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- Colinus virginianus (35)
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- Doctoral Dissertations (74)
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Articles 1 - 30 of 173
Full-Text Articles in Physical Sciences and Mathematics
Core-Collapse Supernova Simulations With Spectral Two-Moment Neutrino Transport, Ran Chu
Core-Collapse Supernova Simulations With Spectral Two-Moment Neutrino Transport, Ran Chu
Doctoral Dissertations
The primary focus of this dissertation is to develop a next-generation, state-of-the-art neutrino kinetics capability that will be used in the context of the next-generation, state-of-the-art core-collapse supernova (CCSN) simulation frameworks \thornado\ and \FLASH.\index{CCSN} \thornado\ is a \textbf{t}oolkit for \textbf{h}igh-\textbf{or}der \textbf{n}eutrino-r\textbf{ad}iation hydr\textbf{o}dynamics, which is a collection of modules that can be incorporated into a simulation code/framework, such as \FLASH, together with a nuclear equation of state (EOS)\index{EOS} library, such as the \WeakLib\ EOS tables. The first part of this work extends the \WeakLib\ code to compute neutrino interaction rates from~\cite{Bruenn_1985} and produce corresponding opacity tables.\index{Bruenn 1985} The processes of emission, …
Constrained Collective Movement In Human-Robot Teams, Joshua Fagan
Constrained Collective Movement In Human-Robot Teams, Joshua Fagan
Doctoral Dissertations
This research focuses on improving human-robot co-navigation for teams of robots and humans navigating together as a unit while accomplishing a desired task. Frequently, the team’s co-navigation is strongly influenced by a predefined Standard Operating Procedure (SOP), which acts as a high-level guide for where agents should go and what they should do. In this work, I introduce the concept of Constrained Collective Movement (CCM) of a team to describe how members of the team perform inter-team and intra-team navigation to execute a joint task while balancing environmental and application-specific constraints. This work advances robots’ abilities to participate along side …
Elucidating The Importance Of Structure, Surfaces, And Interfaces In Polymer Nanoparticles And Nanocomposites, Jacob E. Fischer
Elucidating The Importance Of Structure, Surfaces, And Interfaces In Polymer Nanoparticles And Nanocomposites, Jacob E. Fischer
Doctoral Dissertations
This dissertation details research conducted to elucidate the importance of structure, surfaces, and interfaces in both polymeric nanoparticles and polymer nanocomposites. The fundamental understanding that is garnered in these studies provides a foundation to rationally develop nanocomposites tailored for unique functionalities, performance and applications.
Soft polymeric nanoparticles, have shown to imbue non-traditional diffusive properties, the strength of which decreases with crosslinking density of the nanoparticle. The crosslinking dependent morphology of these nanoparticles is first characterized in a dilute solution of good solvent (Chapter 2). The scattering results revealed that the structure ranges from a swollen polymer in good solvent (0% …
Controlling Polymer Molecular Structure And Morphology: From Illumination Of Conjugated Polymers To Polymer Chain Depolymerization, Josh Moncada
Doctoral Dissertations
Polymers remain a prominent component of our lives, and finding methods to control their structure or morphology are needed to tune material properties. This dissertation reports methods to alter the conformation, morphology, or structure of polymeric materials. Chapter two describes the impact of exposure to white light during annealing of conjugated polymer blends on their morphology and optoelectronic performance. The observed changes in the morphology correlate strongly to the variation in photoluminescence (PL) with illumination, including that the PL varies less with illumination at higher Poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene] loadings, offering foundational understanding to guide the structure and optoelectronic performance of conjugated polymer …
Natural, Experimental, And Educational Explorations Of The Interiors Of Terrestrial Planetary Bodies, Nadine L. Grambling
Natural, Experimental, And Educational Explorations Of The Interiors Of Terrestrial Planetary Bodies, Nadine L. Grambling
Doctoral Dissertations
Planetary interiors are enigmatic, inaccessible, and vital to the processes that have formed the rocks we see on the surface of bodies in the inner Solar System today. Based on geophysical explorations of the Moon and Earth, along with information gleaned from rocks at the surface today, there is understanding of the basic structure and processes at depth. Using a combination of natural samples and experimental studies, we attempt to learn more about the physical conditions beneath the surface, and their effect on material properties and tectonics processes in the mantle.
On Earth, mid-ocean ridge processes have long been debated, …
Intra-Skeletal Variation In Stable Isotopes Through Non-Destructive Approaches: Applications Of The Patterns Of Skeletal Remodeling To Biological Anthropology, Armando Anzellini
Intra-Skeletal Variation In Stable Isotopes Through Non-Destructive Approaches: Applications Of The Patterns Of Skeletal Remodeling To Biological Anthropology, Armando Anzellini
Doctoral Dissertations
Stable isotope analysis is a well-established method in biological anthropology used to deliver data on residence, diet, and life history. Samples for these analyses are often collected from the diaphyses of long bones with an assumption of an expected rate of turnover between five and ten years, depending on the skeletal element. However, the biological foundations of this assumption are still uncertain, especially concerning the intra-skeletal and intra-element variation of isotopic signatures that may relate to patterns of remodeling. Exploring these gaps in intra-element isotopic variation requires fine-grained work using multiple bones from multiple individuals, but such work is limited …
Light Matter Interactions: A Study Of Soft Materials Using Linear And Nonlinear Spectroscopy, Muhammad Redwan Hassan
Light Matter Interactions: A Study Of Soft Materials Using Linear And Nonlinear Spectroscopy, Muhammad Redwan Hassan
Doctoral Dissertations
The adoption of complex fluids for various industrial applications is becoming normal. Complex fluids offer tunability, wide range solubility, and chemical and thermal stability which are the factors that conventional polar and non-polar solvents often lack. However, fundamental studies of these fluid systems are still lacking which is limiting the appropriate use of these complex fluids in many applications. The goal of this dissertation was to study and characterize complex fluids for application in electrolytes for redox flow batteries. Chapter 3 and chapter 4 feature the study of microemulsions and deep eutectic solvents (DES) by fluorescence techniques. Fluorescence studies of …
Geochemical And Climatic Controls On The Sulfur Cycle In Volcanic Settings: Implications For The Origin Of Sulfur-Rich Deposits Investigated By The Spirit And Opportunity Rovers On Mars, Rhianna D. Moore
Doctoral Dissertations
On Earth, volcanic activity with elevated sulfur (S) degassing in the presence of water leads to the formation of hydrothermal deposits enriched in S-bearing minerals. Similar processes may have been an important source of S on Mars. The landing sites of Gusev crater and Meridiani Planum investigated by the Spirit and Opportunity rovers, respectively, showed elevated SO42- [sulfate] concentrations, suggesting high- and low-temperature aqueous processes. However, the SO42- contribution from subsequent aqueous weathering of hydrothermal S deposits has been poorly constrained, thus its importance to regional S cycling in the landing sites is unclear. In this …
Analytical Techniques For The Analysis Of Uranium Bearing Materials, Nathaniel D. Fletcher
Analytical Techniques For The Analysis Of Uranium Bearing Materials, Nathaniel D. Fletcher
Doctoral Dissertations
The interest in the use of nuclear power has increased drastically in recent years. This is due to significantly increased efficiency at producing energy when compared to fossil fuels. With the increased use of nuclear power comes an increased need to for monitor for uranium bearing materials outside of regulatory control. This dissertation covers four projects aimed at improving the analysis of these materials. The first projects aims to develop a method that allows for the analysis of elements that exist in nature as anions by triple quadrupole ICP – MS. This would allow for the ability to measure more …
Towards Reduced-Order Model Accelerated Optimization For Aerodynamic Design, Andrew L. Kaminsky
Towards Reduced-Order Model Accelerated Optimization For Aerodynamic Design, Andrew L. Kaminsky
Doctoral Dissertations
The adoption of mathematically formal simulation-based optimization approaches within aerodynamic design depends upon a delicate balance of affordability and accessibility. Techniques are needed to accelerate the simulation-based optimization process, but they must remain approachable enough for the implementation time to not eliminate the cost savings or act as a barrier to adoption.
This dissertation introduces a reduced-order model technique for accelerating fixed-point iterative solvers (e.g. such as those employed to solve primal equations, sensitivity equations, design equations, and their combination). The reduced-order model-based acceleration technique collects snapshots of early iteration (pre-convergent) solutions and residuals and then uses them to project …
Enhancing The Performance Of The Mtcnn For The Classification Of Cancer Pathology Reports: From Data Annotation To Model Deployment, Kevin De Angeli
Enhancing The Performance Of The Mtcnn For The Classification Of Cancer Pathology Reports: From Data Annotation To Model Deployment, Kevin De Angeli
Doctoral Dissertations
Information contained in electronic health records (EHR) combined with the latest advances in machine learning (ML) have the potential to revolutionize the medical sciences. In particular, information contained in cancer pathology reports is essential to investigate cancer trends across the country. Unfortunately, large parts of information in EHRs are stored in the form of unstructured, free-text which limit their usability and research potential. To overcome this accessibility barrier, cancer registries depend on expert personnel who read, interpret, and extract relevant information. Naturally, as the number of stored pathology reports increases every day, depending on human experts presents scalability challenges. Recently, …
Experimental Approaches To Evaluating Silicate Melt Properties And Trace Element Fractionation During Crystallization At High Pressures And High Temperatures, Megan D. Mouser
Doctoral Dissertations
Current understanding of the evolution and behavior of silicate materials that form in planetary interiors at high-pressures and high-temperatures largely come from experimental work as natural samples are either rare, or physically inaccessible. Laboratory experiments provide a comprehensive way to constrain the crystallization history, elemental partitioning, and viscosity of different silicate materials at planetary mantle pressure and temperature conditions. This work utilizes two high-pressure experimental techniques, the Paris-Edinburgh apparatus, and the piston cylinder apparatus, to measure physical and chemical properties of silicate materials. The viscosity of reduced, Fe-free silicate liquids, with and without sulfur (S-free and S-bearing), were measured to …
Transition Metal Computational Catalysis: Mechanistic Approaches And Development Of Novel Performance Metrics, Brett Anthony Smith
Transition Metal Computational Catalysis: Mechanistic Approaches And Development Of Novel Performance Metrics, Brett Anthony Smith
Doctoral Dissertations
Computational catalysis is an ever-growing field, thanks in part to the incredible progression of computational power and the efficiency offered by our current methodologies. Additionally, the accuracy of computation and the emergence of new methods that can decompose energetics and sterics into quantitative descriptors has allowed for researchers to begin to identify important structure-function relationships that predict the properties of unexplored subspaces within the overall chemical space. Catalytic descriptors have been used frequently in data driven high-throughput computational screenings. With the use of machine learning, a large portion of the chemical space an be predicted in matter of minutes or …
Development Of A New High-Resolution Neutron Detector And Beta-Delayed Neutron Spectroscopy Of 24o., Shree K. Neupane
Development Of A New High-Resolution Neutron Detector And Beta-Delayed Neutron Spectroscopy Of 24o., Shree K. Neupane
Doctoral Dissertations
An efficient neutron detection system with good energy resolution is needed to correctly characterize the decays of neutron-rich nuclei where beta-delayed neutron emission is a dominant decay mode. Precision neutron spectroscopy probes nuclear structure effects in neutron-rich nuclei and is essential to exploit the opportunities in new-generation radioactive beam facilities. A new high-resolution neutron detector, Neutron dEtector with Xn Tracking (NEXT), has been constructed, characterized, and tested in decay and reaction experiments. Its essential capability is the neutron interaction position localization, which enables improvement in energy resolution without compromising detection efficiency in the time-of-flight measurements. Neutron-gamma discrimination capability of NEXT …
Tethered Axial Coordination As A Control Modality In Rhodium(Ii)-Catalyzed Carbene Transfer Reactions, Anthony Dean Abshire
Tethered Axial Coordination As A Control Modality In Rhodium(Ii)-Catalyzed Carbene Transfer Reactions, Anthony Dean Abshire
Doctoral Dissertations
Rhodium(II) paddlewheels are versatile carbene transfer catalyst that are broadly applied in insertion reactions, cycloadditions, and ylide transformations. The effects of axial coordination in rhodium(II)-catalyzed carbene transfer reactions are still little understood due to compounding factors that are difficult to isolate. Traditionally, researchers study axial coordination by addition of Lewis base additives. To ensure interaction between the Lewis base and catalyst, high molar equivalents are used. This can also have the undesired effect of hampering the activity of the catalyst and suppressing the yield of the reaction. We have developed ligands with a tethered Lewis base to overcome these issues. …
Constraining The 30p(P,Γ)31s Reaction Using 30p(D,Pγ)31p With Goddess, Rajesh Ghimire
Constraining The 30p(P,Γ)31s Reaction Using 30p(D,Pγ)31p With Goddess, Rajesh Ghimire
Doctoral Dissertations
The 30P(p,γ)31S reaction acts as a bottleneck for classical nova nucleosynthesis beyond A=30 in ONe novae, due in part to the long lifetime of 30P (∼2.5 minutes) with respect to the timescale of a nova outburst. Also, the 30P(p,γ)31S reaction rate directly affects the isotopic ratio of 30Si/28Si, which is an important nova identifier in the analysis of pre-solar grains. O/S, S/Al, O/P, and P/Al elemental abundance ratios can be used as nuclear thermometers for classical novae by constraining the 30P(p,γ)31S reaction rate.
However, direct measurement of …
Development Of Raman Spectroscopic Methods For Detection Of Molecules Indicating Life In Extraterrestrial Environments, Grace Sarabia
Development Of Raman Spectroscopic Methods For Detection Of Molecules Indicating Life In Extraterrestrial Environments, Grace Sarabia
Doctoral Dissertations
Mineral analysis is of great importance to the understanding of the world around us and worlds beyond. Geology, chemistry, and environmental studies all benefit from characterization of the structure and properties of minerals. While various techniques have been applied towards the study of minerals, we propose that Raman spectroscopy is specifically suited for the detection and study of minerals under various conditions, including for terrestrial and space applications.
In our terrestrial studies, we explored the polymorphs of calcium carbonate within freshwater mollusk shell matrices with Raman spectroscopy. We found that aragonite was the main calcium carbonate polymorph present in the …
The Impact Of A Nuclear Disturbance On A Space-Based Quantum Network, Alexander Miloshevsky
The Impact Of A Nuclear Disturbance On A Space-Based Quantum Network, Alexander Miloshevsky
Doctoral Dissertations
Quantum communications tap into the potential of quantum mechanics to go beyond the limitations of classical communications. Currently, the greatest challenge facing quantum networks is the limited transmission range of encoded quantum information. Space-based quantum networks offer a means to overcome this limitation, however the performance of such a network operating in harsh conditions is unknown. This dissertation analyzes the capabilities of a space-based quantum network operating in a nuclear disturbed environment. First, performance during normal operating conditions is presented using Gaussian beam modeling and atmospheric modeling to establish a baseline to compare against a perturbed environment. Then, the DEfense …
Microplastic Accumulation In Terrestrial Gastropods And Soils, Gregory B. Bonilla
Microplastic Accumulation In Terrestrial Gastropods And Soils, Gregory B. Bonilla
Masters Theses
Microplastics (MPs) have become an emerging threat to ecosystems across the world. Transport, impacts, and fates are grossly understudied, especially in terrestrial environments. Current research on MP bioaccumulation has focused mainly on aquatic organisms with little study of terrestrial organisms, including snails where data are nearly nonexistent. To address this, we collected and examined land snails and their surrounding soil for MP content in shell and tissue. From September 11, 2020, to October 25, 2021, cover boards were placed (n=30) along relatively undisturbed sites in hardwood, forested areas, and tall grasses in a Wildlife Management Area (WMA) in Oak Ridge …
Imaging Normal Fluid Flow In He Ii With Neutrons And Lasers — A New Application Of Neutron Beams For Studies Of Turbulence, Xin Wen
Doctoral Dissertations
Turbulence is ubiquitous in life —from biology to astrophysics. The best direct numeric simulations (DNS) have only been benchmarked against low resolution, time-averaged experimental configurations—partly because of limitations in computing power. With time, computing power has greatly increased, so there is need for higher quality data of turbulent flow. In this dissertation, we explore a solution that enables quantitative visualization measurement of the velocity field in liquid helium, which has the potential of breaking new ground for high Reynolds number turbulence research and model testing.
Our technique involves creation of clouds of molecular tracers using 3He-neutron absorption reaction in liquid …
Synthesis And Characterization Of 2,6-Diisopropylphenoxy Tetrapyrazinoporphyrazines As Potential Molecular Qubits, Benjamin Marx
Synthesis And Characterization Of 2,6-Diisopropylphenoxy Tetrapyrazinoporphyrazines As Potential Molecular Qubits, Benjamin Marx
Masters Theses
This thesis reports the synthesis of metal-free and metal-containing phthalocyanine derivatives using methods typical for that class of functional dyes. A mixture of the target compounds prepared here, one paramagnetic and one diamagnetic tetrapyrazinoporphyrazine, will be tested for their potential use in spintronics – the application of spin-active species in molecular electronics. Phthalocyanines and their derivatives are well-known for their ease of preparation and tunability; they have been utilized as sensitizers for photodynamic therapy of cancer and solar cells, as well as in catalysis and chemical sensing. Tetrapyrazinoporphyrazine complexes are compared with the parent phthalocyanine as their chemistry is similar …
On Interpreting Eddy Covariance In Small Area Agricultural Situations With Contrasting Site Management., Joel Oetting
On Interpreting Eddy Covariance In Small Area Agricultural Situations With Contrasting Site Management., Joel Oetting
Doctoral Dissertations
This dissertation examined the carbon sequestration potential of a low C:N soil amendment and its incorporation into the soil over a rolling agricultural field. A segmented planar fit was developed to assess and correct the systematic errors the topography introduces on the carbon dioxide fluxes. The carbon dioxide fluxes were then be partitioned into gross primary productivity and soil respiration to understand the influence of the contrasting management practices, using flux variance partitioning. Concomitant with the partitioning, high resolution temporal and spatial scale remote sensing images were interpolated and standardized to conduct hypothesis testing for treatment effects.
Evaluation Of Distributed Programming Models And Extensions To Task-Based Runtime Systems, Yu Pei
Evaluation Of Distributed Programming Models And Extensions To Task-Based Runtime Systems, Yu Pei
Doctoral Dissertations
High Performance Computing (HPC) has always been a key foundation for scientific simulation and discovery. And more recently, deep learning models' training have further accelerated the demand of computational power and lower precision arithmetic. In this era following the end of Dennard's Scaling and when Moore's Law seemingly still holds true to a lesser extent, it is not a coincidence that HPC systems are equipped with multi-cores CPUs and a variety of hardware accelerators that are all massively parallel. Coupling this with interconnect networks' speed improvements lagging behind those of computational power increases, the current state of HPC systems is …
Validation Of A Method For Pantoprazole And Its Sulfone Metabolite In Goat Plasma Using High Performance Liquid Chromatography, Sherry Cox, Lainey Harvill, Sarah Bullock, Joseph Smith, Joan Bergman
Validation Of A Method For Pantoprazole And Its Sulfone Metabolite In Goat Plasma Using High Performance Liquid Chromatography, Sherry Cox, Lainey Harvill, Sarah Bullock, Joseph Smith, Joan Bergman
Faculty Publications and Other Works -- Large Animal Clinical Sciences
No abstract provided.
Winter Wheat Cover Crop Increased Subsoil Organic Carbon In A Long-Term Cotton Cropping System In Tennessee, Rounak Patra, Debasish Saha, Sindhu Jagdamma
Winter Wheat Cover Crop Increased Subsoil Organic Carbon In A Long-Term Cotton Cropping System In Tennessee, Rounak Patra, Debasish Saha, Sindhu Jagdamma
Biosystems Engineering and Soil Science Publications and Other Works
Long-term cover-cropping and no-tillage practices can facilitate soil organic carbon (SOC) accumulation in agroecosystems for soil health and climate mitigation benefits. However, the contribution of these conservation management practices to SOC gain from the subsoil layers is not been extensively studied. To understand this knowledge gap, it is essential to determine the distribution of total SOC and SOC fractions in response to management practices across the soil profile. Therefore, this study was conducted by leveraging a 40-year replicated field experiment in a continuous cotton (Gossypium hirsutum) system. The management treatments examined included three cover crop treatments: 1) hairy vetch, HV …
Full Issue, Frank R. Thompson Iii
Full Issue, Frank R. Thompson Iii
National Quail Symposium Proceedings
No abstract provided.
The Evolution Of Quail Research: Trends In Themes, Cognitive Extent, And Lexical Diversity, Fidel Hernández
The Evolution Of Quail Research: Trends In Themes, Cognitive Extent, And Lexical Diversity, Fidel Hernández
National Quail Symposium Proceedings
Language is an interesting characteristic that is unique to humans. Language represents a method of human communication and is believed to reflect a person’s view of reality (Kramsch 2004). The words used by a person or a community provide insight into the ideas, concepts, and worldview held by people (Pennebaker et al. 2003). In science, publications represent a primary form of communication of ideas among scientists. Publications provide a historical record of a discipline and reflect the relative interest of a scientific community in particular concepts during a given era (Kim et al. 2018). Consequently, how word use in publications …
Effects Of Climate Change On Northern Bobwhite Nesting Chronology And Clutch Size, Justin A. Rectenwald, D. Clay Sisson, James A. Martin
Effects Of Climate Change On Northern Bobwhite Nesting Chronology And Clutch Size, Justin A. Rectenwald, D. Clay Sisson, James A. Martin
National Quail Symposium Proceedings
Widespread changes to breeding bird phenology in response to climate change have been apparent in North America for several decades. While the impact of an earlier breeding season may be minimal by itself, changes in community-level interactions can be greatly influenced because of varying responses to climate change in different trophic levels. Climate change has been shown to alter the onset of breeding season and chick survival, and lead to population declines for game birds in high latitudes, at high elevations, and on the periphery of their range. The topic of climate change in relation to northern bobwhite (Colinus …
Examining A Habitat-Weather Threshold For Northern Bobwhite Populations In The Southwestern United States, John T. Edwards, Fidel Hernández, Andrea Montalvo, Masahiro Ohnishi
Examining A Habitat-Weather Threshold For Northern Bobwhite Populations In The Southwestern United States, John T. Edwards, Fidel Hernández, Andrea Montalvo, Masahiro Ohnishi
National Quail Symposium Proceedings
In semiarid portions of the northern bobwhite (Colinus virginianus; hereafter, bobwhite) geographic distribution, weather is a strong driver of interannual abundance. However, the strength of this relationship may depend on habitat amount. Given this habitat–weather dependence, there is likely to be a threshold value for habitat that determines how strongly a bobwhite population responds to weather. Our objective was to evaluate the relationship between habitat amount and the relative influence of weather on bobwhite abundance in Texas and Oklahoma, USA and determine a potential land-cover threshold value. We collected bobwhite abundance and land-cover data from the Breeding Bird …
Climate Impacts On North American Quail, Shelby M. Perry, Erin Moser, Jeffrey G. Whitt, Kelly S. Reyna
Climate Impacts On North American Quail, Shelby M. Perry, Erin Moser, Jeffrey G. Whitt, Kelly S. Reyna
National Quail Symposium Proceedings
North America’s quail population trends are often linked to regional climate. Extreme climate events such as severe drought, hard freezes, or excessive winter precipitation can reduce quail populations by as much as 84%. Above-average spring and summer temperatures coincident with drought can reduce the laying season for quail by ≤60 days. Exposure of quail eggs to high temperatures during preincubation can initiate and alter embryonic development. Here, we review the impacts of extreme climate events and a changing climate on the survival, reproduction, and population trends of 6 North American quail species: California quail (Callipepla californica), Gambel’s quail …