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University of Wollongong

Performance

2013

Articles 1 - 8 of 8

Full-Text Articles in Physical Sciences and Mathematics

Synergetic Combination Of Limd With Chpd For The Production Of Economical And High Performance Mgb2 Wires, Minoru Maeda, Md Shahriar Ai Hossain, Ashkan Motaman, Jung Ho Kim, Anna Kario, Matt Rindfleisch, Mike Tomsic, S X. Dou Jan 2013

Synergetic Combination Of Limd With Chpd For The Production Of Economical And High Performance Mgb2 Wires, Minoru Maeda, Md Shahriar Ai Hossain, Ashkan Motaman, Jung Ho Kim, Anna Kario, Matt Rindfleisch, Mike Tomsic, S X. Dou

Australian Institute for Innovative Materials - Papers

We propose an economical fabrication concept, the localized internal magnesium diffusion (IMD) method. Instead of using a single magnesium (Mg) rod in the center of a metal sheath tube, we use large-sized Mg particles (20-50 mesh) mixed well with cheap 97% crystalline boron powder to fill the metal sheath tube. After a repeated drawing process, the coarse Mg is elongated along the core wire axis of the metal sheath tube. Textured MgB2 grains are then formed during the sintering process. In the localized IMD process, however, there is still a need to improve the overall density. In order to increase …


A Significant Improvement In Both Low- And High-Field Performance Of Mgb2 Superconductors Through Graphene Oxide Doping, K S B De Silva, S H Aboutalebi, Xun Xu, Xiaolin Wang, W X Li, Konstantin Konstantinov, S X. Dou Jan 2013

A Significant Improvement In Both Low- And High-Field Performance Of Mgb2 Superconductors Through Graphene Oxide Doping, K S B De Silva, S H Aboutalebi, Xun Xu, Xiaolin Wang, W X Li, Konstantin Konstantinov, S X. Dou

Australian Institute for Innovative Materials - Papers

The effects of graphene oxide (GO) doping on the superconducting properties of MgB2 were studied using bulk samples made by the diffusion method. Homogeneous dispersions of GO in tetrahydrofuran were obtained through a novel synthesis method, which is then chemically doped with MgB2. It was found that GO doping significantly improves the critical current density, under both low and high magnetic fields, which distinguishes GO from all the other elements doped into MgB2 so far. 2013 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.


A Facile Route To Synthesize Transition Metal Oxide/Reduced Graphene Oxide Composites And Their Lithium Storage Performance, Chongjun Zhao, Shulei Chou, Yunxiao Wang, Cuifeng Zhou, Hua-Kun Liu, S X. Dou Jan 2013

A Facile Route To Synthesize Transition Metal Oxide/Reduced Graphene Oxide Composites And Their Lithium Storage Performance, Chongjun Zhao, Shulei Chou, Yunxiao Wang, Cuifeng Zhou, Hua-Kun Liu, S X. Dou

Australian Institute for Innovative Materials - Papers

Transition metal oxide (Mn3O4, Fe2O3, Co3O4, and ZnO) and reduced graphene oxide (RGO) composites were successfully synthesized via a hydrothermal method using the direct reaction between the corresponding metal powder and graphene oxide (GO). In this process, the GO can be reduced by transition metal powder in water, and the nanosized metal oxide can be obtained, and homogeneously mixed with and wrapped by RGO to form a metal oxide/RGO composite at the same time. X-ray diffraction, Raman spectroscopy, X-ray photoelectron spectroscopy, and scanning and transmission electron microscopy were used to characterize the as-prepared materials. The different experimental parameters, including reactants, …


Simple Synthesis Of Yolk-Shelled Znco2o4 Microspheres Towards Enhancing The Electrochemical Performance Of Lithium-Ion Batteries In Conjunction With A Sodium Carboxymethyl Cellulose Binder, Jingfa Li, Jiazhao Wang, David Wexler, Dongqi Shi, Jianwen Liang, Hua-Kun Liu, Shenglin Xiong, Yitai Qian Jan 2013

Simple Synthesis Of Yolk-Shelled Znco2o4 Microspheres Towards Enhancing The Electrochemical Performance Of Lithium-Ion Batteries In Conjunction With A Sodium Carboxymethyl Cellulose Binder, Jingfa Li, Jiazhao Wang, David Wexler, Dongqi Shi, Jianwen Liang, Hua-Kun Liu, Shenglin Xiong, Yitai Qian

Australian Institute for Innovative Materials - Papers

Mixed metal oxides have been attracting more and more attention recently because of their advantages and superiorities, which can improve the electrochemical performance of single metal oxides. These advantages include structural stability, good electronic conductivity, and reversible capacity. In this work, uniform yolk-shelled ZnCo2O4 microspheres were synthesized by pyrolysis of ZnCo-glycolate microsphere precursors which were prepared via a simple refluxing route without any precipitant or surfactant. The formation process of the yolk-shelled microsphere structure during the thermal decomposition of ZnCo-glycolate is discussed, which is mainly based on the heterogeneous contraction caused by non-equilibrium heat treatment. The performances of the as-prepared …


Cation Exchange At Semiconducting Oxide Surfaces: Origin Of Light-Induced Performance Increases In Porphyrin Dye-Sensitized Solar Cells, Matthew J. Griffith, Kenji Sunahara, Akihiro Furube, Attila J. Mozer, David L. Officer, Pawel Wagner, Gordon G. Wallace, Shogo Mori Jan 2013

Cation Exchange At Semiconducting Oxide Surfaces: Origin Of Light-Induced Performance Increases In Porphyrin Dye-Sensitized Solar Cells, Matthew J. Griffith, Kenji Sunahara, Akihiro Furube, Attila J. Mozer, David L. Officer, Pawel Wagner, Gordon G. Wallace, Shogo Mori

Australian Institute for Innovative Materials - Papers

The origin of simultaneous improvements in the short-circuit current density (Jsc) and open-circuit voltage (Voc) of porphyrin dye-sensitized TiO2 solar cells following white light illumination was studied by systematic variation of several different device parameters. Reduction of the dye surface loading resulted in greater relative performance enhancements, suggesting open space at the TiO2 surface expedites the process. Variation of the electrolyte composition and subsequent analysis of the conduction band potential shifts suggested that a light-induced replacement of surface-adsorbed lithium (Li+) ions with dimethylpropylimidazolium (DMPIm+) ions was responsible for an increased electron lifetime by decreasing the recombination with the redox mediator. …


Aqueous Dispersions Of Reduced Graphene Oxide And Multi Wall Carbon Nanotubes For Enhanced Glucose Oxidase Bioelectrode Performance, Willo Grosse, Joffrey Champavert, Sanjeev Gambhir, Gordon G. Wallace, Simon E. Moulton Jan 2013

Aqueous Dispersions Of Reduced Graphene Oxide And Multi Wall Carbon Nanotubes For Enhanced Glucose Oxidase Bioelectrode Performance, Willo Grosse, Joffrey Champavert, Sanjeev Gambhir, Gordon G. Wallace, Simon E. Moulton

Australian Institute for Innovative Materials - Papers

Aqueous dispersions of reduced graphene oxide (rGO) and multi walled carbon nanotubes (MWCNT) were fabricated through a modified chemical reduction method. The significant advantage of the method developed here is the omission of any stabilising compound or organic solvent to obtain stable rGO-MWCNT dispersions. Significantly biological entities, in this case the enzyme glucose oxidase (GOx), can be successfully incorporated into the dispersion. These dispersions were characterised using XPS, SEM, zeta potential and particle size measurements which showed that the dispersion stability is not sacrificed with the addition of GOx, and significantly, the electrical properties of the rGO and MWCNTs are …


Evaluation Of Encapsulating Coatings On The Performance Of Polypyrrole Actuators, Sina Naficy, Nicholas Stoboi, Philip G. Whitten, Geoffrey M. Spinks, Gordon G. Wallace Jan 2013

Evaluation Of Encapsulating Coatings On The Performance Of Polypyrrole Actuators, Sina Naficy, Nicholas Stoboi, Philip G. Whitten, Geoffrey M. Spinks, Gordon G. Wallace

Australian Institute for Innovative Materials - Papers

Conjugated polymer actuators are electroactive materials capable of generating force and movement in response to an applied external voltage. Many potential biomedical and industrial applications require these actuators to operate in a liquid environment. However, immersion of uncoated conducting polymer actuators in non-electrolyte liquids greatly reduces their operating lifetime. Here, we demonstrate the use of spray coating as an effective and simple method to encapsulate polypyrrole (PPy) tri-layer bending actuators. Poly(styrene-b-isobutylene-b-styrene) (SIBS) was used as an encapsulating, compliant spray coating on PPy actuators. A significant enhancement in actuator lifetime in both air and water was observed by encapsulating the actuators. …


Highly Uniform Tio2/Sno2/Carbon Hybrid Nanofibers With Greatly Enhanced Lithium Storage Performance, Zunxian Yang, Qing Meng, Zaiping Guo, Xuebin Yu, Tailiang Guo, Rong Zeng Jan 2013

Highly Uniform Tio2/Sno2/Carbon Hybrid Nanofibers With Greatly Enhanced Lithium Storage Performance, Zunxian Yang, Qing Meng, Zaiping Guo, Xuebin Yu, Tailiang Guo, Rong Zeng

Australian Institute for Innovative Materials - Papers

Highly uniform, relatively large area TiO2/SnO 2/carbon hybrid nanofibers were synthesized by a simple method based on thermal pyrolysis and oxidation of an as-spun titanium-tin/polyacrylonitrile nanoweb composite in an argon atmosphere. This novel composite features the uniform dispersion and encapsulation of highly uniform nanoscale TiO 2/SnO2 crystals in a porous carbon matrix. The high porosity of the nanofiber composite material, together with the conductive carbon matrix, enhanced the electrochemical performance of the TiO 2/SnO2/carbon nanofiber electrode. The TiO 2/SnO2/carbon nanofiber electrode displays a reversible capacity of 442.8 mA h g-1 for up to 100 cycles, and exhibits excellent rate capability. …