Physical Sciences and Mathematics Commons^™

The Progressive Evolution Of The Champlain Thrust Fault Zone: Insights From A Structural Analysis Of Its Architecture, Matthew Merson

Graduate College Dissertations and Theses

Near Burlington, Vermont, the Champlain Thrust fault placed massive Cambrian dolostones over calcareous shales of Ordovician age during the Ordovician Taconic Orogeny. Although the Champlain Thrust has been studied previously throughout the Champlain Valley, the architecture and structural evolution of its fault zone have never been systematically defined. To document these fault zone characteristics, a detailed structural analysis of multiple outcrops was completed along a 51 km transect between South Hero and Ferrisburgh, Vermont.

The Champlain Thrust fault zone is predominately within the footwall and preserves at least four distinct events that are heterogeneous is both style and slip direction. …

Market Efficiency In U.S. Stock Markets: A Study Of The Dow 30 And The S&P 30, Colin Michael Van Oort

Graduate College Dissertations and Theses

The U.S. National Market System (NMS), the largest marketplace in the world for securities and exchange traded funds, suffers from geographic market fragmentation which leads to reduced market efficiency.

Communication lines transmit price updates and other information between geographically isolated exchanges at varying speeds, bounded above by the speed of light.

Market participants have access to federally mandated information provided by the Securities Information Processor (SIP) and privately offered information provided by the exchanges, often called direct feeds.

These feeds are quantitatively and qualitatively distinct, with the direct feeds tending to provide more information at a faster rate than the …

Governing Environmental And Economic Flows In Regional Food Systems, Michael Bishop Wironen

Graduate College Dissertations and Theses

Globalization, specialization, and intensification have transformed the global food system, generating material flows and impacts that span multiple scales and levels, presenting novel governance challenges. Many argue for a transition toward a sustainable food system, although the scope and specific goals are fiercely contested. Theory and method is needed to evaluate competing normative claims and build legitimacy.

In this dissertation Vermont serves as a case study to investigate how environmental and economic flows impact regional governance, focusing on efforts to manage agricultural phosphorus to achieve water quality goals. A material flow account is developed to estimate phosphorus flows embedded in …

Fluvial Processes In Motion: Measuring Bank Erosion And Suspended Sediment Flux Using Advanced Geomatic Methods And Machine Learning, Scott Douglas Hamshaw

Graduate College Dissertations and Theses

Excessive erosion and fine sediment delivery to river corridors and receiving waters degrade aquatic habitat, add to nutrient loading, and impact infrastructure. Understanding the sources and movement of sediment within watersheds is critical for assessing ecosystem health and developing management plans to protect natural and human systems. As our changing climate continues to cause shifts in hydrological regimes (e.g., increased precipitation and streamflow in the northeast U.S.), the development of tools to better understand sediment dynamics takes on even greater importance. In this research, advanced geomatics and machine learning are applied to improve the (1) monitoring of streambank erosion, (2) …

Applying Bayesian Belief Network To Understand Public Perception On Green Stormwater Infrastructures In Vermont, Qing Ren

Graduate College Dissertations and Theses

Decisions of adopting best management practices made on residential properties play an important role in reduction of nutrient loading from non-point sources into Lake Champlain and other waterbodies in Vermont. In this study, we use Bayesian belief network (BBN) to analyze a 2015 survey dataset about adoption of six types of green infrastructures (GSIs) in Vermont’s residential areas. Learning BBNs from physical probabilities of the variables provides a visually explicit approach to reveal the message delivered by the dataset. Using both unsupervised and supervised machine learning algorithms, we are able to generate networks that connect the variables of interest and …

An Autothermal, Representative Scale Test Of Compost Heat Potential Using Geostatistical Analysis, William J. Mccune-Sanders

Graduate College Dissertations and Theses

Composting has been practiced for thousands of years as a way of stabilizing and recycling organic matter into useful soil amendments. Thermophilic compost releases significant amounts of heat at temperatures (~140 °F) that are useful for environmental heating or process water. This heat has been taken advantage of in various ways throughout history, but development of a widely adopted technology remains elusive.

The biggest barrier to adoption of compost heat recovery (CHR) systems is projecting accurate, attractive economic returns. The cost of transfer equipment is significant, and with variability in composting substrates and methods, it is difficult to predict the …

Bottom-Up Adaptive Management And Stakeholder Participation For Clean Water And Healthy Soils In A Complex Social-Ecological System, Sarah Coleman

Graduate College Dissertations and Theses

Protection of water resources in a changing climate depends on bottom-up stewardship and adaptive management. From the ground up, a vital component is maintaining soil ecosystem services that regulate water, recycle nutrients, sequester carbon, provide food, and other benefits. Interacting spatial, social, and physical factors determine agricultural and stormwater management, and their impact on water. This dissertation explores these dimensions within a complex social-ecological system. The first chapter evaluates a participatory process to elicit solutions to complex environmental problems across science, policy, and practice. The second chapter studies on-farm soil assessment and its role in informing management decisions and supporting …

Consumer Engagement With Efficient And Renewable Energy Technology: Case Studies On Smart Meter Utilization And Support For A Community Anaerobic Biodigester System In Vermont, Samantha Whitney Lewandowski

Graduate College Dissertations and Theses

Residential electricity consumption in the United States has many adverse impacts, such as greenhouse gas emissions, dependence on fossil fuels, and costs. Efficient and renewable energy technologies have the potential to help mitigate some of these impacts, but appear to be under-utilized in the United States. One major barrier to expanding the deployment of these kinds of technologies and maximizing the benefits they can provide is a lack of consumer engagement. The overall purpose of this thesis is to better understand the extent to which efficient and renewable energy technologies are being engaged with and what factors may influence such …

From Sea To Lake: The Depositional History Of Saint Albans Bay, Vt, Usa, Matthew Kraft

Graduate College Dissertations and Theses

Sediment accumulated in lakes stores valuable information about past environments and paleoclimatological conditions. Cores previously obtained from Saint Albans Bay, located in the Northeast Arm of Lake Champlain, VT record the transition from the Champlain Sea to Lake Champlain. Belrose (2015) documented the presence of a peat horizon separating the sediments of the Champlain Sea from those of Lake Champlain. Initially, this layer was thought to comprise the transition from the marine environment of the Champlain Sea to a freshwater wetland. However, based on the results from this study, the transition between marine and freshwater conditions is thought to be …

Networks, (K)Nots, Nucleotides, And Nanostructures, Ada Morse

Graduate College Dissertations and Theses

Designing self-assembling DNA nanostructures often requires the identification of a route for a scaffolding strand of DNA through the target structure. When the target structure is modeled as a graph, these scaffolding routes correspond to Eulerian circuits subject to turning restrictions imposed by physical constraints on the strands of DNA. Existence of such Eulerian circuits is an NP-hard problem, which can be approached by adapting solutions to a version of the Traveling Salesperson Problem. However, the author and collaborators have demonstrated that even Eulerian circuits obeying these turning restrictions are not necessarily feasible as scaffolding routes by giving examples of …

Exploration Of Zirconium-Catalyzed Intermolecular Hydrophosphination With Primary Phosphines: Photocatalytic Single And Double Hydrophosphination, Christine Anne Bange

Graduate College Dissertations and Theses

Catalytic hydrophosphination has enormous potential in the selective preparation of value-added organophosphines, despite the challenge of the reaction. This dissertation aims to address the hurdles in catalytic hydrophosphination with respect to substrate scope, selectivity, and reaction conditions using [қ5 –N,N,N,N,C– (Me3SiNCH2CH2)2NCH2CH2NSiMe2CH2]Zr (1).

Compound 1 readily engages with a suite of primary phosphines. These are challenging substrates for this reaction, but 1 readily provides high conversions with these substrates. Increasingly large primary phosphines, including chiral phosphines, undergo catalysis with 1. Furthermore, a variety of underreported unsaturated substrates can be functionalized in catalytic hydrophosphination with 1. Alkynes are underreported substrates, but 1 …

Some Results On A Class Of Functional Optimization Problems, David Rushing Dewhurst

Graduate College Dissertations and Theses

We first describe a general class of optimization problems that describe many natu- ral, economic, and statistical phenomena. After noting the existence of a conserved quantity in a transformed coordinate system, we outline several instances of these problems in statistical physics, facility allocation, and machine learning. A dynamic description and statement of a partial inverse problem follow. When attempting to optimize the state of a system governed by the generalized equipartitioning princi- ple, it is vital to understand the nature of the governing probability distribution. We show that optimiziation for the incorrect probability distribution can have catas- trophic results, e.g., …

Quantification Of Mouse Cardiac Troponin I And Myosin Binding Protein C Phosphorylation By Liquid Chromatography-Mass Spectrometry (Lc-Ms), Praveena Nukareddy

Graduate College Dissertations and Theses

Heart failure is a major public health issue, with its prevalence estimated to be 6.5 million adults in the USA. Of the hospitalized heart failure (HF) cases, 50% are characterized by preserved ejection function (HFpEF). In HFpEF, the heart pumps a normal proportion of blood that enters it. However, thickening of the ventricular walls inhibits the chamber filling to normal volume. The direct basis of HFpEF is a slowed elongation of the cardiac muscle during the diastolic phase of the cardiac cycle. Elucidation of mechanisms that mediate relaxation of cardiac muscle could help understand the pathogenic mechanisms in HFpEF.

Myocardial …

Novelty Detection Of Machinery Using A Non-Parametric Machine Learning Approach, Enrique Angola

Graduate College Dissertations and Theses

A novelty detection algorithm inspired by human audio pattern recognition is conceptualized and experimentally tested. This anomaly detection technique can be used to monitor the health of a machine or could also be coupled with a current state of the art system to enhance its fault detection capabilities. Time-domain data obtained from a microphone is processed by applying a short-time FFT, which returns time-frequency patterns. Such patterns are fed to a machine learning algorithm, which is designed to detect novel signals and identify windows in the frequency domain where such novelties occur. The algorithm presented in this paper uses one-dimensional …

Pharmaceutical Waste In Vermont: Results From A Survey On Purchasing, Use & Disposal, Christine Hart

Graduate College Dissertations and Theses

Pharmaceutical waste is an emerging form of waste with significant impacts on the environment. This study reports the results of a state-wide phone survey on pharmaceutical purchasing, use and disposal behavior among Vermont residents (n = 421). The objectives of this study were: 1) to compare the demographic nature of populations who purchase and use medicaton to those associated with leftover medication, and 2) to evaluate the impact of disposal behavior in Vermont and to recommend strategies to minimize pollution. The findings of this study showed that approximately 93% of survey participants reported purchasing of medication, 60% reported leftover medication …

Application Of Geophysical And Geochronological Methods To Sedimentologic And Stratigraphic Problems In The Lower Cambrian Monkton Formation: Northwestern Vermont, Henry C. Maguire

Graduate College Dissertations and Theses

The Monkton Formation of the western shelf stratigraphic sequence in Vermont (VT) is identified as a Lower Cambrian regressive sandstone unit containing parasequences recording tidal flat progradation. Previous workers identified cycles believed to represent parasequences in a portion of a 1034' deep geothermal well drilled at Champlain College in Burlington, Vermont. For this study, both outcrop and well geophysical surveys were completed to better identify gamma emission curves and relative values for parasequences and select lithologies that are indicators of bathymetry and sea level. After using physical stratigraphic techniques to assemble a composite stratigraphic section for the Monkton Formation, analysis …

Geochronological Constraints On The Timing Of Deformation: An Examination Of The Prospect Rock Fault Footwall In North-Central Vermont, Evan Tam

Graduate College Dissertations and Theses

The Prospect Rock Fault (PRF) is key to our understanding of the regional tectonic evolution of Vermont during the Taconic, Salinic, and Acadian Orogenies, and may have played an important role in the exhumation of blueschist and eclogite-facies rocks in the Tillotson Peak Complex (TPC) during the Taconic Orogeny. The TPC is in the footwall of the PRF in the eastern limb of the Green Mountain Anticlinorium. In the TPC, the dominant foliation is S2 and E-W trending F2 folds parallel L2 stretching lineations, which trend orthogonal to regional N-S trending folds associated with the Taconic Orogeny. The PRF itself …

Geochronologic Constraints On The Timing Of Metamorphism And Exhumation Of The Tillotson Peak Complex In Northern Vermont, Cheyne Aiken

Graduate College Dissertations and Theses

The Tillotson Peak Complex (TPC) in northern Vermont records high-pressure (HP) subduction zone metamorphism that occurred during the Ordovician Taconic Orogeny, and subsequent retrograde metamorphism and deformation that occurred during the Silurian Salinic Orogeny. Previous studies have documented a polymetamorphic history, with peak metamorphic pressures possibly up to 2.5 GPa and temperatures of 550°C. Prior to this research, constraints on the timing of metamorphism in the TPC were limited to a single Middle Ordovician 40Ar/39Ar total fusion age for glaucophane. This study integrates 40Ar/39Ar step heating analyses of multiple mineral phases and U-Pb dating of titanite with field and microstructural …

Spectroscopic Insight Into Oxidative Heme Cleavage By The Non-Canonical Heme Oxygenase Isdg From Staphylococcus Aureus, Matthew A. Conger

Graduate College Dissertations and Theses

IsdG and IsdI are non-canonical heme oxygenases (HO) from Staphylococcus aureus that catalyze the oxidative cleavage of heme to give novel organic products (staphylobilins) and iron as a nutrient for the pathogen. Comparison of the reported equilibrium dissociation constant (Kd) values for heme from IsdG and IsdI compared to the reported concentration of the labile heme pool called into question whether these enzymes are competent HOs in vivo. We took advantage of a second-sphere Trp whose fluorescence is quenched upon heme binding, which led to Kd values 2-3 orders of magnitude smaller than reported in the literature. Importantly, these Kd …

Combining Observations Of Soils And Streams To Investigate Trends Caused By Reduced Acid Depositon In The Sleepers River Watershed, Jesse Armfield

Graduate College Dissertations and Theses

Acid deposition forms when emission-derived sulfur dioxide and nitrogen oxides interact with precipitation and was particularly severe in the northeastern US. Effects of acid deposition include declining soil quality due to low pH and base cation leaching, which subsequently altered the composition of soil solution, ground water (GW) and eventually stream water. Because of the high buffering capacity of carbonates, watersheds underlain by carbonate rich rocks have received limited attention in acid deposition studies, however, carbonate weathering by strong anthropogenic acids can increase atmospheric CO2 levels.

Emission reductions due to the Clean Air Act and Amendments has led to a …

Regularization In Symbolic Regression By An Additional Fitness Objective, Ryan Grindle

Graduate College Dissertations and Theses

Symbolic regression is a method for discovering functions that minimize error on a given dataset. It is of interest to prevent overfitting in symbolic regression. In this work, regularization of symbolic regression is attempted by incorporating an additional fitness objective. This new fitness objective is called Worst Neighbors (WN) score, which measures differences in approximate derivatives in the form of angles. To compute the Worst Neighbors score, place partition points between each pair of adjacent data points. For each pair of data points, compute the maximum angle between the line formed by the pair of data points and the lines …

Microscale Controls On Lead Speciation In Soils: A Framework For Sustainable Remediation, Grant Reeder

Graduate College Dissertations and Theses

The potential of a soil to immobilize heavy metal ions is dependent on the presence of adsorption sites, and the stability of metal species over the range of geochemical conditions present in the soil over time. Lead (Pb) is a cumulative toxin that is enriched in much of the urban pedosphere due to historical use of Pb-based paint and Pb-amended gasoline. Because in-situ remediation of Pb is possible if the bioavailable fraction can be rendered inert, understanding Pb-sorbent interactions is necessary to accurately and efficiently alter Pb speciation in soils. The objectives of this study are to 1) determine efficient …

Conservation Of Ecosystem Services And Biodiversity In Vermont, Usa, Keri B. Watson

Graduate College Dissertations and Theses

Supporting a growing human population while avoiding biodiversity loss is a central challenge towards a sustainable future. Ecosystem services are benefits that people derive from nature. People have drastically altered the earth’s land surface in the pursuit of those ecosystem services that have been ascribed market value, while at the same time eroding biodiversity and non-market ecosystem services. The science required to inform a more balanced vision for land-cover change in the future is rapidly developing, but critical questions remain unanswered regarding how to quantify ecosystem services and ascribe value to them, and how to coordinate efforts to safeguard multiple …

Cargo Transport By Myosin Va Molecular Motors Within Three-Dimensional In Vitro Models Of The Intracellular Actin Cytoskeletal Network, Andrew Thomas Lombardo

Graduate College Dissertations and Theses

Intracellular cargo transport involves the movement of critical cellular components (e.g. vesicles, organelles, mRNA, chromosomes) along cytoskeletal tracks by tiny molecular motors. Myosin Va motors have been demonstrated to play a vital role in the transport of cargos destined for the cell membrane by navigating their cargos through the three-dimensional actin networks of the cell. Transport of cargo through these networks presents many challenges, including directional and physical obstacles which teams of myosin Va-bound to a single cargo must overcome. Specifically, myosin Va motors are presented with numerous actin-actin intersections and dense networks of filaments which can act as a …

Genetic And Demographic Consequences Of Lake And River Habitat Fragmentation On Fishes In Vermont, Peter T. Euclide

Graduate College Dissertations and Theses

Globally, habitat fragmentation has had a major impact on the conservation and management of many species and is one of the primary causes of species extinction. Habitat fragmentation is loosely defined as a process in which a continuous habitat is reduced to smaller, disconnected patches as the result of habitat loss, restriction of migration or the construction of barriers to movement. Aquatic systems are particularly vulnerable to habitat fragmentation, and today an estimated 48% of rivers are fragmented worldwide. My dissertation evaluates how habitat fragmentation has influenced the populations of four different species of fish in the Lake Champlain basin. …

The Synthesis Of Highly Substituted Aromatics And The Reaction Of Alkene Pi Systems With Vinyl Cations, Nicholas Jarrod Dodge

Graduate College Dissertations and Theses

Aldol cyclotrimerizations have been used to achieve the rational chemical synthesis of both fullerenes and fullerene fragments in the past. Under certain conditions this reaction produces the corresponding cyclotetramer which has sometimes been regarded as an undesired byproduct. This work details efforts to synthesize and use these cyclotetramers toward a synthesis of a C240 fullerene fragment. One principal focus in this work is tridecacyclene, a cyclic tetramer of acenaphthylene given its name by our group for its thirteen rings. Relatively low yields for the synthesis of tridecacyclene and its derivatives drove us to investigate the mechanism of its formation and …

Land Use, Power, And Knowledge At The Northern Resource Frontier: Mining, Public Engagement, And Contentious Land Imaginaries In Bristol Bay And The Yukon-Kuskokwim Delta, Jonathan Tollefson

Graduate College Dissertations and Theses

The Donlin and Pebbles mines are two of the eight industrial-scale hard rock mines currently under the review of Alaska’s Large Mine Permitting program. Both projects promise to deliver profit and employment to their respective regions: Pebble to Bristol Bay in the southwest, and Donlin to the Yukon-Kuskokwim Delta, just north of Pebble. Both projects would also produce exceptional quantities of waste and will require almost-unprecedented infrastructure development, potentially threatening the lives and subsistence livelihoods of the Alaska Native peoples in their respective regions. The Pebble project inspired international protest and led to the emergence of a powerful resistance coalition …

Smart Classifiers And Bayesian Inference For Evaluating River Sensitivity To Natural And Human Disturbances: A Data Science Approach, Kristen Underwood

Graduate College Dissertations and Theses

Excessive rates of channel adjustment and riverine sediment export represent societal challenges; impacts include: degraded water quality and ecological integrity, erosion hazards to infrastructure, and compromised public safety. The nonlinear nature of sediment erosion and deposition within a watershed and the variable patterns in riverine sediment export over a defined timeframe of interest are governed by many interrelated factors, including geology, climate and hydrology, vegetation, and land use. Human disturbances to the landscape and river networks have further altered these patterns of water and sediment routing.

An enhanced understanding of river sediment sources and dynamics is important for stakeholders, and …

No Farm Is An Island: Pollinators And Pollination In Agricultural Landscapes, Charles C. Nicholson

Graduate College Dissertations and Theses

Productive, resilient and sustainable agricultural systems are required to meet the immediate needs of a burgeoning human population, while avoiding ecosystem collapse. Agriculture provides food, fiber, fuels and other products for our current population of 7 billion and is still the major livelihood for 40% of people worldwide. By replacing natural habitat and employing chemical inputs, agriculture also negatively impacts biodiversity and impairs the provision of ecosystem services. This poses a challenge for agriculture as these impacted services are often those required for high yielding and high-quality crop production. Evidence is accumulating that agricultural management can safeguard biodiversity and ecosystem …

Cityscape Connections: National Park Service Relevance And Resilience In Urban Areas, Elizabeth Eleanor Perry

Graduate College Dissertations and Theses

The National Park Service (NPS) strives to embody U.S. democratic ideals, conserving our collective stories and scenery for their intrinsic value and the enjoyment of current and future generations. However, although these places are conserved for all, they are not enjoyed by all. As with other conservation agencies, the NPS finds itself increasingly concerned with building relevance with diverse potential stewards. In cities, where 80% of the U.S. population and 40% of the NPS portfolio is based, there is a prime opportunity to build relevance with large, diverse, and proximate audiences. Recognizing this opportunity, the NPS initiated its Urban Agenda …