Physical Sciences and Mathematics Commons^™

A Study Of The Curcumin Method For Boron Determination, James Edward Hardcastle

Master's Theses

The purpose of the research project, of which this thesis is a partial report, was two fold: first, to develop a method for determining small quantities of boron, and second, to develop a rapid field test for the determination of atmospheric boron. A literature survey revealed that the curcumin method is the most sensitive colorimetric method presently available for boron determination. Also, the curcumin paper test should be readily adapted to the determination of atmospheric boron.

The Chelation Of Cu(Ii) With 1, 3-Bis(Tris(Hydroxymethyl)Methylamino)-2-Propanol And 1, 3-Bis (2-Hydroxyethylamino)-2-Propanol, David Andrew Jackson Jr.

Master's Theses

The chelating agent 1, 3-bis(2-hydroxyethylamino)-2-propanol dihydro­chloride was prepared and preliminary examinations of the Cu(ll) and Fe(lll) complexes were carried out spectrophotometrically. This dihydrochloride as well as 1, 3 bis(tris(hydroxymethyl)methylamino)-2-propanol dihydrochloride. were converted from the chloride salts to their corresponding ammonium bases. The conversion was carried out by passing an aqueous solution of each chloride salt through an ion exchange column containing Amberlite XE-78 resin.

Solutions of these bases were standardized for use in potentiometric titration&. Each ammonium base was titrated with standard perchloric acid at 20°C, 30°C, and 40°C. The dissociation constants. were calculated using these data. Aqueous solutions of …

Preparation Of Elemental Boron And Measurement Of Its Emittance At Incandescent Temperatures, Claude P. Talley

Master's Theses

The normal spectral emittance at 0. 65 microns of elemental boron specimens was measured at incandescent temperatures by the hollow-tube method, This was made possible by depositing boron onto thin-walled hollow tubes of graphite and molybdenum. An approximate value of the total hemispherical emittance for boron was also obtained. The deposition of boron was accomplished by chemical vapor plating with boron tribromide and hydrogen. The boron produced was characterized in several ways.

The Development Of Nickel Electrodeposits On Copper Monocrystals As Studied With The Electron Microscope, Lucille Burnett Garmon

Master's Theses

Important theoretical and experimental developments in the field of electrocrystallization on single crystals are briefly reviewed and new data presented. The deposition of nickel from a Watts-type bath onto electrolytically polished mono crystals of copper is the system chosen for study. Various aspects of the structural changes in the deposit with increasing thickness are considered. The electron microscope is the main tool employed and the deposit is studied by detaching it from the basis metal as well as by the use of surface replicas. Short backgrounds in crystallography and electron microscopy are included.

A Chromatographic Study Of The Polyphenols In Cured Tobacco, Marvin Dennis Edmonds

Master's Theses

The object of this project was to isolate, separate, and identify the polyphenols in tobacco. Following this, the aim was to develop a method for the quantitative determination of the major polyphenols in tobacco.

Existing methods for the determination of polyphenols in tobacco involve lengthy procedures which are concerned with one or two of the polyphenols rather than the· complete class of compounds. The methods consist of exhaustive extraction procedures, lengthy chromatographic procedures and numerous methods of identification.

Extensive research on the determination of polyphenols by chromatography has been carried out in the field of tobacco and in other fields. …