Physical Sciences and Mathematics Commons^™

Study Of 3,3' Vs. 4,4' Dds Isomer Curatives On Physical Properties And Phenyl Ring Motions Of Dgeba Epoxy Via Molecular Dynamics, Deuterium Nmr, And Dielectric Spectroscopy, Samuel James Tucker

Dissertations

The purpose of this research is to develop a multiscale understanding of crosslinked amorphous matrices, connecting molecular level events to macroscopic properties. To accomplish this goal, our methodology was to identify network architectures that influence molecular level energy dissipation through mechanisms such as bond rotations, torsions, and ring flips and then relate those molecular motions to macroscopic properties. Studies were accomplished on two aerospace grade matrices: the epoxy, diglycidyl ether of bisphenol A (DGEBA) cured with two amines, 3,3’- diaminodiphenyl sulfone (33DDS) and 4,4’-diaminodiphenyl sulfone (44DDS). The 33DDS/DGEBA and 44DDS/DGEBA served both to provide a baseline for experimental testing of …