Physical Sciences and Mathematics Commons^™

Choices And Preferences Of Vermont Master Gardeners - Do Socio-Demographics Matter?, Grace Matiru

Graduate College Dissertations and Theses

ABSTRACT

This study was designed to characterize the choices, preferences and motivations of fruit and vegetable gardeners in Vermont, and to determine whether socio-demographic characteristics affect some of these choices, preferences and motivations. Using a survey of Vermont Extension Master Gardeners (EMGs), data were gathered over a 3-year period (2011-2013). The findings show most EMGs (>90%) garden in private home gardens, and the most popular vegetables grown were tomatoes, herbs, and salad greens. Beans, cucumbers and peppers sere also popular and among fruits, blueberries, apples, raspberries and strawberries were grown by over 40% of EMGs. Approximately 10% of EMG …

Silica Nanoparticles For The Delivery Of Dna And Rnai In Cancer Treatment, Michael Aaron Vrolijk

Graduate College Dissertations and Theses

DNA and interfering RNA (RNAi) – short interfering RNA (siRNA) and micro RNA (miRNA) – are promising new cancer therapies, especially for drug resistant lines. However, they require a delivery system in vivo to prevent degradation and off target effects. Silica based nanoparticles, both solid and mesoporous, are a promising option due to their biocompatibility, ease of preparation and morphology control, reproducibility, and facile addition of functional groups including targeting ligands.

After a brief introduction to cancer treatment and review of the current nanoparticle treatments undergoing clinical trials, this thesis details the many methods explored over the past ten years …

Estimating Landscape Quality And Genetic Structure Of Recovering American Marten Populations In The Northeastern United States, Cody Michael Aylward

Graduate College Dissertations and Theses

The American marten (Martes americana) is an endangered species in Vermont and a Regional Species of Greatest Conservation Need in the northeastern United States. Though historically widespread in northeastern forests, their range presumably contracted to northern Maine and the High Peaks region of the Adirondacks by the early 1900s. Regionally, populations appear to be in recovery. Natural recolonization is believed to have occurred in New Hampshire, northeastern Vermont and the western Adirondacks. A reintroduction effort in southern Vermont that was originally declared unsuccessful is now believed to be the source of a recently detected population in the area. However, our …

An Exposition Of Selberg's Sieve, Jack Dalton

Graduate College Dissertations and Theses

A number of exciting recent developments in the field of sieve theory have been done concerning bounded gaps between prime numbers. One of the main techniques used in these papers is a modified version of Selberg's Sieve from the 1940's. While there are a number of sources that explain the original sieve, most, if not all, are quite inaccessible to those without significant experience in analytic number theory. The goal of this exposition is to change that. The statement and proof of the general form of Selberg's sieve is, by itself, difficult to understand and appreciate. For this reason, the …

Detecting Landscape Response To Perturbations By Climate And Base Level In Central Pennsylvania Using In-Situ 10be And 26al, Alison R. Denn

Graduate College Dissertations and Theses

The change of topography with time and the consequent structure of Earth's surface is dependent on the production and transport of weathered bedrock. I use measurements of in-situ cosmogenic 10Be to investigate erosion rates and exposure ages of boulders, streams, and hillslope sediments in central Pennsylvania, a landscape shaped by glacial/interglacial climate cycles and changes in base level. I measure rates of landscape change at three separate sites, Hickory Run boulder field, Young Womans Creek watershed, and Garner Run, a small upland catchment bounded by two ridgelines.

Hickory Run Boulder field is the largest of its kind in the eastern …

Accelerating Quantum Monte Carlo Via Graphics Processing Units, Benjamin Evert Himberg

Graduate College Dissertations and Theses

An exact quantum Monte Carlo algorithm for interacting particles in the spatial continuum is extended to exploit the massive parallelism offered by graphics processing units. Its efficacy is tested on the Calogero-Sutherland model describing a system of bosons interacting in one spatial dimension via an inverse square law. Due to the long range nature of the interactions, this model has proved difficult to simulate via conventional path integral Monte Carlo methods running on conventional processors. Using Graphics Processing Units, optimal speedup factors of up to 640 times are obtained for N = 126 particles. The known results for the ground …

Quantifying Tree Response To Alterations In Pollution Deposition And Climate Change In The Northeastern Us, Alexandra M. Kosiba

Graduate College Dissertations and Theses

Understanding tree physiological responses to climate change is critical for quantifying forest carbon, predicting species' range change, and forecasting growth trajectories. Continued increases in temperature could push trees into conditions to which they are ill adapted -- such as decreased depth of winter snow cover, altered water regimes, and a lengthened effective growing season. A complicating factor is that in the northeastern United States, climate change is occurring on a backdrop of acid deposition and land-use change. In this dissertation, I used three studies to investigate the spatiotemporal nuances of resultant tree and sapling physiology to environmental change.

First, I …

Wronskian And Gram Solutions To Integrable Equations Using Bilinear Methods, Benjamin Wiggins

Graduate College Dissertations and Theses

This thesis presents Wronskian and Gram solutions to both the Korteweg-de Vries and Kadomtsev-Petviashvili equations, which are then scalable to arbitrarily large numbers of interacting solitons.

Through variable transformation and use of the Hirota derivative, these nonlinear partial differential equations can be expressed in bilinear form. We present both Wronskian and Gram determinants which satisfy the equations.

N=1,2,3 and higher order solutions are presented graphically; parameter tuning and the resultant behavioral differences are demonstrated and discussed. In addition, we compare these solutions to naturally occurring shallow water waves on beaches.

Towards A Science Of Human Stories: Using Sentiment Analysis And Emotional Arcs To Understand The Building Blocks Of Complex Social Systems, Andrew James Reagan

Graduate College Dissertations and Theses

We can leverage data and complex systems science to better understand society and human nature on a population scale through language --- utilizing tools that include sentiment analysis, machine learning, and data visualization.

Data-driven science and the sociotechnical systems that we use every day are enabling a transformation from hypothesis-driven, reductionist methodology to complex systems sciences.

Namely, the emergence and global adoption of social media has rendered possible the real-time estimation of population-scale sentiment, with profound implications for our understanding of human behavior.

Advances in computing power, natural language processing, and digitization of text now make it possible to study …

The Role Of N-Terminal Acidic Inserts On The Dynamics Of The Tau Protein., Miranda Redmond

Graduate College Dissertations and Theses

Alzheimer’s disease (AD), the most prevalent neurodegenerative disease, is characterized in part by disruptions in axonal transport. Axonal transport is a process by which motor proteins carry organelles and other cargo made in the neuronal cell body along microtubule tracks to distal regions of the axon. The microtubule-associated protein (MAP) Tau plays a crucial role in regulating axonal transport, and is implicated in the development of AD and other types of dementia collectively known as Tauopathies. Tau is a neuronal-specific MAP that has six isoforms alternatively spliced from a single gene. These isoforms differ by the presence of zero, one, …

What’S In Your Body Of Water? Reducing The Psychological Distance Of Pharmaceutical Pollution Through Metaphor In Risk Communication, Alexandra Z. Millarhouse

Graduate College Dissertations and Theses

Aquatic pharmaceutical pollution poses ecotoxicological risks to the environment and human health. Consumer attitudes and behavior represent a significant source of pharmaceutical compounds found in water. Thus, understanding public perceptions of aquatic pharmaceutical pollution and developing effective risk communication techniques are critical to engaging society in the type of widespread change necessary for addressing the presence of pharmaceuticals in water. This mixed-methods study applies conceptual metaphor theory in conjunction with construal level theory of psychological distance to assess how metaphoric framing affects perceptions of aquatic pharmaceutical contamination across four principal dimensions of psychological distance (geographic, social and temporal distance and …

Weighted Networks: Applications From Power Grid Construction To Crowd Control, Thomas Charles Mcandrew

Graduate College Dissertations and Theses

Since their discovery in the 1950's by Erdos and Renyi, network theory (the study of objects and their associations) has blossomed into a full-fledged branch of mathematics.

Due to the network's flexibility, diverse scientific problems can be reformulated as networks and studied using a common set of tools.

I define a network G = (V,E) composed of two parts: (i) the set of objects V, called nodes, and (ii) set of relationships (associations) E, called links, that connect objects in V.

We can extend the classic network of nodes and links by describing the intensity of these associations with weights. …

Shaping Policy In The Anthropocene: Gender Justice As A Social, Economic And Ecological Challenge, Phoebe Spencer

Graduate College Dissertations and Theses

Environmental pressures such as natural disasters, resource scarcity, and conflict related to climate change have emphasized the importance of considering social justice within its ecological context. Gender inequality is one type of injustice that has traditionally been addressed as a social matter, yet gendered divisions in bargaining power, mobility, and access to resources are exacerbated by environmental instability. One barrier to gender equity in the face of a changing climate is the mainstream economic paradigm, which promotes growth and individualism, often at the cost of environmental and social wellbeing. The issue of gender inequality in the Anthropocene, the proposed geological …

The Use Of Bokashi As A Soil Fertility Amendment In Organic Spinach Cultivation, Dana Mae Christel

Graduate College Dissertations and Theses

Soil fertility management presents the organic farmer with assorted challenges. Organic farmers generally don't follow the typical nutrient prescription approach for fertilizing crops as their conventional counterparts do, having to respond to criteria established by the USDA National Organic Program (NOP). Instead they aim towards improving the organic matter and biological activity of soil. Often this is achieved through the use of composts, either made on farm or purchased. Yet, composting presents challenges to the farmer too, requiring considerable land base, specialized equipment, and attention to various parameters to ensure compost meets NOP standards. There are alternatives to composts that …

Regeneration Responses To Management For Old-Growth Characteristics In Northern Hardwood-Conifer Forests, Aviva Joy Gottesman

Graduate College Dissertations and Theses

Silviculture practices interact with multiple sources of variability to influence regeneration trends in northern hardwood forests. There is uncertainty whether low-intensity selection harvesting techniques will result in desirable tree regeneration. Our research is part of a long-term study that tests the hypothesis that a silvicultural approach called "structural complexity enhancement" (SCE) can promote accelerated development of late-successional forest structure and functions. Our objective is to understand the regeneration dynamics following three uneven-aged forestry treatments modified to increase postharvest structural retention: single-tree selection, group selection, and SCE. In terms of regeneration densities and composition, how do light availability, competition, seedbad, and …

Spawning Site Selection And Fry Development Of Invasive Lake Trout In Yellowstone Lake, Yellowstone National Park, Wyoming, Lee Simard

Graduate College Dissertations and Theses

Since their discovery in Yellowstone Lake in 1994, Lake Trout (Salvelinus namaycush) have been the object of an intensive gillnet suppression program due to their predation on native Yellowstone Cutthroat Trout (Oncorhynchus clarkii bouvieri). Managers are also interested in targeting early life stages to augment suppression. A benthic sled was used to sample for Lake Trout eggs at 24 locations, hypothesized to be spawning sites, that encompassed a range of depths, slopes, and substrate composition to determine the location and characteristics of spawning sites in Yellowstone Lake. Lake Trout eggs were collected at seven sites, five of which had not …

Education For Sustainability: Exploring Teaching Practices And Perceptions Of Learning Associated With A General Education Requirement, Lisa Watts Natkin

Graduate College Dissertations and Theses

Nationwide, higher education institutions are increasingly interested in infusing sustainability content into their curricula. The world is facing complex and interconnected problems creating a need for college graduates with an understanding of the ecological, economic, and social dimensions of sustainability. There is a shortage of research studying sustainability-related teaching practices, particularly in higher education contexts. The University of Vermont (UVM) recently established Sustainability Learning Outcomes (SLOs) as a general education requirement. As a result of this initiative, sustainability-designated courses are offered across the university that fulfill the requirement, creating a unique opportunity to explore related teaching practices. The purpose of …

Evaluating Alternative Technologies And Monitoring Methods For Water Quality In A Field Setting; Research On Effects On Phosphorous And Solids Removal From Cheese Factory Wash Water And Stormwater Runoff Treatment, Dana J. Allen

Graduate College Dissertations and Theses

Lake Champlain is a major economic driver for Vermont's tourism economy, as well as a primary source of drinking water for many of the state's residents but nutrient pollution represents a potential threat to ecosystem health and economic well-being. From December 2011 to December 2012 a field trial of an EAF steel slag filter was assessed for its feasibility in treating wastewater originating from Swan Valley Cheese (SVC), in Swanton, VT. The study focuses on a period of the filter's operation from May 4 to October 10, 2012. The plant generates approximately 20,000 gallons per day of high P concentration …

Investigation Of Pyrolysis Gas Chemistry In An Inductively Coupled Plasma Facility, Corey Tillson

Graduate College Dissertations and Theses

The pyrolysis mechanics of Phenolic Impregnated Carbon Ablators (PICA) makes it a valued material for use in thermal protection systems for spacecraft atmospheric re-entry. The present study of the interaction of pyrolysis gases and char with plasma gases in the boundary layer over PICA and its substrate, FiberForm, extends previous work on this topic that has been done in the UVM 30 kW Inductively Coupled Plasma (ICP) Torch Facility. Exposure of these material samples separately to argon, nitrogen, oxygen, air, and carbon dioxide plasmas, and combinations of said test gases provides insight into the evolution of the pyrolysis gases as …

Cyclopentadienyl Compounds Of The First Row Transition Metals And Early Actinides: Novel Main-Group Bond Forming Catalysis And New Metallacycles, Justin Kane Pagano

Graduate College Dissertations and Theses

Cyclopentadienyl first row transition-metal compounds have been well studied since the 1950's, with the nearly ubiquitous CpFe(CO)2Me (FpMe) (Cp = η5-C5H5) being one of the first organometallics to be fully characterized. Despite the decades of study that have been poured into this complex, reactions between FpMe and primary phosphines have not been reported. Catalytic reactions with primary phosphines are generally understudied, including dehydrocoupling and P-C bond forming reactions such as hydrophosphination. A novel mechanism of dehydrocoupling and P-C bond formation that has received even more limited attention is α-elimination. This dissertation describes efforts in proving that FpMe is a competent …

Sediment Mobilization From Streambank Failures: Model Development And Climate Impact Studies, Jody Juniper Stryker

Graduate College Dissertations and Theses

This research incorporates streambank erosion and failure processes into a distributed watershed model and evaluates the impacts of climate change on the processes driving streambank sediment mobilization at a watershed scale. Excess sediment and nutrient loading are major water quality concerns for streams and receiving waters. Previous work has established that in addition to surface and road erosion, streambank erosion and failure are primary mechanisms that mobilize sediment and nutrients from the landscape. This mechanism and other hydrological processes driving sediment and nutrient transport are likely to be highly influenced by anticipated changes in climate, particularly extreme precipitation and flow …

Fingerprinting Wolframite: An Atomic/Crystallographic, Chemical And Spectroscopic Study Along The Solid Solution Series, Gina Marie Accorsi

Graduate College Dissertations and Theses

In accordance with the 2010 Dodd-Frank Act, conflict minerals refer to gold, tantalum, tin, and tungsten bearing minerals sourced from the Democratic Republic of Congo (DRC) that have been mined illegally and used to funnel funds to rebel forces. In response to an increasing demand for these metals used in cellphones, computers, and other popular technologies, Dodd-Frank mandates that industrial consumers demonstrate due diligence and assure that the materials they use have been extracted legally. Because current chain-of-custody methods have not been effective in sourcing ores, a study was undertaken whereby the range of mineralogical characteristics of 15 samples along …

Tetrabenzo[8]Circulene: Synthesis And Structural Properties Of Polycyclic Aromatic Hydrocarbons With Negative Curvature, Robert William Miller

Graduate College Dissertations and Theses

Contorted polycyclic aromatic hydrocarbons have found increasing utility in the application of molecular electronics due to the surpamolecular properties that result from these non-planar structures. The [n]circulene series of molecules are particularly attractive members of the contorted aromatic family due to the unique structural implications that result from their changing value of n. For example, when n ≤ 5, the structures adopt a bowl-like shape; when n = 6, a planar structure is observed; and when 7 ≤ n ≤ 16, the compounds assume a saddle-like shape. Very few molecules exhibit the structural contortions that these contorted aromatics do – …

A Formal Approach To Combining Prospective And Retrospective Security, Sepehr Amir-Mohammadian

Graduate College Dissertations and Theses

The major goal of this dissertation is to enhance software security by provably correct enforcement of in-depth policies. In-depth security policies allude to heterogeneous specification of security strategies that are required to be followed before and after sensitive operations. Prospective security is the enforcement of security, or detection of security violations before the execution of sensitive operations, e.g., in authorization, authentication and information flow. Retrospective security refers to security checks after the execution of sensitive operations, which is accomplished through accountability and deterrence. Retrospective security frameworks are built upon auditing in order to provide sufficient evidence to hold users accountable …

Temporal Feature Selection With Symbolic Regression, Christopher Winter Fusting

Graduate College Dissertations and Theses

Building and discovering useful features when constructing machine learning models is the central task for the machine learning practitioner. Good features are useful not only in increasing the predictive power of a model but also in illuminating the underlying drivers of a target variable. In this research we propose a novel feature learning technique in which Symbolic regression is endowed with a ``Range Terminal'' that allows it to explore functions of the aggregate of variables over time. We test the Range Terminal on a synthetic data set and a real world data in which we predict seasonal greenness using satellite …

Role Of Community Social Capital For Acute Food Security Following An Extreme Weather Event, Alana N. Chriest

Graduate College Dissertations and Theses

Worsening climate changes effects are predicted to increase the severity and frequency of extreme weather events (EWE), which can disrupt food systems, from the local to global level, and compromise community food security. In the rural U.S., food insecurity, poverty, low economic growth, and population loss are prevalent, and rural communities often lack the physical capital to bolster community resiliency to climate change adaptation. In 2011, Tropical Storm Irene (TS Irene) in Vermont was the most damaging EWE the state’s history. Severely damaged roads, infrastructure, homes, and land, rendered many rural towns isolated for up to several days. The levels …

Hilbert Class Fields Of Imaginary Quadratic Fields And Reflex Fields Of Certain Sextic Cm Fields, Garvin Gaston

Graduate College Dissertations and Theses

In this thesis we look at particular details of class field theory for complex multiplication fields. We begin by giving some background on fields, abelian varieties, and complex multiplication. We then turn to the first task of this thesis and give an implementation in Sage of a classical algorithm to compute the Hilbert class field of a quadratic complex multiplication field using the j-invariant of elliptic curves with complex multiplication by the ring of integers of the field, and we include three explicit examples to illustrate the algorithm.

The second part of this thesis contains new results: Let K be …

Speciation, Distribution, Prediction, And Mobility Of Lead In Urban Soils: A Multiscale Study, Jennifer Bower

Graduate College Dissertations and Theses

Lead (Pb), a trace metal notorious for its impacts on human health, has achieved worldwide environmental dispersal resulting from centuries of use by human society. The toxicity of Pb is governed largely by its mineral form, which is in turn controlled by pH, localized reactivity and soil processes that differ according to soil type, location and Pb source. Given the context of these localized dependencies, or site specificity, efforts to predict Pb toxicity and refine sustainable remediation techniques are most useful when Pb behavior is constrained and predicted within environments with homogeneous conditions, such as a single soil. I evaluated …

Microwave Bessel-Beam Propagation Through Spatially Inhomogeneous Media, Ryan Francis Grecco

Graduate College Dissertations and Theses

Long range wireless power transmission (WPT) is a critical technology for the development of remote power systems for air and space vehicles as well as for point-to-point transmission on Earth. This can be achieved using either a laser for transmission in the infrared to optical frequency domain or by using microwaves. The objective of this research is to study the application of microwave power transmission (MPT) through the use of a so-called Bessel-beam whose unique propagation properties include a self-healing ability as well as non-diffractive properties. These two unique properties lead to an increase in the efficiency of microwave power …

Predictive Modeling Of Adolescent Cannabis Use From Multimodal Data, Philip Spechler

Graduate College Dissertations and Theses

Predicting teenage drug use is key to understanding the etiology of substance abuse. However, classic predictive modeling procedures are prone to overfitting and fail to generalize to independent observations. To mitigate these concerns, cross-validated logistic regression with elastic-net regularization was used to predict cannabis use by age 16 from a large sample of fourteen year olds (N=1,319). High-dimensional data (p = 2,413) including parent and child psychometric data, child structural and functional MRI data, and genetic data (candidate single-nucleotide polymorphisms, "SNPs") collected at age 14 were used to predict the initiation of cannabis use (minimum six occasions) by age 16. …