample drying and on-line High-Temperature-Conversion-Elemental-Analysis (TCEA) Continuous-Flow-Isotope-Ratio-Mass-Spectrometry protocol, facilitated isotopic measurements. A stronger interlayer cation hydration enthalpy (Ca²⁺>Na⁺>K⁺), …

Determining Geological Controls On Nutrient Availability At Different Depths In The Soils Of The Pelee Island Winery, Lindsay M. Blythe

Electronic Thesis and Dissertation Repository

Terroir describes a sense of place that can give a unique flavour to wines grown in different environments. We explored the role of soil in the terroir at Canada’s most southern vineyard, Pelee Island Winery. This study examined the abundance of major nutrients, trace and rare earth elements of minerals and plant extractable nutrients from 19 soils across the vineyard to a depth of 2 m. We found that bedrock does not influence the element content of Pelee Island soils, the parent materials of the soils are tills and there are geochemical, mineralogical and grain size differences between the two …

The Relationship Between Visible Gold And Arsenopyrite At The Orenada Zone 4 Deposit, Val D'Or, Quebec, Cassandra Powell

Electronic Thesis and Dissertation Repository

The Orenada Zone 4 deposit is an Archean orogenic gold deposit situated southeast of Val d’Or, Québec in the southeastern Abitibi Greenstone Belt. It is located directly within the Cadillac-Larder-Lake Deformation Zone. Mineralization is hosted within a volcanoclastic horizon of the Cadillac Group where two distinct facies were defined. Both facies underwent a pervasive sericite-chlorite-carbonate±albite alteration assemblage that predates gold mineralization. Gold is associated with two generation of auriferous quartz-carbonate-tourmaline veins and within fractures of corroded arsenopyrite grains, located proximal to the vein walls. A LA-ICP-MS study determined that neither textural type of arsenopyrite displayed refractory gold. Therefore, gold was …

Characterization Of Impact Melt Rocks And Hydrothermal Mineralization At The Haughton Impact Structure, Devon Island, Canada: An Investigation Of Impacts Into Carbonate Targets, Cassandra L. Marion

Electronic Thesis and Dissertation Repository

Impact cratering is a fundamental and ubiquitous geological process on all solid planetary bodies in our solar system. Impacts into carbonate-rich sedimentary target rocks on Earth are still poorly understood. The fate of carbonates during impact, in particular whether they undergo melting or decomposition, is actively debated. The dominant process is significant as decomposition would cause severe climatic effects due to release of large amounts of carbon dioxide into the atmosphere. At the root of the problem is the difficulty to distinguish and characterize the genesis of the variety of impactite carbonates produced. The Haughton impact structure in the Canadian …

Paleoproductivity Of Late Holocene Lake Huron, Jamal Khaled Nigim

Electronic Thesis and Dissertation Repository

The paleolimnology of North America’s Lake Huron is described using lead-210 dating, mineralogy, magnetic susceptibility, total organic carbon (TOC), total nitrogen (TN), carbon:nitrogen (C/N) ratio, grain size, and the δ¹³C_OM and δ¹⁵N_TN of organic matter. Sediment cores from Lake Huron’s 6 depositional basins and Georgian Bay span the Medieval Warm Period, Little Ice Age, and Canadian-European settlement. The main organic matter source is lacustrine algae, as indicated by δ¹³C_OM, δ¹⁵N_TN and C/N. Prior to the 19th century, primary production changes are reflected only by small variations in …

Rare-Metal Alkaline Granite From The Arabian Shield, Saudi Arabia, Abdullah A. Aseri

Electronic Thesis and Dissertation Repository

Mineral deposits of high field strength elements (HFSE) and rare earth elements (REE) are commonly within granites that have experienced strong post-magmatic alterations. There has been a long debate on whether the mineralization is due to magmatic and/or hydrothermal processes. The Arabian Shield hosts several economical rare-metal alkaline granites that are poorly understood. This work aims to evaluate the nature of the mineralization in three rare-metal granites from the Arabian Shield, showing distinct mineralization styles ranging between disseminated mineralization at Al-Ghurayyah, pegmatite and hematized granite at Jabal Sayid, and quartz veins at Dyaheen.

The granites from all three areas are …

Shock Effects Recorded By The U-Pb Radiometric System In Zircons Of Apollo 17 Impact Breccias And By Raman Spectroscopy In Enstatite Meteorites, Bidong Zhang

Electronic Thesis and Dissertation Repository

Impact cratering processes and formations are ubiquitous on the rocky planets within the Solar System. The Earth-Moon system was formed by a massive planetary impact, and numerous impacts afterwards significantly reshaped the topography and lithology of the Moon surface. This dissertation focuses on studying some specific geochemical, geochronological, and geophysical signatures of impact processes preserved in lunar rocks and asteroidal meteorites.

The zircon U-Pb radiometric system is one of the most reliable geochronometers in measuring geological time. Recently, unsupported radiogenic Pb enrichment has been reported to compromise the accuracy and precision of zircon U-Pb geochronometer in terrestrial rocks. In Chapter …

Sm-Nd, Lu-Hf, And Mn-Cr Isotope Geochemistry Of Achondrite Meteorites: Implications For The Formation Reservoirs Of Differentiated Planetesimals, Zhiguo Guo

Electronic Thesis and Dissertation Repository

Accretion and differentiation of planetesimals are critical steps of planetary formation. By studying achondrite meteorites, we can bring further geochemical and chronological constraints on the source and composition of materials and their evolution throughout the protoplanetary disk. Major and trace element analyses for mineral and whole-rock compositions and high-precision isotopic compositions for the short- and long-lived radiochronometers ⁵³Mn-⁵³Cr, ^147,146Sm-^143,142Nd and ¹⁷⁶Lu-¹⁷⁶Hf are reported for two eucrites, two diogenites, and three ungrouped achondrites. Of these, NWA 12338 is a newly classified ungrouped achondrite with an anomalously higher Δ¹⁷O than mean …

Ni And Fe Isotope Fractionation During Weathering And The Formation Of Ni Laterite Ore Deposits In The Philippines, Congxi Zhu

Electronic Thesis and Dissertation Repository

Weathering processes on Ni-rich ultramafic rocks in tropical areas produce laterites that become exploitable for Ni mining. To better understand these processes, samples were collected stratigraphically with water samples from several Ni mines in the Philippines and studied for Ni and Fe isotope compositions. This study found that Ni isotope fractionation takes place during the formation of Ni-enriched minerals (goethite), when light Ni isotopes are preferentially incorporated into new minerals formed, leaving heavy Ni isotopes in groundwater. The Δ⁶⁰Ni_{Limonite-Bedrock} is up to -0.19 ± 0.32‰. Even though Fe is partitioned with redox state change during these reactions, …

Using Stable Isotopes To Understand Survival Versus Extinction Of Late Pleistocene Muskoxen, Stephanie Mabee

Electronic Thesis and Dissertation Repository

This thesis uses stable isotopes to investigate the adaptive advantages of Ovibos moschatus, a muskox, relative to now-extinct Pleistocene megafauna in eastern Beringia (Yukon Territory and Alaska), including another muskox Bootherium bombifrons. Ecological niches were defined for Ovibos and Bootherium using stable carbon and nitrogen isotope compositions of bone collagen. Plant remains trapped in modern Ovibos molars were used to determine the carbon and nitrogen isotope collagen-diet discrimination factors, which were then applied to ancient specimens. Ovibos possessed larger isotopic – and hence ecological – niches than Bootherium across eastern Beringian sites. The larger niche suggests that Ovibos …

Calcium Isotopes In The Saint Agatha Kettle Lake Deposits Of Southern Ontario, Emma-Dawn Ferguson

Electronic Thesis and Dissertation Repository

The St. Agatha kettle lake deposits, ON, Canada, contain a thick section of endogenic marl and coeval shelly fauna. Marl accumulation occurred from ~13,500 to ~8,200 cal yrs BP. This study examines controls on marl and shell δ^44/42Ca, element ratios (Mg, Fe, and Ba), δ¹⁸O, δ¹³C, and ⁸⁷Sr/⁸⁶Sr ratios of marl calcite, shell aragonite, groundwater, and bedrock as proxies for paleolacustrine conditions. Results for Interval A (532.0 to 475.0cm) indicates a cooler, wetter climate, lower primary lake productivity and higher lake levels. Interval B (475.0 to 345.0cm) marks the onset of …

Impact Cratering Processes On The Earth And Moon: Meteorites, Complex Craters, And The Origin Of The Moon, Patrick Hill

Electronic Thesis and Dissertation Repository

This thesis seeks to understand the mechanism of hypervelocity impacts, lunar origin and geology, and stable isotope techniques and its application to lunar material. Three lunar regolith breccias, Dhofar 1673, Dhofar 1983, and Dhofar 1984, were examined. The petrography, mineralogy, isotope chemistry, and bulk chemistry of these meteorites were quantified to investigate their origin. The chemistry of the impact melt rock and bulk chemical analysis suggests sourcing from either the Feldspathic or Outer Feldspathic Highland Terranes. Given the similarities in the meteorites, and the proximal location of each find (within 500 m), this thesis proposes strong evidence for their pairing. …

Understanding New Trends On Gold Mineralization At The Yellowknife City Gold Project, Northwest Territories, Using Synchrotron X-Ray Spectroscopy, Ramjay Jude L. Botor

Electronic Thesis and Dissertation Repository

The Yellowknife City Gold Project (YCGP) currently encompasses 780 sq. km of contiguous land north, south and east of the city of Yellowknife. The project lies in the prolific Archean north-south trending Yellowknife Greenstone Belt, a suite of mafic and felsic volcanics and greywacke turbidites overlying a gneissic basement. Exploration and drilling efforts have been focused along 70 km of strike length on the southern and northern extensions of the mineralized shear zones and quartz veins associated with the past-producing high-grade Con (6.1 Moz @ 16.1 g/t Au) and Giant (8.1 Moz @ 16.0 g/t Au) gold mines.

Synchrotron X-ray …

Stable Carbon Isotope Variations Of Organic Matter And N-Alkanes In The Plant-Bulk Soil-Clay Fraction Continuum, Alana Crump

Electronic Thesis and Dissertation Repository

Organic matter (OM) adsorbed to clay minerals in soils can have C/N similar to lacustrine algal matter. Accurate source identification of OM in sediments is crucial for predicting future climate change impacts in the Great Lakes region. We analyzed C/N, carbon-isotope compositions, n-alkane abundances and compound-specific carbon-isotope compositions of vegetation, soil, and OM associated with clay minerals in soils and glacial till in order to determine if (i) OM associated with clay minerals has unique signatures distinct from lacustrine algal matter and is traceable to modern vegetation, and (ii) if these signatures have been transferred to and preserved in …

Trace Element Geochemistry And Nd-Sr Isotope Systematics Of Scheelite From The Thunder Creek And 144 Gap Deposits, Timmins, Ontario: Implications For Timing And Genesis Of Gold, Annika Van Kessel

Electronic Thesis and Dissertation Repository

The age of the youngest gold event at the Timmins West Mine is unknown. Scheelite geochemistry and geochronology at the TWM were constrained using WDS and EDS mapping, LA-ICPMS and MC-ICPMS analytical techniques. Trace element analyses by LA-ICPMS revealed scheelites mineralized from a common and oxidized fluid. Samarium-Neodymium isotopic analyses of 15 scheelite grains yielded a linear regression isochron with a corresponding age of 2587 +/- 49 Ma (MSWD = 2.5) and εNdi, calculated from CHUR, of 1.01 ± 0.11 (2SD). A second internal isochron from a single scheelite grain yielded an age of 2516 +/- 88 Ma (MSWD = …

A Targeted Investigation Of The Upper Contact Unit Of The Sudbury Igneous Complex In The North Range, Sudbury Impact Structure, Canada, Lindsay E. Debono

Electronic Thesis and Dissertation Repository

The Sudbury Igneous Complex (SIC) represents the remnant of a crystalline impact melt sheet of the Sudbury impact structure; and is historically and presently a strategic exploration target sustaining the region's prolific mining camp. In order to better understand the SIC, it is critical to investigate the chilled upper contact of the SIC, which has historically received little recognition. Through field observations, whole rock geochemistry, petrography, and electron microprobe analysis, this study concludes that the SIC upper contact is in fact extensive across the North Range of the SIC. Additionally, the geochemistry of the SIC units, offset dykes, and upper …

Characterization Of Kelyphite Rims: Relevance To Diamond Exploration, Mallory N.G. Metcalf

Electronic Thesis and Dissertation Repository

A detailed investigation into the mineralogy and chemistry of kelyphitic rims/veins on garnets was conducted using µXRD, EPMA and Raman spectroscopy for a suite of samples from economic and non-economic kimberlites in Canada and South Africa. Mineralogy demonstrates the influence of metasomatic fluids during the reactions which produced kelyphite in all localities and was used to propose P-T regions where kelyphite could have formed. Using chemical analyses of host garnets and the mineralogy obtained for kelyphite, modified chemical reactions representing Types 1 and 2 kelyphite are provided to describe kelyphite reactions in open systems. Elastically-strained secondary garnet is common in …

An Investigation Of Hydrothermal Veins Along The Foy Offset Dyke, Sudbury Impact Structure, Ontario, Sarah Ann Codyre

Electronic Thesis and Dissertation Repository

A multi-stage hydrothermal system is related to the 1.85 Ga Sudbury impact structure. This system began in the Sudbury Igneous Complex (SIC) and radiated outward along the offset dykes. Through the combination of orientation measurements of veins in the field, petrography and geochemistry of these veins, this study has determined that there are four types of hydrothermal epidote-quartz veins categorized by their orientation, petrography and geochemistry. This study discovered that there are general trends with increasing distance from the SIC along the Foy Offset Dyke. From this it can be concluded that this is in fact SIC-driven hydrothermal event not …

Study On The Surface Features Of Preg-Robbing Carbonaceous Matter During Oxidation Treatment, Mana Pourdasht

Electronic Thesis and Dissertation Repository

Carbonaceous gold ores have the ability to adsorb gold (I) cyanide from leach solutions during processing. This phenomenon, known as preg-robbing, is responsible for poor recoveries as the carbonaceous materials of the ore compete with activated carbon used during the leaching and adsorption phase of processing. Chemical oxidation of carbonaceous materials by different reagents has been utilized to investigate and compare the mechanism of Au (CN)₂ adsorption onto carbonaceous materials prior to and following the treatment.

The procedure for characterization of the carbonaceous materials (plain and modified) in the sample combines the use of several analytical techniques and test …