Physical Sciences and Mathematics Commons^™

Gamma-Ray Metallic Magnetic Calorimeters With Nbta Passive Persistent Switches And Electroformed Au Absorbers, Ruslan Hummatov

Physics & Astronomy ETDs

Metallic Magnetic Calorimeters (MMCs) are low temperature particle detectors which can be used for a wide range of applications including high-resolution γ -ray spectroscopy. High energy resolution in γ -ray spectroscopy is desired for Non Destructive Assay (NDA) of nuclear material and improved measurements of nuclear data. Our group has been developing γ -ray MMCs that should ultimately provide energy resolution more than an order of magnitude better than the benchmark detector technology, high purity germanium detectors (HPGe). Two components of these MMCs have been developed as a part of this dissertation: an on-chip passive superconducting persistent current switch and …

Weighted Inequalities For Dyadic Operators Over Spaces Of Homogeneous Type, David Edward Weirich

Mathematics & Statistics ETDs

A so-called space of homogeneous type is a set equipped with a quasi-metric and a doubling measure. We give a survey of results spanning the last few decades concerning the geometric properties of such spaces, culminating in the description of a system of dyadic cubes in this setting whose properties mirror the more familiar dyadic lattices in R^n . We then use these cubes to prove a result pertaining to weighted inequality theory over such spaces. We develop a general method for extending Bellman function type arguments from the real line to spaces of homogeneous type. Finally, we uses this …

Assessment Of Vegetation Response To Wildfire At Bandelier National Monument, New Mexico: Case Study Of The Las Conchas Fire, Gladys Valentin-Gonzalez

Geography ETDs

In the past couple of decades, there has been an increase in the occurrence of wildfire events in the United States. The U.S. Forest Service estimates that over 73,000 wildfires on average occur annually in the U.S., burning about 7.3 million acres of land. Bandelier National Monument, in northern New Mexico, has been affected by several wildfires in the past 40 years, one of the most recent being the Las Conchas Fire in 2011, which burned over 60,700 hectaresin Bandelier National Monument and Valles Caldera National Preserve. This research explores a remote-sensing based assessment of vegetation response to and recovery …

Synthesis, Characterization, And Spectroscopy Of Donor-Acceptor Charge Transfer Complexes, Dominic K. Kersi

Chemistry and Chemical Biology ETDs

A series of square-planar metal (diimine)(dichalcogenolene) chromophoric complexes have been synthesized, characterized and studied spectroscopically. Studies conducted on diimineplatinum(II) dichalcogenolene complexes (LPtL’) using time resolved spectroscopic techniques such as transient absorption and emission, reveal a charge-separated excited state of the type dichalcogenolene → diimine charge-transfer (LL’CT) [(dichalcogenolene^•+)Pt(diimine^•-) with an open shell donor-acceptor biradical character. Long-live excited state lifetimes were observed for these complexes upon visible photoexcitation of the LL’CT or MMLL’CT band. A direct linear relationship is observed to exist between photoluminescence rates, calculated SOC matrix elements, and ¹³C-NMR chemical shifts.

A series of …

Which Factors Influence Student Success In Intermediate Algebra, Math 101-102-103?, Linh T. Ward

Mathematics & Statistics ETDs

At The University of New Mexico (UNM), Intermediate Algebra (MATH 120 and MATH 101-102-103) has historically been a so-called “killer course”, with very low pass rates: approximately 40% in Fall 2009 to Spring 2011 and about 50% from Fall 2011 to Spring 2013. Furthermore, many students failed the class multiple times. Since 2013, a computer system called ALEKS has been used to teach the course and, along with some additional interventions, on Albuquerque/Main campus success rates for MATH 101 have increased to roughly 80% and MATH 102 to about 70%. This thesis provides a strategy to identify those 20-30% as-risk …

Hydrogeochemical Investigation Of Recharge Pathways To Intermediate And Regional Groundwater In Cañon De Valle And Technical Area 16, Los Alamos National Laboratory, Brendan W. Brady

Civil Engineering ETDs

In aquifers consisting of fractured or porous igneous rocks, as well as conglomerate and sandstone products of volcanic formations, silicate minerals actively dissolve and precipitate (Eby, 2004; Eriksson, 1985; Drever, 1982). Dissolution of hydrated volcanic glass is also known to influence the character of groundwater to which it is exposed (White et al., 1980). Hydrochemical evolution, within saturated zones of volcanic formations, is modeled here as a means to resolve the sources feeding a perched groundwater zone. By observation of solute mass balances in groundwater, together with rock chemistry, this study characterizes the chemical weathering processes active along recharge pathways …

Investigating Scalable Manufacturing Of High-Conductivity Wires And Coatings From Ultra-Long Carbon Nanotubes, Pouria Khanbolouki

Mechanical Engineering ETDs

Carbon nanotubes (CNTs) are a promising candidate for next generation of electrical wirings and electromagnetic interference (EMI) shielding materials due to their exceptional mechanical and electrical properties. Wires and coatings from ultralong nanotubes that are highly crystalline, well-aligned and densely packed can achieve this goal. High-performance CNT conductors will be relatively lightweight and resistant to harsh conditions and therefore can potentially replace current conductors in many industries including aerospace, automotive, gas and oil.

This thesis investigates a new manufacturing approach, based on conventional solution coating and wire drawing methods, to fabricate high conductivity wires and coatings from ultra-long carbon nanotubes. …

Formation Of Highly Functionalized Indole Through Carbon-Carbon Bond Cleavage, Ryan A. S. Pike

Chemistry and Chemical Biology ETDs

Indoles are one of the most abundant heterocycles found in nature and have a wide range of functions. There are a wide variety of indole synthesis methods known both in synthetic chemistry and through biosynthesis. Many of the known indole synthesis routes use a benzene derivative or cyclized ring structure derivative as a starting material. Here, we describe a novel synthetic method utilizing 1, 3-diketones and fumaronitrile with a catalytic amount of base to form a highly functionalized indole as our product. We have isolated and characterized 12 functionalized indoles.

Construction Of Synthetic Signal Pathways In Mammalian Cells Via Induced Protein Proximity, Guihua Zeng

Chemistry and Chemical Biology ETDs

Cell signaling translates extracellular signals into intracellular processes that carry out cellular functions. The introduction of artificial signaling networks using synthetic biology methods has facilitated the investigation of signaling mechanisms and the generation of novel cell functions. Several synthetic biology methods that are based on chemical controls have been developed to provide precise temporal regulation. In my dissertation, we constructed new synthetic biology engineering strategies to control tailored cellular events.

Described in Chapter 2, we developed a new chemical strategy to generate de novo signaling pathways that link a signaling molecule, H₂O₂, to different downstream cellular …

Proposed Method For Measuring The Let Of Radiotherapeutic Particle Beams, Stephen D. Bello

Physics & Astronomy ETDs

The Bragg peak geometry of the depth dose distributions for hadrons allows for precise and effective dose delivery to tumors while sparing neighboring healthy tissue. Further, compared against other forms of radiotherapeutic treatments, such as electron beam therapy (EBT) or photons (x and \(\gamma\)-rays), hadrons create denser ionization events along the particle track, which induces irreparable damage to DNA, and thus are more effective at inactivating cancerous cells. The measurement of radiation's ability to inactivate cellular reproduction is the relative biological effectiveness (RBE). A quality related to the RBE that is a measurable physical property is the linear energy transfer …

Improving Hpc Communication Library Performance On Modern Architectures, Matthew G. F. Dosanjh

Computer Science ETDs

As high-performance computing (HPC) systems advance towards exascale (10^18 operations per second), they must leverage increasing levels of parallelism to achieve their performance goals. In addition to increased parallelism, machines of that scale will have strict power limitations placed on them. One direction currently being explored to alleviate those issues are many-core processors such as Intel’s Xeon Phi line. Many-core processors sacrifice clock speed and core complexity, such as out of order pipelining, to increase the number of cores on a die. While this increases floating point throughput, it can reduce the performance of serialized, synchronized, and latency sensitive code …

Nanowire-Based Light-Emitting Diodes: A New Path Towards High-Speed Visible Light Communication, Mohsen Nami

Physics & Astronomy ETDs

Nano-scale optoelectronic devices have gained significant attention in recent years. Among these devices are semiconductor nanowires, whose dimeters range from 100 to 200 nm. Semiconductor nanowires can be utilized in many different applications including light-emitting diodes and laser diodes. Higher surface to volume ratio makes nanowire-based structures potential candidates for the next generation of photodetectors, sensors, and solar cells. Core-shell light-emitting diodes based on selective-area growth of gallium nitride (GaN) nanowires provide a wide range of advantages. Among these advantages are access to non-polar m-plane sidewalls, higher active region area compared to conventional planar structures, and reduction of threading …

Miniclean Dark Matter Experiment, Juijen Wang

Physics & Astronomy ETDs

Particle Dark Matter is a hypothesis accounting for a number of observed astrophysical phenomena such as the anomalous galactic rotation curves. From these astronomical observation, about 23% of the universe appears to consist of dark matter. Among the possible candidates for dark matter, a plausible one is a Weakly Interacting Massive Particle (WIMP). A particle with the required properties is beyond the standard model of particle physics. The MiniCLEAN experiment is single-phase liquid-argon detector instrumented with 92 photomultiplier tubes placed inside the cryogenic liquid with 4-pi coverage of a 500 kg (150 kg) target (fiducial) mass. For this experiment, PMT …

Molecular Tracers Of Star Formation Feedback In Nearby Galaxies, Mark Gorski

Physics & Astronomy ETDs

The energy and momentum injected into the ISM from stars has a drastic effect on the star formation history of a galaxy. This is called feedback. It is responsible for the inefficient collapse of the ISM into stars. The ``Survey of Water and Ammonia in Nearby Galaxies" (SWAN) is a survey of molecular line tracers in four nearby galaxies. By using molecular tracers of feedback, we provide insights into the star forming ecosystem of the galaxies NGC 253, IC 342, NGC 6946, and NGC 2146. These galaxies were chosen to span an order of magnitude in star formation rate and …

Nonlinear Waves, Instabilities And Singularities In Plasma And Hydrodynamics, Denis Albertovich Silantyev

Mathematics & Statistics ETDs

This work concentrates on Langmuir wave filamentation instability in the kinetic regime of plasma and computation of Stokes wave with high precision using conformal maps.

Nonlinear effects are present in almost every area of science as soon as one tries to go beyond the first order approximation. In particular, nonlinear waves emerge in such areas as hydrodynamics, nonlinear optics, plasma physics, quantum physics, etc. The results of this work are related to nonlinear waves in two areas, plasma physics and hydrodynamics, united by concepts of instability, singularity and advanced numerical methods used for their investigation.

The first part of this …

Novel Design Strategies For Platinum-Containing Conjugated Polymers And Small Molecules For Organic Solar Cells, Wenhan He

Chemistry and Chemical Biology ETDs

Current state-of-the-art organic solar cells (OSCs) adopt the strategy of using conjugated polymers or small molecules as donors and fullerene derivatives as acceptors in their active layers. Regarding to the donors of interest, the conjugated polymers and small molecules coupled with heavy metals have been less explored compared to their counterparts. Among various transition metal complexes applied, Pt(II) complexes are unique because of their intrinsic square planar geometries and ability to serve as building blocks for conjugated systems. Furthermore, the heavy metal Pt facilitates the formation of triplet excitons with longer life times through spin-orbital coupling which are of benefit …

Trace Formulas For Perturbations Of Operators With Hilbert-Schmidt Resolvents, Bishnu Prasad Sedai

Mathematics & Statistics ETDs

In this dissertation, we study Taylor approximations of functions of operators with Hilbert-Schmidt resolvents. We obtain integral representations for traces of the respective Taylor remainders that are analogous to trace formulas obtained in the case of Schatten perturbations in [10, 11, 16].

Geochemistry Of Volatiles Released By Incipient Continental Rifting And Subduction Processes, Hyunwoo Lee

Earth and Planetary Sciences ETDs

Volatiles (N2, CO2, and He) are released by volcanism and hydrothermal activity during continental rifting and subduction processes. Analyses of volatile components have been conducted to obtain gas contents (CO2, SO2, H2S, N2, Ar, He, and so on), stable isotope compositions (δ13C, δ15N, and so on), and noble gas isotopes (3He/4He, 40Ar/36Ar, and so on). This dissertation includes four chapters to report new nitrogen isotope fractionation factors of bubbling gases during gas-water transfer at various water temperatures (Chapter 1), first measurements of massive amounts of CO2 released by incipient continental rifting in the Magadi and Natron Basin, East African Rift …

Evaluation And Enhancement Of Clean Energy Systems: Analytical, Computational And Experimental Study Of Solar And Nuclear Cycles, Nima Fathi

Mechanical Engineering ETDs

Clean (and specifically renewable) energy is steadily improving its global share. However, finite availability of fossil fuels and the growing effects of climate change make it an urgent priority to convince the industry and governments to incentivize investment in the renewable energy field and to make it more attractive by decreasing the capital cost. Until recently, uncertainties in funding limited renewable energy development, especially in the US. That limitation has been one of the barriers to progress. Another limitation of many renewable energy systems is the variability in their output, which makes them unsuitable for baseline power production. Therefore, fossil …

High Order Hermite And Sobolev Discontinuous Galerkin Methods For Hyperbolic Partial Differential Equations, Adeline Kornelus

Mathematics & Statistics ETDs

Many real-world problems involving dynamics of solid or fluid bodies can be modeled by hyperbolic partial differential equations (PDEs). Up to this point, only solutions to selected PDEs are available. Many PDEs are physically or geometrically complex, resulting in difficulties computing the analytical solutions. In this thesis, we focus on numerical methods for approximating solutions to hyperbolic PDEs. Long-term simulation for the motion of the body described by the PDE requires a method that is not only robust and efficient, but also produces small error because the error will be propagated and accumulated over the course of the simulation. Therefore, …

Ion Size Effects On The Properties Of Charge Regulating Electric Double Layers, Divya Jyoti Prakash

Nanoscience and Microsystems ETDs

The behavior of charged interfaces formed in various systems like colloidal solution, fuel cells, battery, electro-deposition, catalysis is governed by the properties of electrical double layer(EDL). Civilized model with charge regulation boundary condition determined by thermodynamic equilibrium at the interface has been used to model electrical double layer and shows that size of the solvent plays a critical role in characterizing the properties of EDL using classical density functional theory.This thesis investigates the impact of ion size in electrolyte solutions on the electrical double layer formed at the interface using a similar model. It is found that ion size greatly …

Distributed Knowledge Discovery For Diverse Data, Hossein Hamooni

Computer Science ETDs

In the era of new technologies, computer scientists deal with massive data of size hundreds of terabytes. Smart cities, social networks, health care systems, large sensor networks, etc. are constantly generating new data. It is non-trivial to extract knowledge from big datasets because traditional data mining algorithms run impractically on such big datasets. However, distributed systems have come to aid this problem while introducing new challenges in designing scalable algorithms. The transition from traditional algorithms to the ones that can be run on a distributed platform should be done carefully. Researchers should design the modern distributed algorithms based on the …

Comparison Of Two Methods In Estimating Standard Error Of Simulated Moments Estimators For Generalized Linear Mixed Models, Danielle K. Duran

Mathematics & Statistics ETDs

We consider standard error of the method of simulated moment (MSM) estimator for generalized linear mixed models (GLMM). Parametric bootstrap (PB) has been used to estimate the covariance matrix, in which we use the estimates to generate the simulated moments. To avoid the bias introduced by estimating the parameters and to deal with the correlated observations, (Lu, 2012) proposed a multi-stage block nonparametric bootstrap to estimate the standard errors. In this research, we compare PB and nonparametric bootstrap methods (NPB) in estimating the standard errors of MSM estimators for GLMM. Simulation results show that when the group size is large, …

Observed Changes In Climate And Streamflow In The Upper Rio Grande Basin, Shaleene Chavarria

Earth and Planetary Sciences ETDs

Observed streamflow and climate data are used to test the hypothesis that climate change is already affecting the streamflow volume derived from snow accumulation in ways consistent with climate model-based projections of 21st century streamflow. Annual and monthly changes in streamflow volume and surface climate variables on the upper Rio Grande (URG) near its headwaters in southern Colorado are assessed for water years 1958-2015. Trends in discharge are examined together with variations in snow water equivalent and surface climate variables. Results indicate that temperatures in the basin have increased significantly primarily in the winter and spring seasons, April 1 snow …

An Integrated Bioinformatic/Experimental Approach For Discovering Novel Type Ii Polyketides Encoded In Actinobacterial Genomes, Wubin Gao

Chemistry and Chemical Biology ETDs

Discovery of new natural products (NPs) is critical both for diseases treatment and crops protection. Numerous NP biosynthetic gene clusters (BGCs) in sequenced microbial genomes allow identification of new NPs through genome mining. Developing an integrated bioinformatic/experimental approach for discovering novel type II polyketides (PK-IIs) facilitates investigation of this family of NPs in an efficient, systematic way. Here, we developed an approach to analyze ketosynthase α/β (KSα/β) gene sequences to predict PK-II core structures, allowing us to target novel PK-II BGCs either from isolated genomic DNA or genomes from the NCBI databank, and to isolate novel PK-IIs produced by these …

Oxygen Isotope Composition Of Water In Martian Meteorites, Oleg Vitalivich Maltsev

Earth and Planetary Sciences ETDs

The oxygen isotope composition of water extracted from Martian meteorites appears not to be in isotopic equilibrium with the silicate portion of the meteorites. This disequilibrium suggests the existence of multiple distinct oxygen isotope reservoirs on planet Mars. Here we present oxygen isotope measurements of waters extracted from Martian shergottites Tissint, Zagami and NWA-7042 and from nakhlite NWA-10153. These waters were extracted by stepwise heating to preserve segregation between low temperature adsorbed waters, intermediate temperature mineral waters and the high temperature mineral structural OH groups. The results of our study, analyzed cooperatively with previous work by Karlsson et al., (1992) …

Microdischarges Utilized In Portable Gas Sensing And Their Atmospheric Contaminants, Colin H. Sillerud

Chemical and Biological Engineering ETDs

Portable applications of microdischarges such as the chemical detection, remediation of gaseous wastes, or the destruction of volatile organic compounds will mandate operation in the presence of contaminant species. This work examines the temporal evolution of microdischarge optical and ultraviolet emissions during pulsed operation by experimental methods. By varying the pulse length of a microdischarge initiated in a 4-hole silicon microcavity array operating in a 655 Torr ambient primarily composed of Ne, we were able to measure the emission growth rates for different contaminant species native to the discharge environment as a function of pulse length. It was found that …

High Precision Refractive Index Measurement Techniques Applied To The Analysis Of Neutron Damage And Effects In Caf2 Crystals, Joseph P. Morris Ph.D.

Nuclear Engineering ETDs

Neutron irradiation damages material by atomic displacements. The majority of these damage regions are microscopic and difficult to study, though they can cause a change in density and thus a change in refractive index in transparent materials. This work utilized CaF₂ crystals to track refractive index change based on neutron radiation dose. High precision refractive index measurements were performed utilizing a nested-cavity mode-locked laser where the CaF₂ crystal acted as a Fabry-Pérot Etalon (FPE). By comparing the repetition rate of the cavity and the repetition rate of the FPE, refractive index change was determined. Following several irradiation experiments, …

Comprehensive Silica Removal With Ferric Compounds For Industrial Wastewater Reuse, Ehren D. Baca

Civil Engineering ETDs

Cooling towers, integrated circuit (IC) manufacture and reverse osmosis (RO) generate copious amounts of wastewater high in colloidal and reactive silica inhibiting on-site or synergistic reuse. Silica present in cooling water can reach solubility limits via evaporation and form impervious scale on heat transfer surfaces that decreases efficiency. When water is treated by RO operating at high rejection, silica forms difficult-to-remove scale on the membrane feed side in the form of glassy patches and communities of aggregate particles, inhibiting aspirations for zero liquid discharge. Current methods for silica scale mitigation include abundant dosing with chemical antiscalents or complex operating schemes. …

Spam, Fraud, And Bots: Improving The Integrity Of Online Social Media Data, Amanda Jean Minnich

Computer Science ETDs

Online data contains a wealth of information, but as with most user-generated content, it is full of noise, fraud, and automated behavior. The prevalence of "junk" and fraudulent text affects users, businesses, and researchers alike. To make matters worse, there is a lack of ground truth data for these types of text, and the appearance of the text is constantly changing as fraudsters adapt to pressures from hosting sites. The goal of my dissertation is therefore to extract high-quality content from and identify fraudulent and automated behavior in large, complex social media datasets in the absence of ground truth data. …