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Full-Text Articles in Physical Sciences and Mathematics
Management Implications Of Recent Research Into The Effect Of Bitou Bush Invasion, Kristine O. French, Emilie-Jane Ens, Carl Gosper, Elizabeth Lindsay, Tanya J. Mason, Ben Owers, Natalie A. Sullivan
Management Implications Of Recent Research Into The Effect Of Bitou Bush Invasion, Kristine O. French, Emilie-Jane Ens, Carl Gosper, Elizabeth Lindsay, Tanya J. Mason, Ben Owers, Natalie A. Sullivan
Faculty of Science - Papers (Archive)
We review recent research into the impact of bitou bush (Chrysanthemoides monilifera spp. rotundata (DC.) Norl.) on coastal ecosystems which suggest this weed is having widespread impacts on ecosystem services, flora and fauna. Increased decomposition rates and altered nutrient cycling accompany changes in plant community structure and composition. Changes in invaded habitats influence invertebrate and bird assemblages. We summarise research that shows that the establishment phase of seedlings is the key phase where bitou bush outcompetes native species through both resource and interference competition mechanisms.
Reactions Of The Hydroperoxide Anion With Dimethyl Methylphosphonate In An Ion Trap Mass Spectrometer: Evidence For A Gas Phase A-Effect, Andrew M Mcanoy, Martin Paine, Stephen J. Blanksby
Reactions Of The Hydroperoxide Anion With Dimethyl Methylphosphonate In An Ion Trap Mass Spectrometer: Evidence For A Gas Phase A-Effect, Andrew M Mcanoy, Martin Paine, Stephen J. Blanksby
Faculty of Science - Papers (Archive)
The gas phase degradation reactions of the chemical warfare agent (CWA) simulant, dimethyl methylphosphonate (DMMP), with the hydroperoxide anion (HOO–) were investigated using a modified quadrupole ion trap mass spectrometer. The HOO– anion reacts readily with neutral DMMP forming two significant product ions at m/z 109 and m/z 123. The major reaction pathways correspond to (i) the nucleophilic substitution at carbon to form [CH3P(O)(OCH3)O]– (m/z 109) in a highly exothermic process and (ii) exothermic proton transfer. The branching ratios of the two reaction pathways, 89% and 11% respectively, indicate that the …