Physical Sciences and Mathematics Commons^™

Synthesis And Properties Of Diorganomagnesium Compounds, Conrad William Kamienski

Doctoral Dissertations

Introduction: Although dialkylmagnesium compounds have been known for over a hundred years, relatively little effort has been directly expended on these reagents per se; much of what we know about magnesium alkyls has been an outgrowth of previous studies concerned with the nature of the Grignard reagent. Only recently has any effort been made to elaborate on methods for preparing these reagents, to determine carefully their physical and chemical properties, and to develop practical uses for these reagents. It has been the purpose of the present study to review the presently known methods of preparation of dialkylmagnesium compounds, to …

Minimal Weinstein Discs In A Subspace, William Lewis Morris

Doctoral Dissertations

The basic features of Clanton's algorithm are reviewed and it is shown that the analysis of ρ(A; Sx) leads to a refinement of the algorithm. A new algorithm to solve Ay = λy is the concluding item in this investigation

Lithostratigraphy Of Conasauga Group Between Rogersville And Kingsport, Tennessee, Walter Lee Helton

Doctoral Dissertations

Conclusions: The following conclusions are presented from the study of the lithostratigraphy of the Conasauga Group in Carter and Stanley valleys:

1. The Conasauga Group presents classic examples of isopic and heteropic facies.

2. The lithology of the individual formations of the Conasauga Group is remarkably similar in both thrust belts.

3. The carbonate units of the Conasauga Group thicken eastward and southeastward and the claystone units thicken westward and northwestward.

4. The Pumpkin Valley Shale is a transitional unit which has a Rome lithology in the lower half of the formation and Conasauga-type lithologies in the upper one-half of …

Magnetic Properties Of The Bifeo₃-Pbtio₃-Pbzro₃ Ternary System, James Ivan Latham

Doctoral Dissertations

"The magnetic susceptibility and spontaneous magnetic moment of the perovskitic, polycrystalline solid solutions of BiFeO₃ with PbTiO₃, PbZrO₃, and [50PbZrO₃·50PbTiO₃] were determined using the Faraday method. Pure BiFeO₃ has a G-type antiferromagnetic structure. Although the perovskite BiFeO₃ exhibits a sharp peak in the susceptibility at the Néel temperature, it does not possess a spontaneous magnetic moment. The solid solutions investigated possessed a spontaneous magnetic moment throughout the multiple cell rhombohedral region of the BiFeO₃-PbTiO₃-PbZrO₃ ternary phase diagram, which extends from pure BiFeO₃ to …

High Frequency Ferroelectric Properties Of The Bifeo₃-Pbtio₃-Pbzro₃ Ternary System, Robert Travis Smith

Doctoral Dissertations

"High temperature dielectric measurements have been performed on the ferroelectric and antiferroelectric perovskitic polycrystalline solid solutions in the BiFeO₃-PbTiO₃-PbZrO₃ ternary system. The data were taken in the UHF frequency range with the use of a slotted line and specially constructed sample holder capable of operation at temperatures in excess of 800°C.

The Curie points have been found to occur at progressively higher temperatures with the increase of BiFeO₃ content in the solutions except in phase transition regions where minima can occur. The dielectric constants at the Curie temperatures have been found to decrease with …

The Technique Of Lineaments And Linears Analysis And Its Application In The Minerogenic Province Of Southeast Missouri, Hassan A. Etr

Doctoral Dissertations

"Current terminology in the field of lineaments and linears (lineations) analysis was reviewed and quantitative definitions of the common terms offered. A general classification of lineations is herein proposed. Characteristics of drainage and airphoto lineations were reviewed and the procedure used in their analysis discussed.

An area about 1880 square miles was analyzed for lineations based on drainage networks and the resulting patterns showed preferred orientation. These drainage lineations were later compared with the airphoto lineations of the same area and a limited degree of similarity was observed.

The airphoto lineations of an area approximately 7000 sq. mi. covering the …

Study Of Resonance Effects In Allenic And Related Systems, Robert Andrew Steinkamp

Doctoral Dissertations

"In order to investigate the possibility of resonance effects through a non-coplanar substituted acetylene, synthesis of bis-(2,5,8-trimethyl-l-naphthyl)-acetylene was attempted. Condensation of acetylene with 2,5,8-trimethyl-l-tetralone to yield an acetylenic glycol followed by dehydration and dehydrogenation was expected to yield the desired non-coplanar acetylene. Comparison of its ultraviolet spectrum with that of di-l-naphthyl-acetylene would have suggested the true nature of the acetylene pi cloud. The acetylene condensation was unsuccessful, however.

Substituted allenes, which contain one sp hybridized carbon atom, were then successfully synthesized for a similar analysis of potential resonance effects. A series of para-substituted 4-phenyl-2-methylbutadienoic acids were synthesized and their pKa's …

A Theoretical Investigation Of Elastic And Voigt Transient Spherical Waves, And Plane Three-Element Viscoelastic Waves, Edward Hornsey

Doctoral Dissertations

"A mathematical model of explosive generated waves in rock is needed in many areas of engineering endeavor. Investigations to date have been unsuccessful in obtaining a model that satisfactorily represents real wave phenomena at all radial distances and in all of the important characteristics.

In this investigation, spherical waves in elastic and Voigt media were investigated. Series solutions for plane waves in a three-element viscoelastic medium were obtained. A dual exponential pressure pulse, P(t) = P_o (e^-αt-e^-ßt) was assumed because it can exhibit significant features of real pressure pulses while avoiding instantaneous rise time, which …

Kilocycle Range Dislocation Damping In Dilute Magnesium Alloy Single Crystals, Robert Ray Nothdurft

Doctoral Dissertations

"The kilocycle range dislocation damping and Young's modulus of single crystals of magnesium and single crystals of magnesium containing small additions of lithium, zinc, or aluminum have been studied as a function of strain amplitude, temperature, and time during annealing and following a high strain amplitude vibration. The data are compared to the Granato-Lücke theory of dislocation damping, the Granato-Hikata-Lücke theory for the recovery of damping following plastic deformation, and the Yamafuji-Bauer theory for the recovery of damping following a high strain amplitude vibration. Reasonable qualitative agreement is obtained between the Granato-Lücke theory and the observed dependence of the damping …

A Calorimetric Study Of The Effects Of Surface Energy In A Type Ii Superconductor, Robert Rex Rice

Doctoral Dissertations

"A calorimetric study of the effects of the interphase surface free energy has been conducted on ellipsoidal samples of first and second kind superconductors. The measurements were performed using a specially designed magnetization calorimeter by two different techniques. The measurements were made on lead, tin, lead-4at%thallium, and tin-6at% indium. The results confirm the existence and experted sign of the surface energy in a well annealed lead-4at%thallium sample, and indicate that the interphase surface energy in lead and tin is too small to be directly detected by this method. The measured latent heats of transition of lead and tin agree well …