Open Access. Powered by Scholars. Published by Universities.®

Physical Sciences and Mathematics Commons

Open Access. Powered by Scholars. Published by Universities.®

University of Wollongong

Performance

2017

Articles 1 - 4 of 4

Full-Text Articles in Physical Sciences and Mathematics

Capillary-Induced Ge Uniformly Distributed In N-Doped Carbon Nanotubes With Enhanced Li-Storage Performance, Haipeng Guo, Boyang Ruan, Lili Liu, Lei Zhang, Zhanliang Tao, Shulei Chou, Jiazhao Wang, Hua-Kun Liu Jan 2017

Capillary-Induced Ge Uniformly Distributed In N-Doped Carbon Nanotubes With Enhanced Li-Storage Performance, Haipeng Guo, Boyang Ruan, Lili Liu, Lei Zhang, Zhanliang Tao, Shulei Chou, Jiazhao Wang, Hua-Kun Liu

Australian Institute for Innovative Materials - Papers

Germanium (Ge) is a prospective anode material for lithium-ion batteries, as it possesses large theoretical capacity, outstanding lithium-ion diffusivity, and excellent electrical conductivity. Ge suffers from drastic capacity decay and poor rate performance, however, owing to its low electrical conductivity and huge volume expansion during cycling processes. Herein, a novel strategy has been developed to synthesize a Ge at N-doped carbon nanotubes (Ge at N-CNTs) composite with Ge nanoparticles uniformly distributed in the N-CNTs by using capillary action. This unique structure could effectively buffer large volume expansion. When evaluated as an anode material, the Ge at N-CNTs demonstrate enhanced cycling …


Structure-Property Relationships Of Organic Electrolytes And Their Effects On Li/S Battery Performance, Mohammad Kaiser, Shulei Chou, Hua-Kun Liu, Shi Xue Dou, Chunsheng Wang, Jiazhao Wang Jan 2017

Structure-Property Relationships Of Organic Electrolytes And Their Effects On Li/S Battery Performance, Mohammad Kaiser, Shulei Chou, Hua-Kun Liu, Shi Xue Dou, Chunsheng Wang, Jiazhao Wang

Australian Institute for Innovative Materials - Papers

Electrolytes, which are a key component in electrochemical devices, transport ions between the sulfur/carbon composite cathode and the lithium anode in lithium-sulfur batteries (LSBs). The performance of a LSB mostly depends on the electrolyte due to the dissolution of polysulfides into the electrolyte, along with the formation of a solid-electrolyte interphase. The selection of the electrolyte and its functionality during charging and discharging is intricate and involves multiple reactions and processes. The selection of the proper electrolyte, including solvents and salts, for LSBs strongly depends on its physical and chemical properties, which is heavily controlled by its molecular structure. In …


Ag-Mg Antisite Defect Induced High Thermoelectric Performance Of Α-Mgagsb, Zhenzhen Feng, Jihua Zhang, Yuli Yan, Guangbiao Zhang, Chao Wang, Chengxiao Peng, Fengzhu Ren, Yuan Xu Wang, Zhenxiang Cheng Jan 2017

Ag-Mg Antisite Defect Induced High Thermoelectric Performance Of Α-Mgagsb, Zhenzhen Feng, Jihua Zhang, Yuli Yan, Guangbiao Zhang, Chao Wang, Chengxiao Peng, Fengzhu Ren, Yuan Xu Wang, Zhenxiang Cheng

Australian Institute for Innovative Materials - Papers

Engineering atomic-scale native point defects has become an attractive strategy to improve the performance of thermoelectric materials. Here, we theoretically predict that Ag-Mg antisite defects as shallow acceptors can be more stable than other intrinsic defects under Mg-poor-Ag/Sb-rich conditions. Under more Mg-rich conditions, Ag vacancy dominates the intrinsic defects. The p-type conduction behavior of experimentally synthesized ¿-MgAgSb mainly comes from Ag vacancies and Ag antisites (Ag on Mg sites), which act as shallow acceptors. Ag-Mg antisite defects significantly increase the thermoelectric performance of ¿-MgAgSb by increasing the number of band valleys near the Fermi level. For Li-doped ¿-MgAgSb, under more …


Ultra-Light And Flexible Pencil-Trace Anode For High Performance Potassium-Ion And Lithium-Ion Batteries, Zhixin Tai, Yajie Liu, Qing Zhang, Tengfei Zhou, Zaiping Guo, Hua-Kun Liu, Shi Xue Dou Jan 2017

Ultra-Light And Flexible Pencil-Trace Anode For High Performance Potassium-Ion And Lithium-Ion Batteries, Zhixin Tai, Yajie Liu, Qing Zhang, Tengfei Zhou, Zaiping Guo, Hua-Kun Liu, Shi Xue Dou

Australian Institute for Innovative Materials - Papers

Engineering design of battery configurations and new battery system development are alternative approaches to achieve high performance batteries. A novel flexible and ultra-light graphite anode is fabricated by simple friction drawing on filter paper with a commercial 8B pencil. Compared with the traditional anode using copper foil as current collector, this innovative current-collector-free design presents capacity improvement of over 200% by reducing the inert weight of the electrode. The as-prepared pencil-trace electrode exhibits excellent rate performance in potassium-ion batteries (KIBs), significantly better than in lithium-ion batteries (LIBs), with capacity retention of 66% for the KIB vs. 28% for the LIB …