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Articles 1 - 7 of 7
Full-Text Articles in Physical Sciences and Mathematics
Significant Enhancement Of The Cycling Performance And Rate Capability Of The P/C Composite Via Chemical Bonding (P-C), Weijie Li, Shulei Chou, Jiazhao Wang, Hua-Kun Liu, S X. Dou
Significant Enhancement Of The Cycling Performance And Rate Capability Of The P/C Composite Via Chemical Bonding (P-C), Weijie Li, Shulei Chou, Jiazhao Wang, Hua-Kun Liu, S X. Dou
Australian Institute for Innovative Materials - Papers
Among anode materials for sodium ion batteries, red phosphorus is a very promising one due to its abundant reserves, low-cost and high theoretical capacity of 2600 mA h g-1. However, its huge volume expansion on sodiation (∼490%) and poor conductivity leads to dramatic capacity decay, restraining its practical application. To improve the electrochemical performance, here, we prepared a red phosphorus and graphene nanoplate composite using cheap red P and natural graphite as the starting materials via a simple and scalable ball-milling method. The phosphorus-carbon bond formed during the milling process improves the electrical connectivity between P particles and graphene nanoplates, …
Lead-Free Snte-Based Thermoelectrics: Enhancement Of Thermoelectric Performance By Doping With Gd/Ag, Lijuan Zhang, Jian Li Wang, Zhenxiang Cheng, Qiao Sun, Zhen Li, S X. Dou
Lead-Free Snte-Based Thermoelectrics: Enhancement Of Thermoelectric Performance By Doping With Gd/Ag, Lijuan Zhang, Jian Li Wang, Zhenxiang Cheng, Qiao Sun, Zhen Li, S X. Dou
Australian Institute for Innovative Materials - Papers
SnTe, with the same rock-salt structure as PbTe, is a potentially attractive thermoelectric material. Pristine SnTe has poor thermoelectric performance because of its very high hole concentration resulting from intrinsic Sn vacancies, which leads to a high thermal conductivity and a low Seebeck coefficient. In this work, the thermoelectric properties of SnTe were modified by doping with different contents of gadolinium and silver. It is found that SnTe doped with optimal gadolinium (i.e. Gd0.06Sn0.94Te) exhibited extraordinarily low lattice thermal conductivity that is close to the theoretical minimum. The drastic reduction of lattice thermal conductivity is attributed to the formation of …
Expeditious And Eco-Friendly Hydrothermal Polymerization Of Pedot Nanoparticles For Binderfree High Performance Supercapacitor Electrodes, Murugesan Rajesh, C Justin Raj, Byung Chul Kim, Ramu Manikandan, Sung Jin Kim, Sang-Yeup Prof Sang-Yeup Park, Kwangsoo Lee, Kook Hyun Yu
Expeditious And Eco-Friendly Hydrothermal Polymerization Of Pedot Nanoparticles For Binderfree High Performance Supercapacitor Electrodes, Murugesan Rajesh, C Justin Raj, Byung Chul Kim, Ramu Manikandan, Sung Jin Kim, Sang-Yeup Prof Sang-Yeup Park, Kwangsoo Lee, Kook Hyun Yu
Australian Institute for Innovative Materials - Papers
Poly(3,4-ethylenedioxythiophene) (PEDOT) is a promising conjugated polymer that has attracted attention because of its outstanding electronic properties, useful for a wide range of applications in energy storage devices. However, synthesis of high-quality PEDOT occurs via vapour phase polymerization and chemical vapour deposition techniques using extrinsic hard templates or complicated experimental setups. This study introduces a simple hydrothermal polymerization technique using ferric chloride (FeCl3) as an oxidizing agent to overcome the above drawback, which results in good conductive, crystalline PEDOT nanodendrites and nanospheres. The effects of varying the molar ratio of FeCl3 oxidant were investigated in terms of the structural, morphological …
A High-Performance Rechargeable Mg2+/Li+ Hybrid Battery Using One-Dimensional Mesoporous Tio2(B) Nanoflakes As The Cathode, Shuojian Su, Yanna Nuli, Zhenguo Huang, Qi Miao, Jun Yang, Jiulin Wang
A High-Performance Rechargeable Mg2+/Li+ Hybrid Battery Using One-Dimensional Mesoporous Tio2(B) Nanoflakes As The Cathode, Shuojian Su, Yanna Nuli, Zhenguo Huang, Qi Miao, Jun Yang, Jiulin Wang
Australian Institute for Innovative Materials - Papers
Mg2+/Li+ hybrid batteries have recently been constructed combining a Mg anode, a Li+-intercalation electrode, and an electrolyte containing both Mg2+ and Li+. These batteries have been reported to outperform all the previously reported magnesium batteries in terms of specific capacity, cycling stability, and rate capability. Herein, we report the outstanding electrochemical performance of Mg2+/Li+ hybrid batteries consisting of a one-dimensional mesoporous TiO2(B) cathode, a Mg anode, and an electrolyte consisting of 0.5 mol L-1 Mg(BH4)2 + 1.5 mol L-1 LiBH4 in tetraglyme. A highly synergetic interaction between Li+ and Mg2+ ions toward the pseudo-capacitive reaction is proposed. The hybrid batteries …
Superior Sodium-Ion Storage Performance Of Co3o4@Nitrogen-Doped Carbon: Derived From A Metal–Organic Framework, Ying Wang, Caiyun Wang, Yijing Wang, Hua-Kun Liu, Zhenguo Huang
Superior Sodium-Ion Storage Performance Of Co3o4@Nitrogen-Doped Carbon: Derived From A Metal–Organic Framework, Ying Wang, Caiyun Wang, Yijing Wang, Hua-Kun Liu, Zhenguo Huang
Australian Institute for Innovative Materials - Papers
Nitrogen-doped carbon coated Co 3 O 4 nanoparticles (Co 3 O 4 @NC) with high Na-ion storage capacity and unprecedented long-life cycling stability are reported in this paper. The Co 3 O 4 @NC was derived from a metal – organic framework ZIF-67, where the Co ions and organic linkers were, respectively, converted to Co 3 O 4 nanoparticle cores and nitrogen-doped carbon shells through a controlled two-step annealing process. The Co 3 O 4 @NC shows a porous nature with a surface area of 101 m 2 g 1 . When applied as an anode for sodium ion batteries …
Light Activated Electrochemistry: Light Intensity And Ph Dependence On Electrochemical Performance Of Anthraquinone Derivatized Silicon, Ying Yang, Simone Ciampi, Moinul H. Choudhury, J Justin Gooding
Light Activated Electrochemistry: Light Intensity And Ph Dependence On Electrochemical Performance Of Anthraquinone Derivatized Silicon, Ying Yang, Simone Ciampi, Moinul H. Choudhury, J Justin Gooding
Australian Institute for Innovative Materials - Papers
We seek to understand how the thermodynamics and kinetics of anthraquinone-containing self-assembled monolayer on silicon electrodes are affected by two key experimental variables: the intensity of the light assisting the anthraquinone/anthrahydroquinone redox process and the local solution environment. The substrates are chemically passivated poorly doped p-type silicon electrodes. The study presents a strategy for the selective modulation of either the anodic or the cathodic process occurring at the interface. Cyclic voltammetry studies showed that unlike for a proton-coupled electron transfer process performed at metallic electrodes, for the redox reaction of the anthraquinone unit on a silicon electrode it becomes possible …
Characteristics And Cadmium Extraction Performance Of Pvc/Aliquat 336 Electrospun Fibres In Comparison With Polymer Inclusion Membranes, Nurul Syazana Binti Abdul Halim, Philip G. Whitten, Long D. Nghiem
Characteristics And Cadmium Extraction Performance Of Pvc/Aliquat 336 Electrospun Fibres In Comparison With Polymer Inclusion Membranes, Nurul Syazana Binti Abdul Halim, Philip G. Whitten, Long D. Nghiem
Australian Institute for Innovative Materials - Papers
Electrospun fibres and polymer inclusion membranes (PIMs) were prepared from polyvinyl chloride (PVC) and Aliquat 336. Morphological and thermomechanical properties of the electrospun mats differed notably from those of PIMs. The plasticizing effect of Aliquat 336 on electrospun PVC/Aliquat 336 fibres was confirmed by the shifting of the glass transition temperature (Tg). By contrast, Aliquat 336 did not act as a plasticizer in PIMs as Tg was independent of Aliquat 336 concentration. Cadmium extraction to electrospun fibres could occur at a lower Aliquat 336 content (i.e. 6 wt.%) compared with PIMs. At 40 wt.% Aliquat 336 content, both PIMs and …