Physical Sciences and Mathematics Commons^™

Master's Project: The Green Burial Movement & Conservation Burial Grounds, Katherine B. Berdan

Rubenstein School Masters Project Publications

This Master’s project investigates the green burial movement and its relevance as a tool for land conservation organizations. This movement has the potential to change the standard cemetery landscape in the United States by informing consumers of alternative practices and materials that support natural environmental processes and sustainable land management practices. Until a decade ago, the green burial movement had largely taken place at the community and individual level. It is now an established and growing national movement with certifying organizations, standards and practices, and strategic goals. Opportunities exist within this movement to develop partnerships between the burial grounds and …

Master’S Project: Exploring And Supporting Social And Ecological Dimensions Of Pollinator Habitat Enhancement In Burlington, Vt, Victoria Hellwig

Rubenstein School Masters Project Publications

Urbanization and other manmade impacts threaten critical pollinator species like the bumblebee, whose populations are significantly affected by habitat loss. In response, activists in the City of Burlington are enhancing habitat to increase biodiversity through collaborative partnerships in urban green spaces. In an effort to explore and support pollinator habitat enhancement in Burlington, I examined social interactions involved in a group highly motivated to enhance habitat at Lakeview Cemetery and Champlain Elementary School, with an emphasis on power dynamics and place meanings of these sites. In conjunction with this exploration, I created landscape designs, planted a native habitat garden, and …

An International Pilot Study Of Volunteer Stream Monitoring Groups: The Role Of Place Attachment In Volunteer Motivations, Rachel Pierson

Graduate College Dissertations and Theses

Engaging the public in scientific research through volunteer monitoring (a form of community science) has potential to expand knowledge of conditions and to improve collaborative decision-making. Many studies have sought to understand motivations for participation and potential resulting actions or behaviors that benefit the environment. Place-based connections have been demonstrated to lead people to adopt environmentally responsible behaviors. However, few studies have considered possible differences in motivations across countries or the role place attachment may play as a driver of initial or sustained participation.

The aim of this research was to determine the extent to which place attachment influences people’s …

The Feasibility Of Over-Summer Snow Storage At The Craftsbury Outdoor Center, Craftsbury Vt, Hannah Sarah Weiss

Graduate College Dissertations and Theses

Climate change increases the unpredictability of winter weather and threatens the future of nordic skiing. Ski centers at high elevation and high latitude have employed over-summer snow storage, a climate change adaptation strategy, to ensure a consistent start-date to their winter ski season. Over-summer snow storage involves making a large pile of snow during winter and storing the snow beneath protective layers, such as wood chips or foam panels, to impede melt throughout the summer and fall. When ready to open the ski season, the ski center uncovers the pile and spreads the snow to create trails. Though many nordic …

Enhancing Ecosystem Services And Climate Resilience In Agriculture: A Transdisciplinary Approach, Alissa White

Graduate College Dissertations and Theses

A complex of social, economic and environmental factors influences agricultural management in the northeastern US. Farmers often balance goals of farm viability, environmental stewardship, and resilience to climate change, while also under public pressure to enhance the provisioning of ecosystem services from their landscapes. Changes in farm management have been identified as cost-effective ways to address both local water quality issues, and global anthropogenic influences on greenhouse gas concentrations. Individual decision-making on the part of farmers that determines the fate of ecosystem service provisioning from agroecosystems, placing increasing importance on understanding how policy, outreach and research can support farmers’ capacity …

Phosphorus And Nitrogen Losses In Runoff From Fields With And Without Tile Drainage, Leanna Thalmann

Graduate College Dissertations and Theses

Nutrient losses in surface and subsurface drainage from crop fields have important water quality implications. The deterioration of water quality in segments of Lake Champlain has led to efforts to reduce phosphorus (P) and nitrogen (N) export from agricultural fields. This thesis presents data from two years of edge-of-field monitoring in two adjacent corn (Zea mays L.) silage fields in Keeseville, New York. One field has only surface drainage improvements with monitoring equipment, and the other has both surface and subsurface drainage modifications and monitoring equipment. The study took place from October 2018 to September 2020 and quantified flow and …

Estimating Floodplain Storage And Prioritizing Floodplain Reconnection In The Northern Lake Champlain Basin In Vermont, Stephanie Drago

Graduate College Dissertations and Theses

Floodplains play a major role in maintaining the health and sustainability of riverine systems, but human interventions have reduced the connectivity between stream channels and floodplains. Geomorphic assessments of streams and rivers in Vermont (USA) show they have been significantly altered within the past two centuries due to straightening, berming, and armoring channels to accommodate development, agriculture, roads, and rail lines. These alterations in river-floodplain connectivity have decreased floodplain functioning, specifically their capacity to store water during flood events. Currently, there is a lack of knowledge concerning the amount of floodwater, sediment, and nutrient retention provided by Vermont’s floodplains. This …

Coastal Resilience At The Nexus Of Food, Energy, And Water: An Interdisciplinary Perspective For Resilience Planning, Kristin Raub

Graduate College Dissertations and Theses

Global climate change poses increased threats to coastal communities. The resilience of coastal communities relies on the protection and continued availability of essential services such as food, energy, and water (FEW) systems. However, the intersection of FEW nexus research and coastal resilience planning has not been well explored. This dissertation seeks to further the goal of operationalizing resilience planning by examining the usefulness of resilience tools and toolkits that have been developed in recent years and exploring how the FEW nexus approach has been applied to coastal resilience planning in both academic and grey literature. The first chapter provides the …

Organic Amendments Alter Soil Hydrology And Belowground Microbiome Of Tomato (Solanum Lycopersicum), Taylor Readyhough

Graduate College Dissertations and Theses

Manure-derived organic amendments are a cost-effective tool that provide many potential benefits to plant and soil health. For example, amendment applications may increase soil fertility, improve soil structure, stimulate microbial activity, and suppress plant pathogens. Yet, responses to these applications may have unintended consequences. Inherent variability in the physical, chemical, and biological characteristics of these materials can result in inconsistent outcomes observed after their application. These differences are manifested in plant growth, soil physiochemical properties, and soil microbial community composition. Popular manure-derived organic amendments include dairy manure compost and poultry manure pellets. Dairy manure is an abundant resource on many …

Modeling Moose Habitat Use And Fitness Consequences Of Habitat Selection In Vermont, Usa, Joshua Alexander Blouin

Graduate College Dissertations and Theses

The moose (Alces alces) population has been declining across the northeastern US largely due to the impacts of winter ticks (Dermacentor albipictus). In epizootic years, an individual moose can host a staggering number of ticks (> 60,000), affecting both survival and reproduction. Habitat management may be used to improve the status of the moose population and health of individuals, but this requires knowledge of key habitat types used by moose and their spatial distribution. We investigated 1) habitat use by moose and 2) the fitness consequences of habitat selection during two critical winter tick life stages in northeastern Vermont. To …

Small-Scale Roll Coating As A Transitional Stage In The Scaling Of Organic Electronic Device Fabrication Techniques, Jared Benson

Graduate College Dissertations and Theses

Incredible achievements have been made in the field of organic electronics in small-scale laboratory settings. A topic of increasing importance is the realization of the potential for these technologies to be applied in an industrial setting. This is a deceptively challenging process, considering that many of the procedures used to attain exceptional results in a laboratory setting are not viable for translation to larger scale fabrication efforts. Moreover, upscaling fabrication is further complicated by the enormous barrier of entry due to the expensive equipment required to fabricate organic electronics at larger scale as well as the exponentially greater quantity of …

Spillover, Dilution, And Coinfection: Understanding The Spread Of Disease Within Managed And Native Bee Communities., Phillip A. Burnham

Graduate College Dissertations and Theses

Maintaining healthy pollinator communities is vital both for ensuring food securityand ecological diversity. However, managed honeybees and wild bee communities are under threat from an array of stressors including habitat loss, global change, pesticide use, poor beekeeping, and various pests and pathogens. Pathogens have been shown to be spilling over from managed bees into wild bee populations and are known to adversely affect colony function as well as increase mortality. Understanding transmission mechanisms related to general dynamics in this system will not only benefit pollinator health, but also gives us insight into important and understudied topics in disease ecology. In …

Quantifying Proverb Dynamics In Books, News Articles, And Tweets, Ethan Davis

Graduate College Dissertations and Theses

Proverbs are an essential component of language and culture, and though much attention has been paid to their history and currency, there has been comparatively little quantitative work on the frequency with which they are used, and the dynamics of their use over time. With wider availability of large corpora reflecting many diverse genres of documents, it is now possible to take a wider view of the importance of the proverb. Can a corpus linguistic approach to phraseology support existing histories, and what further insight can be gained from a quantitative approach? This study measures temporal changes in the relevance …

Loss Of Precision In Implementations Of The Toom-Cook Algorithm, Marcus Elia

Graduate College Dissertations and Theses

Historically, polynomial multiplication has required a quadratic number of operations. Several algorithms in the past century have improved upon this. In this work, we focus on the Toom-Cook algorithm. Devised by Toom in 1963, it is a family of algorithms parameterized by an integer, n. The algorithm multiplies two polynomials by recursively dividing them into smaller polynomials, multiplying many small polynomials, and interpolating to obtain the product. While it is no longer the asymptotically fastest method of multiplying, there is a range of intermediate degrees (typically less than 1000) where it performs the best.

Some applications, like quantum-resistant cryptosystems, require …

Investigating The Phase Of Green Leaf Volatile Derived Secondary Organic Aerosol Using An Electrical Low Pressure Impactor, Kevin Fischer

Graduate College Dissertations and Theses

Airborne particulate matter consists of small particles suspended in the air and is a ubiquitous component of the Earth’s atmosphere. These particles, known as aerosols, broadly affect both human health and the global climate. Secondary organic aerosol (SOA), a subset of atmospheric aerosol, are produced by the gas phase oxidation of volatile organic compounds (VOCs) originating from anthropogenic and biogenic sources. Of particular interest are a sub class of biogenic VOCs released by stressed plants, green leaf volatiles (GLVs), which are susceptible to oxidation via ozonolysis and form SOA. While important strides have been made in better understanding SOA, many …

Characterizing Mass Loss In Central Cuba Using Long-Term Sediment Generation Rates And Rock Dissolution Rates, Mae Kate Campbell

Graduate College Dissertations and Theses

Knowledge of denudation rates over geologic timescales provides important insight into the processes that govern soil formation, the regulation of Earth’s climate, and the evolution of landscapes. Accurately establishing long-term denudation rates is also key to understanding how human actions have altered the rates and patterns of erosion over time. While cosmogenic nuclides are often used to measure long-term denudation rates at the basin scale, these rates can be unrepresentative of total landscape denudation in areas where significant mass loss occurs through rock dissolution. In tropical landscapes, mass loss by solution often represents a significant portion of total landscape mass …

Perils And Pitfalls Of Symbolic Regression, Ryan Grindle

Graduate College Dissertations and Theses

The ever-growing accumulation of data makes automated distillation of understandable models from that data ever-more desirable. Deriving equations directly from data using symbolic regression, as performed by genetic programming, continues its appeal due to its algorithmic simplicity and lack of assumptions about equation form. However, few models besides a sequence-to-sequence approach to symbolic regression, introduced in 2020 that we call y2eq, have been shown capable of transfer learning: the ability to rapidly distill equations successfully on new data from a previously unseen domain, due to experience performing this distillation on other domains. In order to improve this model, it is …

Trace Metal Contamination In Urban Soils: A Field To Laboratory Methodological Framework For Characterization And Education, Sandra Leighanne Walser

Graduate College Dissertations and Theses

Urban soils around the world have been found to possess elevated concentrations of toxic trace metals such as As, Cd, Cu, Pb, Mn, Hg, Zn known to pose human health risks. Tightening environmental legislation and further elucidation of the detrimental health impacts from trace metals has necessitated more efficient means of contamination assessment, as well as greater public awareness. Within this thesis, I sought to develop an array of tools to holistically approach the socially relevant environmental challenges derived from heavy metal soil contamination. These tools consist in providing means to simplify Pb, Zn and Cu analysis in-situ, develop strategies …

Nonlinear Impedance Spectroscopy To Characterize Hole Transport And Recombination Dynamics In Organic Semiconductor Devices, Robin Rice

Graduate College Dissertations and Theses

Impedance Spectroscopy (IS) is an increasingly common technique to characterize both solid state and electrochemical systems including solar cells and light emitting diodes (LEDs). However, IS relies on a system response being linear with its input such that a time invariant impedance can be defined. This is usually achieved by a small amplitude input. However, doing so suppresses responses of the nonlinear processes which are of considerable interest to those designing and optimizing these devices, such as charge carrier recombination and space charge effects. This investigation employs the recently developed nonlinear extension to IS (NLIS) based in Fourier analysis of …

Two-Dimensional Bose–Hubbard Model For Helium On Graphene, Jiangyong Yu

Graduate College Dissertations and Theses

An exciting development in the field of correlated systems is the possibilityof realizing two-dimensional (2D) phases of quantum matter. For a systems of bosons, an example of strong correlations manifesting themselves in a 2D environment is provided by helium adsorbed on graphene. We construct the effective Bose-Hubbard model for this system which involves hard-core bosons (U ≈ ∞) and repulsive nearest-neighbor (V > 0) interactions. In this work, we focus on the calculations of single particle properties of the model such as the hopping parameter t. This is accomplished via Wannier Theory and Band structure calculations, which proves to be reliable …

Quantifying Language Changes Surrounding Mental Health On Twitter, Anne Marie Stupinski

Graduate College Dissertations and Theses

Mental health challenges are thought to afflict around 10% of the global population each year, with many going untreated due to stigma and limited access to services. Here, we explore trends in words and phrases related to mental health through a collection of 1- , 2-, and 3-grams parsed from a data stream of roughly 10% of all English tweets since 2012. We examine temporal dynamics of mental health language, finding that the popularity of the phrase ‘mental health’ increased by nearly two orders of magnitude between 2012 and 2018. We observe that mentions of ‘mental health’ spike annually and …

Developing Natural Language Processing Instruments To Study Sociotechnical Systems, Thayer Alshaabi

Graduate College Dissertations and Theses

Identifying temporal linguistic patterns and tracing social amplification across communities has always been vital to understanding modern sociotechnical systems. Now, well into the age of information technology, the growing digitization of text archives powered by machine learning systems has enabled an enormous number of interdisciplinary studies to examine the coevolution of language and culture. However, most research in that domain investigates formal textual records, such as books and newspapers. In this work, I argue that the study of conversational text derived from social media is just as important. I present four case studies to identify and investigate societal developments in …

Multiscale Assessment Of Drinking Water Treatment Residuals As A Phosphorus Sorbing Amendment In Stormwater Bioretention Systems, Michael Rick Ament

Graduate College Dissertations and Theses

Bioretention systems can reduce stormwater runoff volumes and filter pollutants. However, bioretention soil media can have limited capacity to retain phosphorus (P), and can even be a P source, necessitating P-sorbing amendments. Drinking water treatment residuals (DWTRs) have promise as a bioretention media amendment due to their high P sorption capacity. This research explores the potential for DWTRs to mitigate urban P loads using a combination of lab experiments, field trials, and an urban watershed model.

In the laboratory portion of this research, I investigated possible tradeoffs between P retention and hydraulic conductivity in DWTRs to inform bioretention media designs. …

Developing An Adaptive Resource Management Framework For Sustainable Cashmere Production In Mongolia, Elisabeth Lohre

Graduate College Dissertations and Theses

Cashmere is a multi-billion dollar commodity and recent increases in demand have led to the degradation of grassland and desert steppe ecosystems in East and Central Asia. Cashmere wool is a product of goats and 90% of the world’s supply originates from Mongolia and northern China. As global demand for cashmere increases, the consequences to the natural landscapes and people of the region may be severe, especially given the rapid rate of environmental change due to warming climatic conditions in the region.

Textile manufacturers recognize the need for better goat herding practices and support the development of a sustainable cashmere …

Language-Based Analysis Of Differential Privacy, Chukwunweike Abuah

Graduate College Dissertations and Theses

Differential privacy (Dwork, 2006; Dwork et al., 2006a) has achieved prominence over the past decade as a rigorous formal foundation upon which diverse tools and mechanisms for performing private data analysis can be built. The guarantee of differential privacy is that it protects privacy at the individual level: if the result of a differentially private query or operation on a dataset is publicly released, any individual present in that dataset can claim plausible deniability. This means that any participating individual can deny the presence of their information in the dataset based on the query result, because differentially private queries introduce …

Geomechanical, Geochemical, And Hydrological Aspects Of Co2 Injection Into Saline Reservoirs, Maziar Foroutan

Graduate College Dissertations and Theses

Carbon dioxide Capturing, and Sequestration (CCS) is a promising technique that helps mitigate the amount of CO2 emitted into the atmosphere. CCS process mainly involves capturing CO2 at the industrial plant, followed by transportation and injection into a suitable geological storage, under supercritical conditions. Saline aquifers are among the best geological storage candidates due to their availability, high storage capacity and injectivity. Despite the CCUS technology promise, several public safety concerns remain to be address, including but not limited to reservoir/wellbore stability and integrity, CO2 leakage, ground deformation (uplift) and induced seismicity.

The injected supercritical CO2 is trapped through different …

Establishing Behavioral Baselines For Computational Systems: Two Case Studies, John Henry Ring

Graduate College Dissertations and Theses

The behavior of modern systems lives in a complex landscape that is unique to its particular application. In this work we describe and analyze the behavior of two modern computational systems: a Linux server and the National Market System (NMS). Though this work is diverse in both the type and scale of system under study, it is unified through the design and implementation of computationally tractable quantitative metrics aimed at defining the state of behavior of these systems. Understanding the behavior of these systems allows us to ensure their desired operation. In the case of a server we need to …

Lcms-Based Analysis Explains The Basis Of Oxidative Resistance In Selenium-Containing Thioredoxin Reductase, Daniel Haupt

Graduate College Dissertations and Theses

Selenocysteine (Sec) is referred to as the 21st proteogenic amino acid and is found in place of the redox-sensitive amino acid cysteine (Cys) in a small number of proteins. Sec and Cys carry out similar chemistry and are structural isomers save for a single atom difference; the former contains selenium (Se), while the latter contains sulfur (S) in the identical position. Sec poses a high bioenergetic cost for its synthesis and subsequent incorporation into protein not shared by Cys. Since Sec’s discovery in 1976, scientists have debated why certain proteins express Sec while others express Cys. In recent years, it …

Exploring Hidden Networks Yields Important Insights In Disparate Fields Of Study, Laurence Clarfeld

Graduate College Dissertations and Theses

Network science captures a broad range of problems related to things (nodes) and relationships between them (edges). This dissertation explores real-world network problems in disparate domain applications where exploring less obvious "hidden networks" reveals important dynamics of the original network.

The power grid is an explicit network of buses (e.g., generators) connected by branches (e.g., transmission lines). In rare cases, if k branches (a k-set) fail simultaneously, a cascading blackout may ensue; we refer to such k-sets as "defective". We calculate system risk of cascading failure due to defective 2-sets and 3-sets in synthetic test cases of the Polish and …

Multiscale Modeling Of Biological Complexes: Strategy And Application, Xiaochuan Zhao

Graduate College Dissertations and Theses

Simulating protein complexes on large time and length scales is often intractable at the atomistic resolution. To address this challenge, we have developed new approaches to integrate coarse-grained (CG), mixed-resolution (referred to as AACG throughout this dissertation), and all-atom (AA) modeling for different stages in a single molecular simulation. First, we developed a top-down multiscale modeling approach — a new approach, which combines CG, AACG, and AA modeling — to simulate peptide self-assembly from monomers. We simulated the initial encounter stage with the CG model, while the further assembly and reorganization stages are simulated with the AACG and AA models. …