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Dehydrogenation/Rehydrogenation Mechanism In Aluminum Destabilized Lithium Borohydride, Xuebin Yu, Guanglin Xia, Zaiping Guo, Hua-Kun Liu

Australian Institute for Innovative Materials - Papers

LiBH₄/Al mixtures with various mol ratios were prepared by ball milling. The hydrogen storage properties of the mixtures were evaluated by differential scanning calorimetry/ thermogravimetry analyses coupled with mass spectrometry measurements. The phase compositions and chemical state of elements for the LiBH₄/Al mixtures before and after hydrogen desorption and absorption reactions were assessed via powder x-ray diffraction, infrared spectroscopy, and x-ray photoelectron spectroscopy. Dehydrogenation results revealed that LiBH₄ could react with Al to form AlB₂and AlLi compounds with a two-step decomposition, resulting in improved dehydrogenation. The rehydrogenation experiments were investigated at 600^{° …}