Physical Sciences and Mathematics Commons^™

Correction To Luminosity Measurement For The Pixel Luminosity Telescope At Cms, Krishna Thapa

Masters Theses

The search for and detailed study of new particles and forces with the Compact Muon Solenoid (CMS) detector at the Large Hadron Collider (LHC) of CERN is fundamentally dependent on the precise measurement of the rate at which proton-proton collisions produce any particles, the so-called luminosity. Therefore, a new detector, the Pixel Luminosity Telescope (PLT), dedicated to measure the luminosity at high precision was added to the CMS experiment in 2015. It measures the inclusive charged particle production from each collision of proton bunches in the LHC. Additional charged particles which are observed by the instrument but produced from sources …

Assessing Tennessee Landowners' Attitudes Toward Wild Hogs And Support For Control Options, Carlotta Anne Caplenor

Masters Theses

Wild hogs (Sus scrofa) are an invasive species with destructive habits, particularly rooting and wallowing, which can directly impact agricultural crops, pasture land, and water quality. Considering wild hogs are widely dispersed across the landscape, it is extremely difficult to control them. Moreover, disagreements can arise among different stakeholders over whether and how their population should be managed. The purpose of this study was to examine Tennessee landowners’ attitudes toward wild hogs, to compare acceptability of control methods, and to evaluate the factors significantly influencing public support for wild hog control regulations. Logistic regression was used to analyze …

Development, Analysis, And Optimization Of A Swirl-Promoting Mean Flow Solution For Solid Rocket Motors, Andrew Steven Fist

Masters Theses

This work demonstrates and analyses a new flow candidate for describing the internal gaseous motion in simulated rocket motors. The fundamental features of this solution include the conservation of key system properties also incorporated in the classic Taylor-Culick (TC) system (i.e. inviscid, axisymmetric, steady and rotational properties), while allowing for the development of a swirling velocity component. The work compares the new solution to the development and formulation of the classic TC system, ultimately identifying that both the new and classic solutions are special cases of the Bragg-Hawthorne equation. Following this development, the text then explores the development of energy-optimized …

Understanding Stakeholder Attitudes And Involvement In Habitat Conservation Plans And The Endangered Species Act, Kyle Andrew Rodgers

Masters Theses

The Endangered Species Act (ESA), established in 1973, was a landmark piece of environmental legislation and remains the standard for endangered species conservation. Implementation of the ESA has often been framed as pitting economic development against species conservation, inciting passions for and against endangered species conservation. The strength of opposing public opinions is highlighted by high-profile controversies such as those around the snail darter, northern spotted owl and the greater sage grouse. In an attempt to reduce conflict, the US Fish and Wildlife Service (USFWS) increasingly seeks to utilize collaborative, stakeholder-based processes that address stakeholder interests, attitudes, and values.

In …

Preliminary Investigation For The Development Of Surrogate Debris From Nuclear Detonations In Marine-Urban Environments, Adam G. Seybert

Masters Theses

No nuclear weapon has ever been detonated in a United States city. However, this also means the nuclear forensic community has no actual debris from which to develop analytical methods for source attribution, making the development of surrogate nuclear debris a vital undertaking. Moreover, the development of marine-urban debris presents an unusual challenge because unlike soil and urban structures, which remain compositionally consistent, the elemental composition of harbor and port waters fluctuates considerably due to natural phenomenon and human activity. Additionally, marine vessel composition and cargo can vary dramatically. While early US nuclear tests were carried out in shallow-water coastal …

Experimental Study On The Production Of Negative Ion Copper Clusters And Applications, Ran Chu

Masters Theses

At the Holifield Radioactive Ion Beam Facility (HRIBF) at Oak Ridge National Laboratories (ORNL), we investigated the formation, production and potential application of negative-ion copper clusters using mass distributions of negative-ion copper clusters obtained by bombarding various copper samples with Cs ions. The Cu samples – in very large mass-selected clusters Cu (e.g. n=54) – included natural Cu, isotopically enriched copper-63 and copper-65, and electroformed ultra-clean Cu. Mass spectra of negative copper cluster produced by Cs sputter source size up to 50 are shown for the first time.

Three main features were observed for all four copper samples: the intensity …

Three Body Interactions Of Rare Gas Solids Calculated Within The Einstein Model, Dan D'Andrea

Masters Theses

Three body interactions can become important in solids at higher pressures and densities as the molecules can come into close contact. At low temperatures, accurate studies of three body interactions in solids require averaging the three-body terms over the molecules' zero point motions. An efficient, but approximate, averaging approach is based on a polynomial approximation of the three-body term. The polynomial approximation can be developed as a function of the symmetry coordinates of a triangle displaced from its average geometry and also as a function of the Cartesian zero point displacements from each atom’s average position. The polynomial approximation approach …

Synthesis And Characterization Of Novel Ligand For Use On Rhodium Paddlewheel Complexes, Gavin J. Rustin

Masters Theses

Dirhodium (II) paddlewheel complexes have proven to be useful catalysts in many transformations including C-H insertions, cyclopropanation, and silane insertion reactions. One deficiency of these catalysts is the inability to modulate the enantioselectivity with reactive diazo compounds. One avenue for potential improvement of paddlewheel complexes is coordinating ligands in the axial site to increase enantioselectivity. The axial site has been occupied by various ligands including Nheterocyclic carbenes, nitrogen compounds, and phosphorous compounds. This work examines compounds that can be used as ligands on dirhodium complexes that have a pendant chain containing a dibenzyl phosphite and dibenzyl phosphate, both of which …

Tagamajig: Image Recognition Via Crowdsourcing, Gregory Martin Simpson

Masters Theses

The University of Tennessee, Knoxville (UTK) Library possesses thousands of unlabeled gray-scale photographs from the Smoky Mountains circa the 1920s - 1940s. Their current method of identifying and labeling attributes of the photographs is to do so manually. This is problematic both because of the scale of the collection as well as the reliance on an individual's limited knowledge of the area's numerous landmarks.

In the past few years, similar dilemmas have been tackled via an approach known as crowd computing. Some examples include Floating Forests, in which users are asked to identify and mark kelp forests in satellite images, …

Mathematics Education From A Mathematicians Point Of View, Nan Woodson Simpson

Masters Theses

This study has been written to illustrate the development from early mathematical learning (grades 3-8) to secondary education regarding the Fundamental Theorem of Arithmetic and the Fundamental Theorem of Algebra. It investigates the progression of the mathematics presented to the students by the current curriculum adopted by the Rhea County School System and the mathematics academic standards set forth by the State of Tennessee.

A Computational Geometric And Graph Theoretic Approach To Reducing Dimensionality On Raster Data Problems, Matthew James Robert Bachstein

Masters Theses

Large scale mathematical models often involve a trade off between computational length and detail. In general, the more detailed the data, the more time it takes for the model to process. Models that use geographic scale data are particularly susceptible to this inflation; fine resolution data (on the order of m2 [meters squared]) brings great benefits, but demolishes the computation time. This thesis presents a method for reducing the dimensionality of large scale data in a systematic manner to maximize the benefits of fine resolution data while minimizing the computational time increase, then applying the method to a simulated invasive …

Regional Dynamic Price Relationships Of Distillers Dried Grains In U.S. Feed Markets, Matthew Fulton Johnson

Masters Theses

Distillers dried grains with solubles (DDGS) is now a mainstream substitute in U.S. animal feed rations. DDGS is rich in fat and protein content and serves as a competitive feed source in livestock markets. The objective of this study is to identify dynamic price relationships among DDGS, corn, soybean meal, and livestock outputs in context of specific livestock sectors and their geographic location. Four locations associated with a predominant livestock sector are selected for analysis by measuring density and relative proportion of a livestock sector’s grain consumption at the county level. A vector error correction model is applied to post-mandate …

Pdroid, Joe Larry Allen

Masters Theses

When an end user attempts to download an app on the Google Play Store they receive two related items that can be used to assess the potential threats of an application, the list of permissions used by the application and the textual description of the application. However, this raises several concerns. First, applications tend to use more permissions than they need and end users are not tech-savvy enough to fully understand the security risks. Therefore, it is challenging to assess the threats of an application fully by only seeing the permissions. On the other hand, most textual descriptions do not …

Role Of Sorting On The Composition Of Siliciclastic Sediment: Implications For Interpreting Provenance After Limited Transport In An Arid Climate, Forrest Christopher Driscoll

Masters Theses

This study tested whether transport distances (< 500 m) have the capacity to shape the geochemistry of sediments across multiple grain-size populations due to sorting derived from a single source. In the Stepladder Mountains, Mojave Desert, CA, a < 1 km² [square kilometers] watershed allows for a controlled study to understand how modern sediments acquire their composition from a single granodioritic source in an arid climate where there is no chemical weathering. Sediments are naturally sorted into distinct grain-size populations, with modes ranging from very fine sand to gravel within a single, alluvial channel. Sediment samples representative of each population were petrographically and geochemically analyzed in order to test the effectiveness of commonly used discrimination diagrams. Sediments became proportionally enriched in plagioclase and biotite and depleted in K-feldspar and quartz with decreasing grain …

Testing The Temporal Stability Of The Climate Response Of Tree Species At Norris Dam State Park, Tennessee, U.S.A., Allison Elizabeth Ingram

Masters Theses

Temporal stability of the climate-tree growth relationship means that over time, tree species were responding to a specific climate variable and continue to respond to that variable into the present. The stability of this response is important to test prior to attempting to reconstruct past climate. In this study, I sampled oaks (white oak = Quercus alba L. and chestnut oak = Quercus montana Willd.) and pines (Virginia pine = Pinus virginiana Mill. and shortleaf pine = Pinus echinata Mill.) growing in Norris Dam State Park in eastern Tennessee and tested the temporal stability of these species and their potential …

The Use Of Sodium Persulfate In Hydraulic Fracturing Fluids: A Degradation Study Based On Furfural, Katherine Elizabeth Manz

Masters Theses

Hydraulic fracturing has allowed natural gas to become a viable energy source via extraction of unconventional shale reserves, but this process requires an enormous amount of water. To ensure a productive fracture, a proprietary blend of chemical additives is added to the water. In this research, a hydraulic fracturing chemical additive – an enzyme breaking agent – is analyzed for organic components using gas chromatography mass spectrometry. The chemical changes that occur over the course of a fracture are also investigated using one model chemical found in the additive, furfural, in order to help assess the environmental risk that hydraulic …

Petrology Of The Paired Dominion Range 2010 Howardites: Indications Of Magmatic Complexity On Asteroid Vesta, Timothy Michael Hahn Jr.

Masters Theses

A comprehensive petrologic and geochemical characterization of six paired howardites collected from the Dominion Range, Antarctica was conducted. These howardites are megaregolith samples from the asteroid 4 Vesta. Collectively, they contain an assortment of igneous rock fragments that indicate magmatic processes were capable of producing a variety of rock types; 22 chemically and texturally discrete basaltic eucrite, cumulate eucrite, and diogenite lithologies are recognized. The implications for remote-sensing observations of Vesta are discussed. The petrogenesis of two previously unrecognized lithologies are described in further detail: an evolved dacite that we propose is a residual melt from extensive crystallization, and a …

Microbial Extracellular Enzymes In Marine Sediments: Methods Development And Potential Activities In The Baltic Sea Deep Biosphere, Jenna Marie Schmidt

Masters Theses

The deep biosphere is defined as the subsurface ecosystem in which little energy is available to microorganisms and microorganisms can live for thousands of years. Heterotrophic microbes survive in the deep biosphere even though organic matter is limited and highly recalcitrant in nature. Measuring microbial extracellular enzyme activity provides a potential means to evaluate the rate at which microorganisms are performing carbon remineralization in the energy limited sediment beneath the seafloor. Extracellular enzymes breakdown organic compounds so that the nutrients can move inside the cell and be used for energy. This study explored the role extracellular enzymes play in the …

A Textural Image Analysis Study Of Mars-Analog Sediment: Comparisons Of 2d And 3d Textural Analysis Methods, Image Resolution, And The Effects Of Shadows, Mary Agnes Eibl

Masters Theses

Sediments from Mars-analog, basaltic, aeolian (Moses Lake dunes, WA) and fluvial (Death Valley region, CA) environments were analyzed for textural properties (grain size, roundness, sphericity) to understand how well image-based analyses compare with actual sediment characteristics. Three interrelated studies determined: (1) how well high-resolution, two-dimensional (2D) image analysis compares with three-dimensional (3D) sediment textures, (2) the extent to which decreasing image resolution affects textural analyses by comparison with high-resolution images, and (3) the extent to which shadows at different incident solar angles has on textural measurements. In both aeolian and fluvial environments, 2D grain-size distributions and statistics closely match 3D …

Effects Of Bullying And Victimization On Friendship Selection, Reciprocation, And Maintenance In Elementary School Children, Marisa Lynn Whitley

Masters Theses

This study examined the effects of elementary school children’s bullying and victimization experiences on their friendships over time. The majority of children experience acts of aggression or bullying before the end of elementary school, and bullying and peer victimization is associated with academic, social, behavioral, and psychological difficulties. This study used social networks analysis (R SIENA 4.0) to examine whether peer reports of forms of bullying and victimization (i.e., overt and relational) affect the likelihood of friendship selection, reciprocation, and maintenance in 2^nd-4^th grade children. Children (N = 143) from the Midwestern region of the United …

Incorporating Carbon Nanotubes Into Carbon Fiber Via Surface Modification, Robert Benjamin Ripy

Masters Theses

Ever more advanced materials need to be designed to further the exploration of avenues of science and engineering. Metals and traditional composites are not meeting the needs of today’s stringent demands for lightweight and strong materials. There is a need for advanced materials that are lighter and stronger to replace conventional materials; carbon fiber composites became the obvious choice because of their outstanding mechanical properties. Polyacrylonitrile (PAN) based carbon fiber has reached its apex in terms of its strength to weight ratio. Carbon nanotubes (CNTs) offer a lightweight and potentially stronger alternative to PAN based fibers. However, it is difficult …

Opportunities In Sustainability: Maize Seeders For The Developing World And Alternative Fertilizers In The United States, Rebecca Mattingly Harman

Masters Theses

Sustainable agricultural systems are needed for both large and small-scale farmers the world over. Central to the sustainability of these systems is the availability of cheap and effective seeders for smallholder farmers and effective utilization of less energy intensive nitrogen sources. In the first two chapters, this thesis considers maize seeders for smallholder use in a Conservation Agriculture system. To sustain the smallholder sector, soil fertility and soil erosion must be addressed and a Conservation Agriculture model seeks to improve soil conditions in agriculture. The technologies available to smallholder farmers, though, need to be tested in a no-till system before …

Knoxville Microclimates: Spatial And Temporal Variability In Ambient Air Temperature Across Four Urban Neighborhoods, David Andrew Howe

Masters Theses

The urban heat island (UHI), has been studied extensively over the past 30 to 40 years, yet questions remain regarding the spatiotemporal variability of the UHI, and what factors influence this variability. More recent studies have emphasized the microclimates within an urban setting, but most do not have the high resolution climate or land cover data necessary to truly understand the interactions taking place at a neighborhood-level scale. This study used a network of 10 identical weather stations and high resolution land use data in Knoxville, Tennessee to analyze the microclimates of a medium-sized city with a temperate climate over …

Tennessee Tornado Frequency, Vulnerability, And Relation To A Large-Scale Climate Variability, Vincent Marshall Brown

Masters Theses

This work explores the climatologies of isolated tornadoes and tornado outbreaks across the state of Tennessee, a state that in some years experiences more tornadoes than states in the heart of Tornado Alley. Part one assesses tornado frequency characteristics and fatality statistics within 100 km of three major Tennessee cities (Nashville, Memphis, and Knoxville) between 1950 and 2013. Nashville reported the most tornadoes, (426) but Memphis reported the most fatalities. Knoxville and Nashville tornadoes occurred on fewer days, while Memphis tornadoes were spread across more tornado days. Spring was the most active season for tornadoes, but Memphis still experienced approximately …

Trends In Location Of Lifetime Maximum Intensity Of Tropical Cyclones In The North Atlantic And West Pacific Oceans, Sarah Ann Bleakney

Masters Theses

Tropical cyclones threaten coastal populations around the world each year. Thus, the climatology of tropical cyclones is an immediate research need, specifically to better understand their long-term patterns and elucidate their future in a changing climate. One important pattern that has recently been detected is the poleward shift of the lifetime maximum intensity (LMI) of tropical cyclones in the Northern Hemisphere. My study further assesses the recent spatial changes in the LMI of tropical cyclones in the Northern Atlantic and Western Pacific basins since 1964. I explored relationships between the intensity and location of LMI with respect to landfall location …

Cd Transport In Eutectic Licl-Kcl And Contamination Of Zr Metal And Thermal Dehydration Of Bulk Licl-Kcl, Nicholas Azoy Earle

Masters Theses

Researchers at Idaho National Labs have noted unexpectedly high Cd content in empty cladding hulls after processing in the Mark-IV ER. It has been theorized that Cd metal is transporting from the LCC pool through the eutectic LiCl-KCl salt bath to the anode baskets containing the empty hull where it is retained as a Zr-Cd intermetallic. This study sought to replicate the Cd contamination in a dry Ar glovebox using small-scale analogue of the Mark-IV ER salt-Cd metal system.

Anhydrous eutectic LiCl-KCl was an essential regent in this research and experiments were conducted to investigate the feasibility of dehydrating nominally …

Developing Synthetic Methods To Prepare Discrete Metal-Organic Nanotubes, Derek L. Mull

Masters Theses

Metal-organic nanotubes (MONTs) are an emerging class of discrete materials that are the 1D variant of metal-organic frameworks (MOFs). MONTs have potential to become an alternative 1D material to carbon nanotubes, metal oxide nanotubes, and boron nitride nanotubes because they possess an organic ligand that can be functionalized and tuned for specific applications. Despite this potential, only a handful of structures have been reported and only two examples of discrete MONTs exist in the literature. It is thus imperative to develop general methods to prepare and characterize discrete MONTs to bring them to the forefront of the scientific literature.

Efforts …

Magnetron Sputtering And Corrosion Of Ti-Al-C And Cr-Al-C Coatings For Zr-Alloy Nuclear Fuel Cladding, Devin Alan Roberts

Masters Theses

The disaster at the Fukushima Daiichi Nuclear Power Plant in March 2011 bought renewed focus to the issue of corrosion in nuclear fuel cladding applications. This thesis reports on the background behind these issues, the investigation strategy, and the analysis of experiments focused on mitigating oxidation of Zr-alloy fuel cladding. This thesis seeks to develop magnetron sputtered Ti-Al-C and Cr-Al-C coatings for Zr-alloy substrates and characterize the as-deposited and corroded samples.

Ti-Al-C and Cr-Al-C coatings were deposited onto ZIRLO, Si, and Al₂O₃ [Aluminum Oxide] substrates under various sputtering conditions. A combinatorial sputtering method was employed to refine …

Impacts Of Biofumigation And Anaerobic Soil Disinfestation On Strawberry Production, Jennifer Renee’ Wheeler

Masters Theses

Due to the phase-out of methyl bromide, there is a need for alternative, nonchemical fumigation treatments in strawberry production. Anaerobic soil disinfestation and biofumigation are two non-chemical methods for controlling soilborne plant pathogens of strawberry. This study was designed to observe strawberry fruit nutrition and soil volatiles of a strawberry field being treated with biofumigation treatments, anaerobic soil disinfestation treatments, and a combination of the two alternative methods. A trial was conducted with 11 pre-plant soil-incorporated treatments arranged in a randomized complete block design with 6 rows (blocks). Biofumigation treatments consisted of deactivated mustard meal, deoiled mustard meal, mustard pellets, …

Improving Ventricular Catheter Design Through Computational Fluid Dynamics, Sofy Hefets Weisenberg

Masters Theses

Cerebrospinal fluid (CSF) shunts are fully implantable medical devices that are used to treat patients suffering from conditions characterized by elevated intracranial pressure, such as hydrocephalus. In cases of shunt failure or malfunction, patients are often required to endure one or more revision surgeries to replace all or part of the shunt. One of the primary causes of CSF shunt failure is obstruction of the ventricular catheter, a component of the shunt system implanted directly into the brain's ventricular system. This work aims to improve the design of ventricular catheters in order to reduce the incidence of catheter obstruction and …