Physical Sciences and Mathematics Commons^™

Modeling Study On The Neopentyl+ O2 Reaction System And Experimental And Modeling Study On Mtbe Pyrolysis And Oxidation, Ru Wei

Dissertations

A modeling study on neopentyl radical + O₂ reaction system is conducted in this study. Thermodynamic parameters on all species and important transition states are calculated. A thermochemical kinetic analysis is performed.

Thermodynamic parameters are estimated using group additivity with HBI groups. Transition state energies are evaluated from experimental and theoretical data in the literature, combined with elementary reaction modeling to account for temperature effects. Transition state structures, vibration frequencies and entropies are determined from semi-empirical calculations, MOPAC PM3. Kinetics are analyzed with quantum RRK theory for k(E) coupled with modified strong collision analysis of Gilbert et al for …

An Investigation Of The Oxygraphic Response Of Stressed Bovine Blood, Cristin Mckenna

Dissertations

Oxygraphic profiles of stressed bovine blood in a temperature controlled 2 ml reactor vessel provide the basis for an investigation of blood's response to various conditions. This response is broken down into an initial response (within 3 seconds), the response over 1 hour and the response over 24 hours. Fast-assay runs which investigate the initial response display a dose-response relationship when chemically stressed by phenol. Phenol concentrations in the 1,000 ppm range indicate a decrease in dissolved oxygen (DO) and higher phenol concentrations of over 20,000 an increase in DO. In addition to phenol concentration, other factors investigated with respect …

Sampling And Analysis Of Trace Level Volatile Organic Compounds From Air Via Membrane Permeation, Naihong Zhu

Dissertations

The objective of this study is to develop air sampling techniques using membrane permeation. Two novel techniques for sampling and analysis of trace level VOCs from air via membrane permeation are presented:

1. selective concentration of VOCs into a canister using a membrane permeator;
2. on-line membrane extraction for direct introduction of VOCs from air emissions into a gas chromatograph.

In the membrane permeator-canister sampling system (MPCS), the air sample containing trace level VOCs as well as some interferences such as moisture are passed through the membrane module. Polydimethyl siloxane membrane used in this research is highly permeable to organic compounds, but …