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Full-Text Articles in Physical Sciences and Mathematics
Sorption Temperature And And The Stability Of Iron-Bound Soil Organic Matter, Michael L. Nguyen
Sorption Temperature And And The Stability Of Iron-Bound Soil Organic Matter, Michael L. Nguyen
Doctoral Dissertations
The preservation of soil organic matter (SOM) is an important control on the global cycling of carbon. Long-term preservation of SOM has important implications on soil fertility and climate regulation. Minerals, such as iron oxides, can react with SOM and serve as a preservation mechanism for SOM. Globally, iron oxide-SOM interactions form a “rusty carbon sink” which protects up to 22% of organic carbon in marine sediments. Climate changes, such as warming, may alter the size or efficacy of the “rusty carbon sink.” The effects of temperature, SOM composition, and mineral particle size on the formation and stability of iron …
Wildfires In The Northeastern United States: Evaluating Fire Occurrence And Risk In The Past, Present, And Future, Daniel R. Miller
Wildfires In The Northeastern United States: Evaluating Fire Occurrence And Risk In The Past, Present, And Future, Daniel R. Miller
Doctoral Dissertations
Climate change is one of the most complex and challenging issues facing the world today. A changing climate will affect humankind in many ways and alter our physical environment, presenting ethical challenges in how we respond. The impact of climate change will likely be exacerbated in heavily populated regions of the planet, such as the Northeastern United States (NEUS). The NEUS is comprised of complex, sprawling urban centers and rural regions, both of which are vital to the economic and cultural character of the region. Furthermore, both urban and rural areas in the NEUS contain communities that have been historically …
The Benefit Of Precise Chemical Shift And Concentration Referencing In Nmr Applications, Ming Huang
The Benefit Of Precise Chemical Shift And Concentration Referencing In Nmr Applications, Ming Huang
Doctoral Dissertations
“In Nuclear Magnetic Resonance (NMR) spectroscopy, the chemical shift and intensity of NMR signals provide critical information about a sample's molecular structure, reaction conditions, and material properties. For the precise determination of structures and properties, it is critical to know sample or reaction conditions such as temperature, pH, concentration, or absolute amount of material. Chemical-shift and signal-intensity calibrations play a key role for extracting the maximum amount of information from NMR experiments. In this dissertation, internal and external reference standards are used to calibrate NMR spectra with respect to chemical shift and signal intensity. Sealed capillary tubes filled with specific …