Physical Sciences and Mathematics Commons^™

Modular Synthesis Of Weinreb Amides Of 2-Fluoro-2,4-Dienoic Acids, Mohammad Chowdhury

Dissertations and Theses

No abstract provided.

Selective Adsorption Of Dibenzothiophenes On Activated Carbons With Metal Species Deposited On Their Surfaces, Jakub Lison

Dissertations and Theses

"The objective of this thesis is an investigation of influence of porosity, surface chemistry, material composition and effects of metals oncarbon adsorbents in desulfurization of liquid fuels. Materials are derived from poly (4-styrenesulfonic acid-co-maleic acid) salts (sodium or transition metals). They are investigated in a dynamic breakthrough process using model diesel fuel containing dibenzothiophene (DBT) and 4, 6-dimethyldibenzothiophene (DMDBT). The performance of adsorbents is evaluated in terms of the capacity and selectivity. Differences in performance are investigated considering the porosity, surface chemistry and the type of material used."

S-Nitrosothiols: Formation, Decomposition, Reactivity And Possible Physiological Effects, Moshood Kayode Morakinyo

Dissertations and Theses

Three biologically-active aminothiols cysteamine (CA), DL-cysteine (CYSH) and DL-homocysteine, were studied in this thesis. These aminothiols react with nitrous acid (HNO₂), prepared in situ, to produce S-nitrosothiols (RSNOs): S-nitrosocyteamine (CANO), S-nitrosocysteine (CYSNO) and S-nitrosohomocysteine (HCYSNO). They also react with S-nitrosoglutathione (GSNO) and S-nitroso-N-acetylpenicillamine (SNAP) through a transnitrosation reaction to produce their corresponding RSNOs. A detailed kinetics and mechanistic study on the formation of these RSNOs and their subsequent decomposition to release nitric oxide (NO) were studied.

For all three aminothiols the stoichiometry of their reaction with nitrous acid is strictly 1:1 with the formation of one mole …

Investigation Of The Sources And Sinks Of Atmospheric Methane, Christopher Lee Butenhoff

Dissertations and Theses

The work presented here represents a number of independent studies that investigated various components of the CH₄ budget, namely the sources and sinks. We used a chemical-tracer model and created unique long-term time series of atmospheric CH₄, carbon monoxide (CO), molecular hydrogen (H₂), and methylchloroform (CH₃CCl₃) measurements at marine background air to derive histories of atmospheric hydroxyl radical (OH) - the main chemical oxidant of CH₄, biomass burning - an important source of CH₄ in the tropics, and emissions of CH₄ from rice paddies - one of …