Physical Sciences and Mathematics Commons^™

Cerulean Warbler (Setophaga Cerulea) And Associated Species Response To Operational Silviculture In The Central Appalachian Region, Gretchen Emily Nareff

Graduate Theses, Dissertations, and Problem Reports

In this study, I assessed the response of Cerulean Warblers (Setophaga cerulea) and 5 additional songbird species to timber harvests prescribed through operational silviculture. The research took place in relatively contiguous mature deciduous forests in 4 states in the central Appalachian region—Kentucky, Pennsylvania, Virginia, and West Virginia, USA.

For the first part of the study, I collected Cerulean Warbler abundance and territory data through point counts and territory mapping, respectively. I used the point count data to model Cerulean Warbler abundance pre- and post-harvest at 5 study areas (Kentucky [n=1], Virginia [n=2], West Virginia [n=2]) and post-harvest at …

Beneath The Gypsum Dunes: Cenozoic History Of Wind And Water From A Core Drilled At White Sands, New Mexico, Jackson Bentley Jakeway

Graduate Theses, Dissertations, and Problem Reports

White Sands, New Mexico is the largest gypsum dune field on planet Earth, the result of reworking of gypsum deposits. The dunes have been well studied, but the Cenozoic history preceding the formation of the dune field has been poorly studied. A core drilled to a depth of 192 ft (58.5 m) beneath the modern dune field contains deposits from saline lakes, sandflats, perennial freshwater lakes, perennial brackish to saline lakes, and saline mudflats.

The core is composed of bottom-growth bedded gypsum, gypsum sandstone and siltstone, mixed siliciclastic-gypsum sandstones and siltstones, laminated siliciclastic mudstones, gypsum mudstones, and carbonate mudstones. Bottom-growth …

Photoluminescent Zirconium Complexes For Visible Light Photoredox Catalysis, Yu Zhang

Graduate Theses, Dissertations, and Problem Reports

Early transition metals like zirconium are attractive candidates for the design of luminescent molecules based on earth-abundant elements. Here, a series of zirconium complexes carrying two pyrrolyl-based ligands have been synthesized and characterized. These complexes are photoluminescent upon excitation with visible light and exhibit remarkably long emission lifetimes of hundreds of μs in solution at room temperature. Computational studies using time-dependent density functional theory (TD-DFT) were conducted to identify the nature of the luminescent excited states as mixed intra-ligand/ligand-to-metal charge-transfer (ILCT/LMCT) states. The electrochemistry studies revealed multiple reversible redox events for each zirconium complex. Furthermore, the excited state of the …

The Structural Information Filtered Features Potential For Machine Learning Calculations Of Energies And Forces Of Atomic Systems., Jorge Arturo Hernandez Zeledon

Graduate Theses, Dissertations, and Problem Reports

In the last ten years, machine learning potentials have been successfully applied to the study of crystals, and molecules. However, more complex materials like clusters, macro-molecules, and glasses are out reach of current methods. The input of any machine learning system is a tensor of features (the most universal type are rank 1 tensors or vectors of features), the quality of any machine learning system is directly related to how well the feature space describes the original physical system. So far, the feature engineering process for machine learning potentials can not describe complex material. The current methods are highly inefficient …

Design Of Experiment And Analysis Techniques For Fuel Consumption Data Using Heavy-Duty Diesel Vehicles And On-Road Testing, Sarah Ann Mills

Graduate Theses, Dissertations, and Problem Reports

Chassis dynamometer and on-road testing are usually employed to test vehicle operation. Testing on a chassis dynamometer reduces data variability compared to on-road testing due to the controlled environment but it does not account for other important variables that affects real-world vehicle operation. This study used on-road testing to investigate the differences between two test fuels under real-world conditions. Three heavy-duty diesel vehicles were driven on different routes for a period of three months. Each vehicle was instrumented with flow meters to gather fuel consumption data, which was then compared to the fuel rate broadcasted by the engine control unit …

Intelligent Malware Detection Using File-To-File Relations And Enhancing Its Security Against Adversarial Attacks, Lingwei Chen

Graduate Theses, Dissertations, and Problem Reports

With computing devices and the Internet being indispensable in people's everyday life, malware has posed serious threats to their security, making its detection of utmost concern. To protect legitimate users from the evolving malware attacks, machine learning-based systems have been successfully deployed and offer unparalleled flexibility in automatic malware detection. In most of these systems, resting on the analysis of different content-based features either statically or dynamically extracted from the file samples, various kinds of classifiers are constructed to detect malware. However, besides content-based features, file-to-file relations, such as file co-existence, can provide valuable information in malware detection and make …

Experimental And Modeling Investigation Of The Oh-Initiated Oxidation Of Semi-Solid And Aqueous Saccharide Aerosols, Hanyu Fan

Graduate Theses, Dissertations, and Problem Reports

My research focuses on investigating the impact of moisture-induced and oligomer-induced viscosity changes on OH-initiated oxidation of semi-solid aerosols,and the role of gas-liquid interfaces in regulating aqueous aerosol chemistry. Saccharides, which are a major constituent of aqueous atmospheric aerosols, are chosen as model molecules to form highly oxygenated organic aerosols. The experiments are performed using an atmospheric pressure flow-tube reactor with both online VUV-AMS (Vacuum-Ultraviolet Aerosol Mass Spectrometer) and offline GC-MS analysis techniques. The decay rates of saccharide are determined by measuring the loss signal of saccharide in the particle phase as a function of OH exposure (time-integrated total concentration …

Pharmaceutical Scheduling Using Simulated Annealing And Steepest Descent Method, Bryant Jamison Spencer

Graduate Theses, Dissertations, and Problem Reports

In the pharmaceutical manufacturing world, a deadline could be the difference between losing a multimillion-dollar contract or extending it. This, among many other reasons, is why good scheduling methods are vital. This problem report addresses Flexible Flowshop (FF) scheduling using Simulated Annealing (SA) in conjunction with the Steepest Descent heuristic (SD).

FF is a generalized version of the flowshop problem, where each product goes through S number of stages, where each stage has M number of machines. As opposed to a normal flowshop problem, all ‘jobs’ do not have to flow in the same sequence from stage to stage. The …

Stream Salamander And Benthic Macroinvertebrate Community Responses To Imidacloprid Exposure, Sara M. Crayton

Graduate Theses, Dissertations, and Problem Reports

The insecticide imidacloprid is widely used to mitigate hemlock (Tsuga spp.) mortality resulting from the invasive hemlock woolly adelgid (HWA), but evidence suggests that

imidacloprid can have negative effects on adjacent stream systems. Imidacloprid exposure causes physiological changes, bioaccumulation, and reduced survival in anurans, and induces physiological impairment and reduced survival in benthic macroinvertebrates. In this thesis, we assessed whether HWA treatments using imidacloprid affect stream salamander abundances and benthic macroinvertebrate community composition. We also investigated whether imidacloprid or its metabolites bioaccumulate in benthic macroinvertebrates or salamanders and cause sublethal effects. We conducted this study in two National Park …

Depth Dependent Atomic Valence Determination In La0.7sr0.3mno3 Thin Films Using Synchrotron Techniques, Robbyn B. Trappen

Graduate Theses, Dissertations, and Problem Reports

The valence of atoms often has a strong effect on the properties of materials, such as magnetism, conductivity, and superconductivity. The atomic valence is often perturbed at the surface and/or interface and this deviation may play a strong role in many physical phenomena such as interfacial coupling and dead layers, both magnetic and electric. In this dissertation, I present a non-destructive approach of combining two X-ray absorption detection modes, electron yield and fluorescence, with very different probing depths in conjunction with theory to map out the layer-by-layer valence of a thin film.

The weighted average Mn atomic valence as measured …

Evaluation And Understandability Of Face Image Quality Assessment, Mohammad I. Nouyed

Graduate Theses, Dissertations, and Problem Reports

Face image quality assessment (FIQA) has been an area of interest to researchers as a way to improve the face recognition accuracy. By filtering out the low quality images we can reduce various difficulties faced in unconstrained face recognition, such as, failure in face or facial landmark detection or low presence of useful facial information. In last decade or so, researchers have proposed different methods to assess the face image quality, spanning from fusion of quality measures to using learning based methods. Different approaches have their own strength and weaknesses. But, it is hard to perform a comparative assessment of …

Using Social Media To Combat Opioid Epidemic, Yiming Zhang

Graduate Theses, Dissertations, and Problem Reports

Opioid addiction has become one of the largest and deadliest epidemics in the United States. To combat such deadly epidemic, there is an urgent need for novel tools and methodologies to gain new insights into the behavioral processes of opioid abuse and addiction. The role of social media in biomedical knowledge mining has turned into increasingly significant in recent years. The data from social media may contribute information beyond the knowledge of domain professionals (e.g., psychiatrists and epidemics researchers) and could potentially assist in sharpening our understanding toward the behavioral process of opioid addiction and treatment.

In this thesis, we …

Soil Health Assessment In Reclaimed Mine Soils, Katie Danielle Stutler

Graduate Theses, Dissertations, and Problem Reports

West Virginia is one of the top coal-producing states in the nation, which has resulted in over 500,000 acres of highly disturbed, anthropogenic mine soils caused by surface mining. Mine soils are often rocky and contain low organic matter content, low plant-available nutrients, and toxic metals, which could result in poor soil health and low productivity. Soil health has been defined as the continued capacity of soil to function as a living ecosystem that sustains plants, animals, and humans. It is assumed that with time since reclamation, mine soil properties and related functions may change, and soil health will improve …

Description Of Motor Control Using Inverse Models, Anton Sobinov

Graduate Theses, Dissertations, and Problem Reports

Humans can perform complicated movements like writing or running without giving them much thought. The scientific understanding of principles guiding the generation of these movements is incomplete. How the nervous system ensures stability or compensates for injury and constraints – are among the unanswered questions today. Furthermore, only through movement can a human impose their will and interact with the world around them. Damage to a part of the motor control system can lower a person’s quality of life. Understanding how the central nervous system (CNS) forms control signals and executes them helps with the construction of devices and rehabilitation …

Sediment Provenance Study Of The Lower Hamilton Group: An Analysis Of The Organic-Rich Facies And Its Depositional History, Luke Patrick Fritz

Graduate Theses, Dissertations, and Problem Reports

Currently, insufficient geological models exist to explain the variability and distribution of TOC in the Marcellus Shale, within the Hamilton Group. TOC is one of the several limiting factors for natural gas production within the Marcellus Shale basin. One possible explanation for the low TOC regions is that detrital dilution was variable across the basin, with different sediment sources contributing detritus to low TOC areas, compared to surrounding regions with higher TOC. This hypothesis is tested by analyzing the source composition of inorganic detritus, using elemental and mineralogical proxies, with two cores in the Hamilton Group. The Armstrong #1 core …

Evaluation Of X-Ray Spectroscopic Techniques For Determining Temperature And Density In Plasmas, Theodore Scott Lane

Graduate Theses, Dissertations, and Problem Reports

Temperature and density measurements of plasmas are important for understanding various phenomena. For example, equations of state, most scaling arguments for Inertial Confinement Fusion and laboratory astrophysics all rely upon accurate knowledge of temperature and density. Spectroscopy is a non-invasive technique to measure these quantities. In this work we establish a new spectroscopic technique by using it to determine temperature. We also compare and contrast the capability of two codes, PrismSPECT and ATOMIC, to infer electron density from experimentally acquired spectra via Stark broadening.

We compare and contrast the capability of isoelectronic line ratios and inter-stage line ratios in an …

Peatlands And Histosols In Canaan Valley National Wildlife Refuge, West Virginia, Mitzy Leigh Schaney

Graduate Theses, Dissertations, and Problem Reports

Canaan Valley in West Virginia contains a greater area of peatlands than any other locality in the mid-Atlantic Highlands. Extensive fieldwork focused on peat stratigraphy and pedology, combined with high-resolution radiocarbon dating, was used to evaluate five peatlands within Canaan Valley National Wildlife Refuge (CVNWR) in the central Appalachian Mountains. One hundred soil cores were profiled and described, 30 with laboratory data, including 52 radiocarbon dates. Calibrated basal peat dates among the five mapped peatlands indicate a late Pleistocene timeframe for the onset of peat genesis, ranging from ~18,600 to ~15,200 cal yr BP. The dates for peat initiation are …

Application Of Global Search Methods To Materials Prediction And Design, Adam J. Payne

Graduate Theses, Dissertations, and Problem Reports

Due to increased availability and power of computational resources over the past few decades, prediction and design of novel materials using computational methods has become feasible. Simulation of material systems has become vital to the further realization of novel material systems. In order to ascertain physical properties, accurate determination and identification of stable crystalline structures is necessary. Additionally, further identification of novel properties, such as magnetic moments or orbital occupation, is necessary to further realize this goal. Global search methods provide a path to accurate prediction of these properties. In this dissertation, the Firefly algorithm and minima hopping methods are …

Compound-Specific Isotope Analysis Of Amino Acids In Biological Tissues: Applications In Forensic Entomology, Food Authentication And Soft-Biometrics In Humans, Mayara Patricia Viana De Matos

Graduate Theses, Dissertations, and Problem Reports

In this work we demonstrate the power of compound-specific isotope analysis (CSIA) to analyze proteinaceous biological materials in three distinct forensic applications, including: 1) linking necrophagous blow flies in different life stages to their primary carrion diet; 2) identifying the harvesting area of oysters for food authentication purposes; and 3) the ability to predict biometric traits about humans from their hair.

In the first application, we measured the amino-acid-level fractionation that occurs at each major life stage of Calliphora vicina (Robineau-Desvoidy) (Diptera: Calliphoridae) blow flies. Adult blow flies oviposited on raw pork muscle, beef muscle, or chicken liver. Larvae, pupae …

Modeling Movement Of Criminals Through Burglary Scenes, Veronica L. Herrmann

Graduate Theses, Dissertations, and Problem Reports

Physical evidence plays a large role in the criminal justice system and in crime scene reconstruction. The purpose of evidence is to assist in connecting a person or persons to an incidence, which helps crime scene investigators in reconstructing the events that occurred at the crime scene. This concept is mainly based off Locard's Exchange Principle, which states that there is always an association between an offender and evidence. However, without patent evidence to lead the investigators to a possible route at the scene, determining the movements taken during the commission at a scene is needed.

Engineers have used simulations …

An Assessment Of Farmer Participation In The United States Department Of Agriculture, Natural Resources Conservation Services’ Conservation Technical Assistance Program In West Virginia, Matt D. Oliver

Graduate Theses, Dissertations, and Problem Reports

Food and fiber production on America’s farmlands have a major influence on the environment, therefore, soil and water conservation practices are critical. NRCS has provided no-fee technical assistance for nearly 100 years through the Conservation Technical Assistance (CTA) program. The CTA program is essential because it provides technical knowledge directly to farmers for planning and implementing conservation practices that are proven to benefit environmental health and on-farm production. CTA program funds support NRCS staff and training and are thereby the local service delivery vehicle for all NRCS programs. However, in recent years, funding for CTA has remained relatively constant while …

Analyzing Mathematicians' Concept Images Of Differentials, Timothy Shawn Mccarty

Graduate Theses, Dissertations, and Problem Reports

The differential is a symbol that is common in first- and second-year calculus. It is perhaps expected that a common mathematical symbol would be interpreted universally. However, recent literature that addresses student interpretations of differentials, usually in the context of definite integration, suggests that this is not the case, and that many interpretations are possible. Reviews of textbooks showed that there was not a lot of discussion about differentials, and what interpretations there were depended upon the context in which the differentials were presented. This dissertation explores some of these issues. Since students may not have the experience necessary to …

Copper-Catalyzed Regioselective Boracarboxylation Of Vinyl Arenes: Catalytic Efficiency And Synthetic Utility, Trina M. Perrone

Graduate Theses, Dissertations, and Problem Reports

Hetero(element) carboxylation is an appealing transformation that involves the installation of CO2 and another hetero(element) in one step. This transition metal-catalyzed one-pot synthesis provides a route to achieve highly functionalized carboxylic acid products with an abundant and cheap C1 feedstock. This difunctionalization also avoids the use of reactive metal hydride species, which is a prominent limitation of hydrocarboxylation chemistry. A copper-catalyzed regioselective boracarboxylation of vinyl arenes has been developed to access pharmaceutically relevant β-boryl-α-aryl propionic acid products. One drawback of this reaction is the necessity for high catalyst loading to achieve catalytic turnover. To circumvent this issue, the reduction of …

Novel Computational Methods For Catalytic Applications, Gihan Uthpala Panapitiya

Graduate Theses, Dissertations, and Problem Reports

Thiolate protected nanoclusters gold nanoparticles are gaining interest of many researchers due to their promising applications in a variety of fields the development of synthesizing techniques capable of producing atomically precise nanoclusters with high purity. Au₂₅(SR)₁₈ is one of the widely studied nanoclsuters due its remarkable stability. In this first part of this study, we explore the structural, electronic and catalytic properties of bimetallic Au_25−xAg_x(SR)₁₈ (for x = 6, 7, 8). Due to the combinatorial enormity of the total number of possible alloyed isomers, we choose a randomly selected subset corresponding to …

Historic Log Buildings As Archives Of Past Forest Ecology, Kristen K. De Graauw

Graduate Theses, Dissertations, and Problem Reports

This dissertation is composed of three separate but related manuscripts with the common theme of using historic log buildings from the central Appalachian Mountain region of eastern North America as ecological archives. In Chapter 1, I explore the biases, limitations, and ecological applications of tree-ring data from historic log buildings. European immigrants selected trees from a forested stand based on species, log sizes, and construction locations. Despite this selection bias, ecological information can be gleaned from historic log buildings, which offer a complementary record of past forest ecology and represent a site type that is not often associated with old-growth …

Rule Extraction And Insertion To Improve The Performance Of A Dynamic Cell Structure Neural Network, Osama Amhamed Elsarrar

Graduate Theses, Dissertations, and Problem Reports

Artificial Neural Networks are extremely useful machine learning tools. They are used for many purposes, such as prediction, classification, pattern recognition, etc. Although neural networks have been used for decades, they are still often not completely understood or trusted, especially in safety and mission critical situations. Typically, neural networks are trained on data sets that are representative of what needs to be learned. Sometimes training sets are constructed in order to train the neural network in a certain way, in order to embed appropriate knowledge. The purpose of this research is to determine if there is another method that can …

A Deep Dive Into The Land Development Dynamics Of A Complex Landscape, Pariya Pourmohammadi

Graduate Theses, Dissertations, and Problem Reports

Land development is a complex and dynamic process simultaneously interacting with numerous environmental, cultural and economic procedures. In this research we studied past, present and future of land transformation in Appalachia. This dissertation is organized in three-essay format and each essay is focused on one aspect of land development processes in a sub-region in the Appalachian region. In the first essay, deep learning techniques are used to build predictive models for the land development. This study presets deconvolutional neural networks models in predicting land development. On the second essay, spatial data analysis and remote sensing are used to investigate the …

Global Existence And Asymptotic Behaviors For Some Nonlinear Partial Differential Equations., Ismahan Dhaw Binshati

Graduate Theses, Dissertations, and Problem Reports

We study global existence and asymptotic behavior of the solutions for two-fluid compressible isentropic Euler-Maxwell equations by the Fourier transform and energy method. We discuss the case when the pressure for two fluids is not identical and we also add the friction between two fluids. In addition, we discuss the rates of decay of $L^{p}-L^{q}$ norms for a linear system. Moreover, we use the result for $L^{p}-L^{q}$ estimates to prove the decay rates for the nonlinear systems. In addition, we prove existence of heteroclinic orbits for the nonlinear Vlasov and the one-dimensional Vlasov-Poisson systems. In the nonlinear Vlasov case with …

Death-Defying Morphologies: Mass Extinction And Disparity In The Order Harpetida, James Desmond Beech

Graduate Theses, Dissertations, and Problem Reports

The trilobite order Harpetida has long been easily recognized but poorly understood. This study seeks to better understand the phylogenetic relationships within Harpetida, with a view towards using this group to explore the relationship between extinction intensity and disparity. The harpetid response to the Late Ordovician mass extinction is of particular interest. A discrete morphological character matrix was created from the formal descriptions of harpetids in the published trilobite literature, and refined using first-hand observations of harpetid fossils. The final matrix consists of 76 discrete characters, including 69 cephalic characters, three thoracic characters, and four pygidial characters. This matrix is …

Phased Array Feed Beamforming And Its Application In Mapping Extended Sources, Gargi Roy

Graduate Theses, Dissertations, and Problem Reports

Ever since the detection of radio signals, technology has strived to improve the performance of the hardware associated with detecting and observing faint radio sources by improving signal processing and detection techniques. Phased array feeds (PAFs) for radio telescopes can yield in an increase in the survey speed and field of view for reflector antennas. Beamforming, calibration, and imaging are some of the challenges that need to be addressed in order to further the development of PAFs. There is a trade-off between achieving high sensitivity and maintaining a stable clean beam pattern when it comes to beamforming design strategies. A …