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Full-Text Articles in Physical Sciences and Mathematics
Structure And Electrochemical Performance Modulation Of A Lini0.8co0.1mn0.1o2 Cathode Material By Anion And Cation Co-Doping For Lithium Ion Batteries, Rong Li, Yong Ming, Wei Xiang, Chunliu Xu, Guilin Feng, Yongchun Li, Yanxiao Chen, Zhenguo Wu, Ben-He Zhong, Xiaodong Guo
Structure And Electrochemical Performance Modulation Of A Lini0.8co0.1mn0.1o2 Cathode Material By Anion And Cation Co-Doping For Lithium Ion Batteries, Rong Li, Yong Ming, Wei Xiang, Chunliu Xu, Guilin Feng, Yongchun Li, Yanxiao Chen, Zhenguo Wu, Ben-He Zhong, Xiaodong Guo
Australian Institute for Innovative Materials - Papers
Ni-rich layered transition metal oxides show great energy density but suffer poor thermal stability and inferior cycling performance, which limit their practical application. In this work, a minor content of Co and B were co-doped into the crystal of a Ni-rich cathode (LiNi0.8Co0.1Mn0.1O2) using cobalt acetate and boric acid as dopants. The results analyzed by XRD, TEM, XPS and SEM reveal that the modified sample shows a reduced energy barrier for Li+ insertion/extraction and alleviated Li+/Ni2+ cation mixing. With the doping of B and Co, corresponding enhanced cycle stability was achieved with a high capacity retention of 86.1% at 1.0C …
Thermoelectric Performance Of Single-Phase Tellurium-Reduced Quaternary (Pbte)0.55(Pbs)0.1(Pbse)0.35, Laaya Shaabani, Graeme Blake, Andrew Manettas, Shokat Keshavarzi, Sima Aminorroaya-Yamini
Thermoelectric Performance Of Single-Phase Tellurium-Reduced Quaternary (Pbte)0.55(Pbs)0.1(Pbse)0.35, Laaya Shaabani, Graeme Blake, Andrew Manettas, Shokat Keshavarzi, Sima Aminorroaya-Yamini
Australian Institute for Innovative Materials - Papers
Lead chalcogenide quaternary systems have been shown to provide high thermoelectric (TE) efficiency superior to those of binary andternary lead chalcogenides, arising from both altered electronic band structures and a reduction in lattice thermal conductivity. Here, we have synthesized single-phase samples of the quaternary compound (PbTe)0.55(PbS)0.1(PbSe)0.35 dopedwith Na and characterized their TE properties. We show that the dopant solubility is limited to 1 at. %. A very low lattice thermal conductivity of∼0.6 Wm−1K−1at 850 K is achieved at all dopant concentrations because of phonon scattering from point defects associated with solute atoms with high contrastatomic mass. As a result, a …