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Full-Text Articles in Physical Sciences and Mathematics

Comparative Life Cycle Assessment Of Small Vertical-Axis Wind Turbines And Natural Gas Facility At An Urban University, Mary Kate Ranii Aug 2023

Comparative Life Cycle Assessment Of Small Vertical-Axis Wind Turbines And Natural Gas Facility At An Urban University, Mary Kate Ranii

Electronic Theses and Dissertations

Fossil fuels generate the majority of the electricity in the United States and generate pollutants that negatively affect public and environmental health. Renewable energy projects serve as an opportunity for low-pollution and low-carbon electricity; small-scale projects, such as vertical axis wind turbines (VAWTs), provide opportunities for generation in urban areas close to consumers. Researchers collected wind speed and directional data from a potential turbine installation site at Duquesne University to better demonstrate the potential benefits in an urban university location. The data was used in a life cycle assessment framework and a social review to better understand the value of …


Structural, Magnetic, Electrical, Pseudocapacitive, And Electrocatalytic Properties Of Bilayered Ruddlesden-Popper Oxides., Chandana Kananke-Gamage May 2023

Structural, Magnetic, Electrical, Pseudocapacitive, And Electrocatalytic Properties Of Bilayered Ruddlesden-Popper Oxides., Chandana Kananke-Gamage

Electronic Theses and Dissertations

Ruddlesden Popper (RP) oxides are perovskite-derived functional materials with the general formula An-1Aʹ2BnO3n+1, where A/Aʹ is often a lanthanide or alkaline earth metal, and B is usually a transition metal. These materials contain perovskite-like connectivity, where BO6 units share apexes to form layers that are stacked above each other. The number of layers in each stack is represented by n in the above formula. The spaces between stacks are often occupied by lanthanide or alkaline-earth metals (Aʹ-site metals), which also reside in intra-stack spaces (A-site) between the octahedra. Oxide materials derived from perovskites have been studied for a wide range …


Advancements Toward Sustainable Solar Fuel Production Utilizing Reductive Homogeneous Electro- And Photocatalysis, Hunter Pratt Shirley Jan 2021

Advancements Toward Sustainable Solar Fuel Production Utilizing Reductive Homogeneous Electro- And Photocatalysis, Hunter Pratt Shirley

Electronic Theses and Dissertations

Molecular CO2 and H+ reductive catalysts, whether they be electro- or photocatalytic, have been shown to be possible routes of harnessing solar energy in a clean, renewable manner. There are few electrocatalysts operating at reasonable overpotentials to prove useful in artificial photosynthetic systems, and there are a number of environmental factors within these systems that have yet to be evaluated. Photo-driven catalysis is rare, difficult to control, and rarely provides high-value CO2 reduction products. I report herein an exceptionally low overpotential H+ reduction catalyst, a method of modulating electrocatalysts in-situ to improve performance, a first-of-its-kind mononuclear proton reduction photocatalyst, a …


Biophysical And Stable Isotopic Profiles Of The Salmon Louse Lepeophtheirus Salmonis (Krøyer, 1837), Emma Taccardi Aug 2020

Biophysical And Stable Isotopic Profiles Of The Salmon Louse Lepeophtheirus Salmonis (Krøyer, 1837), Emma Taccardi

Electronic Theses and Dissertations

The salmon louse Lepeophtheirus salmonis is a parasitic copepod that infects wild and farmed salmonids throughout the northern hemisphere. L. salmonis represents the largest economic hurdle of the Atlantic salmon (Salmo salar) industry, with an estimated annual cost of nearly $1 billion globally due to production losses and anti-parasitic control measures. Salmon farming in Maine has existed for decades and is a critical economic driver, yet the region is underrepresented in global sea lice research. The aim of this work was to examine parasites in the context of animal trophic transfer and characterize physiological condition by quantifying the …


Homogeneous Ligand-Centered Hydrogen Evolution And Hydrogen Oxidation : Exploiting Redox Non-Innocence To Drive Catalysis., Andrew Z. Haddad May 2017

Homogeneous Ligand-Centered Hydrogen Evolution And Hydrogen Oxidation : Exploiting Redox Non-Innocence To Drive Catalysis., Andrew Z. Haddad

Electronic Theses and Dissertations

Hydrogen is a promising carbon-free fuel / energy carrier and is an essential building block for many industrial and agricultural processes. Rising energy demands have ignited interest in the development of carbon-free and carbon neutral energy sources. In this context, hydrogen is an attractive candidate—being energy-dense, carbon-free—and easily accessible through a two-electron reduction of water. Accordingly, many electrochemical homogeneous catalyst systems have been studied, with a focus on understanding the mechanism of hydrogen evolution proceeding through metal-hydride intermediates. However, there has been a renaissance in hydrogen evolution reaction (HER) catalyst design, with many groups implicating ligand redox non-innocence as a …


Emergent Geographies In Green Energy, Sean Tierney Jan 2010

Emergent Geographies In Green Energy, Sean Tierney

Electronic Theses and Dissertations

A consensus on climate change is spurring an energy transition, but the geography of this transition is uneven and this paper evaluates the energy landscape globally, in the United States and in Colorado. Developed countries have taken the lead in installations and of next generation energy technology ownership. Green electricity has still not achieved parity with fossil fuels, which puts their adoption in the hands of policy makers who are trying to spur innovation with minimal financial disruption. Yet the future of green electricity is in question due to weak and fragmented policy regimes, but also because of inadequate R&D …