Physical Sciences and Mathematics Commons^™

Variety-Dependent Physiologic And Biochemical Effects Of Copper Nano Particles On Rosie And Green Bok Choy (Brassica Rapa) Phenotypes, Chaoyi Deng

Open Access Theses & Dissertations

The effects of Cu-based nanoparticles (NPs) in bok choy (Brassica rapa subsp. chinensis) are unknown. In this study, Rosie and Green, two varieties of bok choy, with different anthocyanin content, were cultivated for 70 days in soil amended with copper oxide nanoparticles (nano CuO), bulk copper oxide (bulk CuO) and copper chloride (CuCl2) at 75, 150, 300 and 600 mg Cu/kg soil. Cu and essential elements in tissues, and relative chlorophyll content, were determined. In both varieties, nano CuO treatments caused significantly more Cu uptake in roots and shoots, compared with bulk CuO and ion CuCl2 (p ≤ 0.05). Additionally, …

Modulation Of The Physiological And Biochemical Effects Of Copper Nanoparticles In Kidney Beans (Phaseouls Vulgaris) Treated By Kinetin, Suzanne Annette Apodaca

Open Access Theses & Dissertations

It is imperative to not only understand the impact of engineered nanomaterials (ENMs) in edible plants, but also the interactions they have with various additives used in agriculture. In this study, kidney bean plants were grown in potting soil treated with nano copper (nCu), bulk copper (bCu), and copper chloride (CuCl2) at concentrations of 0, 50, and 100 mg/kg for 55 and 90 days. At 15 days of growth, 0, 10, and 100 μm of kinetin (KN) were applied to plants. Plant tissue samples were harvested at 55 days and seeds were reaped at 90 days. Physiological and biochemical parameters …

Geophysical Model Of The Cu-Mo Porphyry Ore Deposit At Copper Flat Mine, Hillsboro, Sierra County, New Mexico, Adrian Emmanuel Gutierrez

Open Access Theses & Dissertations

A 3D gravity model of the Copper Flat Mine was performed as part of the exploration of new resources in at the mine. The project is located in the Las Animas Mining District in Sierra County, New Mexico. The mine has been producing ore since 1877 and is currently owned by the New Mexico Copper Corporation, which plans o bringing the closed copper mine back into production with innovation and a sustainable approach to mining development. The Project is located on the Eastern side of the Arizona-Sonora-New Mexico porphyry copper Belt of Cretaceous age. Copper Flat is predominantly a Cretaceous …

Biological Effects Of Copper On Prosopis Pubescens (Screw Bean Mesquite), Marian Nicte Zappala

Open Access Theses & Dissertations

Phytoremediation is an emerging technology for cleaning industrial and urban contamination (Peuke and Rennenberg, 2005). Many factors including germination rate, biomass changes, biochemical changes, and nutrient changes must be determined in order to utilize a plant for phytoremediation. Our results showed that Prosopis pubescens (Screw bean mesquite) is a hyperaccumulator of copper from copper sulfate and a feasible option to remediate fields with up to 200 ppm of copper sulfate.

Screw bean mesquite seeds are viable even after 30 years of storage. Both copper sulfate and copper nitrate decreased the germination rate of screw bean mesquite seeds. In soil grown …

The Impact Of Sulfide Mineral Weathering On The Isotopic Signatures Of Fe And Cu In Metal-Rich Streams, Ana Lourdes Gutierrez

Open Access Theses & Dissertations

The oxidative weathering of sulfide minerals, like pyrite, at the Earth's surface controls the formation of acid mine drainage sites as well as the Fe isotope composition of these areas and the main processes taken place. In this study, water and rock samples were collected from acidic drainages (most from abandoned mining sites) from the St. Juan Mountains in Colorado. The water samples were measured in-situ for dissolved oxygen, dissolved Fe(II), pH, and conductivity. Filtered acidified, unfiltered acidified, and Fe-oxide samples were analyzed for their metal concentrations. Ion-exchange chromatography was applied to both water and digested oxide fractions in order …

Supramolecular Organization Of Nanoparticles, Brenda M. Porta Linnell

Open Access Theses & Dissertations

The study of supramolecular structures with nano-architectures has become an active area of research in recent years. They have the potential to generate functional materials with applications in medicine and emerging technologies. In this dissertation, the supramolecular organization of gold nanoparticles (AuNP) and other nano-scale structures such as discrete styrene-based polymers was investigated. The synthesis and characterization of metal-mediated AuNPs systems using pendant ligands on the AuNP such as 11-diethylenetriamine-undecane-1-thiol, 11-Mercapto-undecanoic acid [2-(2-amino-ethylamino)-ethyl]-amide, Bis(11-oxo-nicotinic acid, undecine)disulfide, and 11-mercaptoundecanoic acid, and using Cu(II) to mediate the formation of supramolecular AuNP systems with sizes of 200 nm ¡V 3 fÃ?m, are …

Application Of Copper And Zinc Isotopes To Fingerprint Metal Sources And Identify Attenuation Mechanisms In The Abandoned Waldorf Mine Area, Clear Creek County, Colorado, Suzan Aranda Luna

Open Access Theses & Dissertations

Acid rock drainage (ARD) is caused by the oxidative weathering of sulfide minerals. Sulfur is oxidized by dissolved oxygen or Fe(III) and sulfate ions, metals, and protons are released into the environment. Hence, the pH of nearby water and soils often decreases in response to ARD while metal concentrations increase. Because a large part of the Rocky Mountains of Colorado are highly mineralized (i.e., the Colorado Mineral Belt), ARD is a serious problem in this region. Moreover, the many abandoned mining areas in the Rocky Mountains that include waste rock piles, tailings impoundments, and surface disturbances add to the problem …

Copper Isotope Fractionation During Surface Adsorption And Intracellular Incorporation By Bacteria, Jesica Urbina Navarrete

Open Access Theses & Dissertations

Copper isotopes may prove to be a useful tool for investigating bacteria-metal interactions recorded in natural waters, soils, and rocks. However, experimental data that constrain Cu isotope fractionation in biologic systems are limited and unclear. In this study we utilized Cu isotopes (65Cu) as a tool to investigate Cu-bacteria interactions, including surface adsorption and intracellular incorporation. Experiments were conducted with individual Gram-positive (Bacillus subtilis) and Gram-negative (Escherichia coli) bacterial species as well as with bacterial consortia from several natural environments. Adsorption experiments were conducted with live or dead cells over the pH range 2.5 to 6. Surface adsorption of Cu …

Investigations Of Grade Control, Macarthur Mine, Yerington, Nevada: An Oxidized Porphyry Copper System, Joseph Daniel Louis Lori

Open Access Theses & Dissertations

Supergene enriched, low-grade oxidized porphyry copper deposits are of great economic value. Oxidized porphyry sections are economic targets because even low-grade prospects have the potential to produce low-cost copper in an environmentally friendly fashion due to easy leachability and high recovery rates of the oxide mineralization. The MacArthur Mine, in the historic Yerington mining district of Nevada, is the focus of this study. The MacArthur is a tilted oxidized porphyry deposit, partially mined by open pit methods, hosted in the Jurassic Bear Quartz Monzonite of the Yerington batholith. The objective of the study is to define controls of copper oxide …