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Full-Text Articles in Physical Sciences and Mathematics

Adsorptive And Kinetic Characterization Of Aqueous Zinc Removal By Biochars, Sergio Mireles, Yongsik Ok, Chu-Lin Cheng, Jihoon Kang Nov 2016

Adsorptive And Kinetic Characterization Of Aqueous Zinc Removal By Biochars, Sergio Mireles, Yongsik Ok, Chu-Lin Cheng, Jihoon Kang

School of Earth, Environmental, and Marine Sciences Faculty Publications and Presentations

Biochars have shown a great potential to treat stormwater runoff contaminated with heavy metals due to their favorable physical and chemical characteristics. Biochar materials were produced from pyrolysis of oak tree and wood at 400C and 450C respectively, and their Zn adsorption behavior from aqueous solutions were evaluated to assess their applicability as a filter media for stormwater treatment. Two adsorption isotherm models, Freundlich and Langmuir, were used to fit the batch-scale experimental data. The kinetics of Zn adsorption was investigated under two contrasting physical condition (stagnant vs. agitated). The adsorption isotherm was better fitted with the Langmuir model (R2 …


Removal Of Arsenic From Water Using Synthetic Fe7s8 Nanoparticles, Jesus Cantu, Louis E. Gonzalez, Jacqueline Goodship, Monica Contreras, Meera Joseph, Cameron Garza, Thomas Eubanks, Jason Parsons Apr 2016

Removal Of Arsenic From Water Using Synthetic Fe7s8 Nanoparticles, Jesus Cantu, Louis E. Gonzalez, Jacqueline Goodship, Monica Contreras, Meera Joseph, Cameron Garza, Thomas Eubanks, Jason Parsons

Chemistry Faculty Publications and Presentations

In the present study, pyrrhotite was used to remove arsenite and arsenate from aqueous solutions. The Fe7S8 was synthesized using a solvothermal synthetic method and it was characterized using XRD and SEM micrographs. Furthermore, the particle size for the nanomaterial Fe7S8 was determined to be 29.86 ± 0.87 nm using Scherer’s equation. During the pH profile studies, the optimum pH for the binding of As (III) and As (V) was determined to be pH 4. Batch isotherm studies were performed to determine the binding capacity of As(III) and As(V), which was determined to be 14.3 mg/g and 31.3 mg/g respectively …