Physical Sciences and Mathematics Commons^™

A Bland–Altman Comparison Of The Lead Care® System And Inductively Coupled Plasma Mass Spectrometry For Detecting Low-Level Lead In Child Whole Blood Samples, Christina Sobin, Tanner Schaub, Natali Parisi, Eva De La Riva

Christina Sobin, Ph.D.

Chronic childhood lead exposure, yielding blood lead levels consistently below 10 μg/dL, remains a major public health concern. Low neurotoxic effect thresholds have not yet been established. Progress requires accurate, efficient, and cost-effective methods for testing large numbers of children. The LeadCare® System (LCS) may provide one ready option. The comparability of this system to the “gold standard” method of inductively coupled plasma mass spectrometry (ICP-MS) for the purpose of detecting blood lead levels below 10 μg/dL has not yet been examined. Paired blood samples from 177 children ages 5.2–12.8 years were tested with LCS and ICP-MS. Triplicate repeat tests …

Rare's Implementation Strategies Of Environmental Conservation In Indonesia, Alvaro Arvizo

Open Access Theses & Dissertations

Like most developing nations, Indonesia is at a crucial stage in its modern political and economic history. Opposing forces are constantly at work, a government struggling to make Indonesia a modern nation and the economic demands of a growing population. This presents the country with a multitude of problems. One of several is that nature's resources are exploited for personal economic gain with no regard for the long-term effects. This is a major concern for environmental conservation and non-profit government organizations (NGOs) worldwide. The American NGO Rare is at the forefront of this issue. Its aim is to meet community …

Pwisegen: A Genetic Algorithms-Based Framework For Pairwise Test Set Generation, Pedro Flores

Open Access Theses & Dissertations

Pairwise testing is a combinatorial testing approach that can be used to reduce the number of test cases dramatically for a software system. It specializes in the type of testing where the outcome of a system depends on the combination of several input parameters. This technique is widely used when there is not enough time to try out all possible combinations of the input parameters involved, because that would be very time consuming. The purpose of pairwise testing technique is to avoid testing all possible value combinations that a system can receive, and to preferably take a representative sample of …

Bagc.M: Three Dimensional Gravity Modeling Software With An Application In Death Valley, Ca, Brian Eugene Eslick

Open Access Theses & Dissertations

Basin Anomaly Gravity Calculator (BAGC.m) is a 3D interactive gravity modeling package designed to create, edit, and calculate the gravitational attraction of basin models entirely within the MATLABTM environment. Gravity anomalies are calculated using the Rectangular Prism Method (Bott, 1960; Kane, 1962; and Plouff, 1966) which subdivides earth models into regularly spaced rectangular prisms. This approach requires large 3D matrices to store most realistic earth models. The process of model editing is simplified by storing basins as 2D gridded files which define the depth to the boundary between basement rock and sedimentary fill for each model cell. In order to …

On Relational Quantum Mechanics, Oscar Acosta

Open Access Theses & Dissertations

A problem facing quantum mechanics is that there are a number of views or interpretations available that purport to 'explain' quantum mechanics. In this paper I discuss and analyze the view of relational quantum mechanics by Carlo Rovelli in the context of theoretical underdetermination. I will show that even though Rovelli offers a view that consolidates some of the aspects of competing theories it still falls short of breaking out of the theoretical underdetermination. The criteria that I have used to consider a theory successful in this context is one that increases the predictive output of quantum theory. Lacking an …

Synthesis And Conjugation Of Terminal Α-Galactose Containing, Roger Allan Ashmus

Open Access Theses & Dissertations

Over 16 million people in Latin America are infected with the protozoan parasite Trypanosoma cruzi (T. cruzi), the causative agent of Chagas disease, and up to 50,000 infected people die annually due to complications during the chronic stage of the disease. To date, there are no vaccines or effective drugs to treat chronic Chagas disease. It is known that T. cruzi contains cell surface mucin-like glycoproteins with terminal α-galactosyl residues, and it is well established that they are highly immunogenic. The exact structure of the immunogenic carbohydrate epitopes, however, remains unknown. To determine which epitopes have the ability to interact …

Results Of New Petrologic And Remote Sensing Studies In The Big Bend Region, Stevan Christian Benker

Open Access Theses & Dissertations

The initial section of this manuscript involves the South Rim Formation, a series of 32.2-32 Ma comenditic quartz trachytic-rhyolitic volcanics and associated intrusives, erupted and was emplaced in Big Bend National Park, Texas. Magmatic parameters have only been interpreted for one of the two diverse petrogenetic suites comprising this formation. Here, new mineralogic data for the South Rim Formation rocks are presented. Magmatic parameters interpreted from these data assist in deciphering lithospheric characteristics during the mid-Tertiary.

Results indicate low temperatures (< 750 °C), reduced conditions (generally below the FMQ buffer), and low pressures (≤ 100 MPa) associated with South Rim Formation magmatism with slight conditional differences between the two suites. Newly discovered fayalite microphenocrysts allowed determination of oxygen fugacity values (between -0.14 and -0.25 ΔFMQ over temperature ranges of 680-700 °C), via mineral equilibria based QUILF95 calculations, for Emory Peak Suite.

Petrologic information is correlated with structural evidence from Trans-Pecos Texas and adjacent regions to evaluate debated timing of tectonic …

Pressure Induced Dynamical Instabilities In Body Center Cubic Crystals, Oscar Guerrero

Open Access Theses & Dissertations

Large-scale atomistic simulations of shock-wave propagation in single crystals exhibit large anisotropies in the elastic-plastic and solid-liquid transitions. Characteristic of this type of simulations are the large strains at which the crystal yields plastically, regardless of crystal orientation. At these large strains, uniaxial deformations, such as those produced in planar shock loading generate dynamical instabilities. We have investigated the directional anisotropy of the elastic limit in bcc crystals, in particular Tantalum (Ta), employing molecular dynamics (MD) simulations. We show that the elastic - plastic transition in BCC defect-free crystals is caused by the appearance of soft-phonon modes and not via …

Tectonic Geomorphology Of The Puna Tsang Chhu, Western Bhutan, Abby May Woody

Open Access Theses & Dissertations

There are two boundaries, or physiographic transitions, between three distinct topographic regions in Bhutan. The southern and northern regions have relatively steep hillslopes and high relief, while the central region has gentle hillslopes and low relief. The geomorphology of a 70-km stretch along the Puna Tsang Chhu valley between the towns of Uma and Amrimo was studied in March and April of 2009 to provide constraints on the active tectonics of western Bhutan and the nature of these physiographic transitions.

The Puna Tsang Chhu valley contains a set of alluvial cut-and-fill and bedrock (strath) river terraces with associated sediments - …

Use Of Cognitive Constructs In Linear Algebra, Azucena Zamora

Open Access Theses & Dissertations

Thesis analyzed the presence of two cognitive entities-- modes of thinking and metonymies and metaphors- in the reasoning of three students enrolled in a first year matrix algebra course at a southwest university via the responses given to a set of eight questions asked during one-on-one interviews. The findings of our analysis shed light on the cognitive constructs that students employ to form their understanding of linear algebra concepts. Furthermore, our findings provide clues about the ways in which students move from one mode of thinking to another in the context of varying levels of exposure to graphical, algebraic, and …

Use Of The Cmaq And Wrf-Chem Models To Investigate Tropospheric Ozone And Particulate Matter In The El Paso-Juarez Airshed, Juan Gustavo Arias Ugarte

Open Access Theses & Dissertations

Ground level ozone pollution is a continuing environmental concern in several U.S cities. A necessary step towards understanding and quantifying the problem is the implementation of numerical models that can predict pollutant concentrations. Simulations were performed using the Community Multiscale Air Quality (CMAQ) and the (Weather Research Forecast/Chemical (WRF-Chem) models to study the tropospheric ozone and particulate matter concentrations in the El Paso-Juarez Airshed and to analyze the influence of U.S and Mexican cities as possible contributors to ground level ozone pollution in this region. This study involves the implementation and validation of both the CMAQ and WRF-Chem models for …

Enthalpies Of Mixing Of Water And Alkoxyethanols, John Enriquez

Open Access Theses & Dissertations

Alkoxyethanols [C_mH_2m+1·(OC₂H₄)·OH] (conveniently abbreviated to C_mE₁) are a subgroup of the alkyl poly(ethylene glycol) mono-ethers. They are small relatives of a large number of non-ionic detergents. The thermodynamic properties of their mixing in water have been shown to be good sources of information about the interactions of both hydrophilic and hydrophobic groups with water. Theses alkoxyethanols, or glycol ethers, are the ether derivatives of ethylene glycol where one hydroxyl functional group is substituted for an alkoxy functional group. Our group has already published results for aqueous excess properties …

Iron And Manganese Based Nanomaterials For The Removal Of Selenite And Selenate From Aqueous Solution, Christina Marie Gonzalez

Open Access Theses & Dissertations

Selenium, a naturally occurring element in the environment, is an essential nutrient for humans and animals. However, there is a narrow range between selenium deficiency and toxicity. Selenium in natural waters generally has a concentration of < 10 ppb (parts per billion); however, in the San Joaquin Valley of California concentrations of selenium ranging from 140 to 1400 ppb have been observed. Anthropogenic practices such as agricultural irrigation drainage, coal burning power plants, combustion of fossil fuels, and mining operations are increasing selenium concentrations in aqueous environments. Once in aqueous environments, selenium exists primarily as the two inorganic oxoanions selenite (SeO32-) and selenate (SeO42-). Both of these selenium oxoanions are known to bioaccumulate and can cause embryotoxic and teratogenic effects to waterfowl. There has been a variety of treatment technologies developed for remediation of both selenium oxoanions in water including bacterial reduction, membrane filtration, chemical reduction, reverse osmosis, and solar ponds. However, these treatment technologies are not cost efficient. In this study an alternative treatment technique known as adsorption was used with three synthetic nanomaterials consisting of an iron oxide, manganese oxide, and an iron/manganese oxide. The pH profiles, time dependencies, competitive anion effects, and adsorption isotherms were performed with each of the nanomaterials for both selenite and selenate. In addition, X-ray absorption spectroscopy (XAS) studies were performed to determine both the oxidation state and binding coordination of the selenium oxoanion binding to the nanomaterials.

The investigation revealed the non microwave-assisted and microwave-assisted synthetic Fe3O4 and Mn3O4 nanomaterials, as well as the non microwave-assisted synthetic MnFe2O4 nanomaterial had the phases of magnetite, hausmannite, and Jacobsite, while the grain sizes were 27, 25, 25, 34, and 27 nm, respectively. The optimal binding of selenium oxoanions for all nanomaterials examined was reached at pH 4. Both non microwave-assisted and microwave-assisted Fe3O4 …

Hydrological Characteristics Of A Large-Scale Flooding And Draining Experiment, Barrow, Alaska, Edith Jaurrieta De Velasco

Open Access Theses & Dissertations

The Arctic appears to be affected by climate change more so than any other region on Earth. Some of the most significant climate change impacts reported for the Arctic are associated with dramatic shifts in the hydrologic regime of terrestrial ecosystems. Understanding the hydrologic processes that are associated with different components of arctic terrestrial ecosystems is important because water in the form of snow or rain influences a range of properties and processes such as land-atmosphere energy and trace gas fluxes, nutrient cycling, ecosystem dynamics, biodiversity, periglacial processes and surface albedo. Furthermore, plants, animals, and native people of the Arctic …

Modeling Geographic Awareness Of Road Networks For Consistency Verification, Ari Kassin

Open Access Theses & Dissertations

Problems related to transportation and inspection of valuable or sensitive assets such as commercial products and materials, cultural items and works of art, and hazardous materials share similarities and can be modeled by a core set of abstract entities including a payload, a vehicle, a driver, and an inspector. To make the load handling capabilities of security monitoring and inspection systems more scalable, security can be increased by reducing the variability of transportation routes to a finite set of authorized routes between trip origin and destination locations. Then trip anomalies, which are unexpected trip variations, can be used in inspection …

Renewable Energy Integration: An Approach For Micro-Grid Optimization., Nicolas Lopez

Open Access Theses & Dissertations

This thesis explores the Renewable Energy Integration Problem beginning with a literature review on the different sources of electrical energy classified as Non-Renewable and Renewable, stating that the integration of renewable sources within the pre-existing Power-Grids is a current worldwide problem that is being addressed with different approaches.

The impossibility to exactly model the different equations relating the electric output of the renewable energy sources as they relate with meteorological factors, makes the renewable sector a stochastic component of the overall mathematical model, where it can be concluded that most of the problem is in the area of the forecast. …

Microstructure And Property Evaluation Of Lifepo4 Thin Films For Application In Microbatteries, Jose Marcos Mares

Open Access Theses & Dissertations

The shortage of fossil fuels and the requirements to produce clean, environmental friendly, efficient, and economical energy are the principal problems in the context of energy technology for current and future generations. Therefore, advanced energy storage and conversion capabilities with higher capacity and efficiency are desired. Currently, there is an enormous interest in the development of high energy density rechargeable batteries for use in domestic applications, automotive industries and portable electronic applications. The present research focuses on the development of LiFePO4 thin films for solid-state thin-film microbatteries. The present effort was performed with a specific purpose of understanding the effect …

Coordination Directed Self Assembly Of Pt/Pd Mono-And Multinuclear Complexes, Robert Moreno

Open Access Theses & Dissertations

This research focuses on the development of mononuclear platinum complexes; multinuclear platinum complexes, both of which self assemble into micelles in the presence of water. This work also involved the synthesis of a reverse micelle that allows for detection of water nanocrystals within a defined size molecular envelope. The novel synthesis of these compounds allows for ligand substitution and the creation of a library of compounds.

A New Green Chemistry Method Based On Plant Extracts To Synthesize Gold Nanoparticles, Milka Odemariz Montes Castillo

Open Access Theses & Dissertations

Extraordinary chemical and physical properties exhibited by nanomaterials, as compared to their bulk counterparts, have made the area of nanotechnology a growing realm in the past three decades. It is the nanoscale size (from 1 to 100 nm) and the morphologies of nanomaterials that provide several properties and applications not possible for the same material in the bulk. Magnetic and optical properties, as well as surface reactivity are highly dependent on the size and morphology of the nanomaterial. Diverse nanomaterials are being widely used in molecular diagnostics as well as in medicine, electronic and optical devices. Among the most studied …

Understanding The Promotion Effect: A Density Functional Theory Study Based On High Resolution Transmission Electron Microscopy Images For Mos2-Cobalt Promoted Interfaces, Manuel A. Ramos

Open Access Theses & Dissertations

Many studies had been done in order to understand promotion effect and structure/function in unsupported catalyst. Results indicated that d-electrons play an important role promoting catalytical active sites at the edges of MoS2 catalytically structures. Sulfur removal from crude oil, occurs on the edge of molybdenum di-sulfide (MoS2) nano structures, due to promotion of MoS2 nano structures with nickel or cobalt in sulfur-terminated or molybdenum-terminated edge planes. The promotion leads to formation of so-called CoMoS phase (MoS2/Co9S8) first discovered by meaning of Mössbauer spectroscopy, much more CoMoS phase usually called unsupported catalytical particles, have been topic of great interest in …

Information Sharing Across Private Databases, Swapnil Suresh Samant

Open Access Theses & Dissertations

While the explosion of availability of information has become invaluable in modern society, it has also raised valid concerns about erosion of privacy. More and more, different entities are encouraged to share information in order to discover potential security risks, health pattern, or social behavior trends. However, some of this information is sensitive. Owners of information may be unwilling to share their whole databases with other entities, either to protect the privacy of the records, or because of the proprietary nature of the information.

We consider the following problem. How can we compute the intersection and the equijoin of databases …

Identifying Influential Observations Through The Intraclass Correlation Coefficient, Angel De Jesus Davalos

Open Access Theses & Dissertations

In this thesis, we analyze the performance of adapting the DFBETA statistic for identifying influential observations on the intraclass correlation coefficient under the assumptions of the one-way random effects model. Additionally, we introduce an approach for transforming negative intraclass correlation coefficient estimation values using the method of moments estimator. We apply this method on a data set of repeated blood pressure measurements, after which we will investigate implications of identifying influential observations.

An Ab-Initio Study Of The Elastic Properties Of Important Group Iv Diborides At High Temperatures, Manny Gonzales

Open Access Theses & Dissertations

Presented is an ab-initio Molecular Dynamics (MD) study, employing the Density Functional Theory (DFT), of the lattice parameter, thermal expansion coefficients and elastic constants of ZrB₂, TiB₂ and HfB₂ as a function of temperature. The MD trajectories provide the equilibrium lattice parameters at finite temperatures, and the gradient of the energy from these equilibrium solutions is then used to calculate the components of the stiffness tensor. The results for ZrB₂ are shown to agree well with reported experimental results for the lattice parameters and elastic constants as a function of temperature.

Oxidation Of Dibenzothiophene To Dibenzothiophene Using Metal Nanoparticles Supported On Silica, Karina Castillo

Open Access Theses & Dissertations

Silica and nanoparticles of Pt, Au, and Ag supported on silica were tested for the ability to oxidize dibenzothiophene (DBT) to sulfone. High performance liquid chromatography was used to study the removal of DBT from solution. In addition, X- ray diffraction, infrared spectroscopy and Raman Spectroscopy were used to characterize the product of the oxidation reaction. Further studies involved the use X-ray absorption spectroscopy to characterize the nanoparticle catalysts before and after the oxidation reaction.

To better understand the reaction, silica was synthesized at different pHs using three different acids. The acids used to synthesize the silica were HCl, HNO3, …

Development Of Nanotube Hexaniobate For Photocatalytic Production Of Hydrogen From Water, Saroja Pradhan

Open Access Theses & Dissertations

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A New Photochemical Method For The Preparation Of Amino Acid-α-Phenylthioesters And Peptide-α-Phenylthioesters, Tyrone Hogenauer

Open Access Theses & Dissertations

We describe the development of a novel resin with a photoreactive N-acylnitroindoline linker that allows for the synthesis of amino acid- (in solution) or peptide-α-thioesters using standard Fmoc/t-Bu standard solid phase peptide synthesis (SPPS). Recent advances have shown that the yields of this thioesterification reaction have dramatically increased due to a simple change in the order of addition of reagents. Upon illumination with UV-light, in the presence of N-hydroxybenzotriazole (HOBt), the amino acid- or peptide-α-OBt ester is generated by direct photo-release from the nitroindoline linker with minimal epimerization, followed by reaction with thiophenol in the dark to produce amino acid-α-phenylthioesters …

Incidence Functions, Yiyu Liao

Open Access Theses & Dissertations

In the mid 1960's, the incidence algebra was introduced in the seminal paper of Gian-Carlo Rota. He addressed the importance of the Mobius function in combinatorics. In particular, the incidence algebra of a locally finite poset plays an essentially unifying role in the theory of the Mobius function. One of the significant generalizations is the incidence algebra of a Mobius category introduced by Pierre Leroux. With the help from Mobius category, it was exciting to be able to extend the combinatorial results more broadly than just on posets. Before attempting to study this generalization of the Mobius function, we have …

Development Of Wide Band Gap Semiconductor Materials For Renewable Energy, S.M. Sarif Masud

Open Access Theses & Dissertations

Several new wide band gap semiconductor nanocomposite photocatalytic materials have been synthesized from HTiNbO5 and HNb3O8 for solar energy conversion. As a source of renewable energy, the materials are being tested to produce hydrogen fuel from water via photolysis. The materials have high surface areas, are macroporous, and have flatband potentials suitable for reducing water to create hydrogen. Under visible or ultra violet light, the materials were found to be very promising as hydrogen evolving photocatalysts. As part of the synthesis of the composites, the catalysts also exhibited excellent catalytic activity under UV light for reducing ionic platinum and gold …

Bayesian Nonparametric Regression With A Flexible Error Term Distribution, Courtney Marie Barnes

Open Access Theses & Dissertations

Datasets often exhibit heavy tailed behavior and standard analyses are often heavily influenced by outliers. We propose a nonparametric regression model whose error term distribution is a mixture of a normal and a Student t distribution. This results in a model that is more resistant to outliers compared to a model with a normal error term.

Test Case Automation For Specification Patterns System And Composite Propositions, Cuauhtemoc Munoz

Open Access Theses & Dissertations

Specifying software properties is a common activity in the software development process. Software properties are often written in a natural language such as English. However, the ambiguity in natural languages makes validation and verification time-consuming and error-prone. Specifying software properties in formal languages such as Linear Temporal Logic (LTL) or Computation Tree Logic (CTL) enables the use of formal verification tools such as model checkers. Nevertheless, formal languages require software developers to have a strong background in mathematics and logic.

The specification Patterns System (SPS) and Composite Propositions (CPs) use a higher-level abstraction to specify software properties formally. The SPS …