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Physical Sciences and Mathematics Commons

Open Access. Powered by Scholars. Published by Universities.®

University of Nevada, Las Vegas

2004

Physical Chemistry

Calcium phosphate; Fluorides; Fluorination; Radioactive wastes — Storage; Separation (Technology); Zirconium compounds

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Full-Text Articles in Physical Sciences and Mathematics

Evaluation Of Fluorapatite As A Waste-Form Material, Dennis W. Lindle, Oliver Hemmers Jan 2004

Evaluation Of Fluorapatite As A Waste-Form Material, Dennis W. Lindle, Oliver Hemmers

Separations Campaign (TRP)

Fluorapatite, fluorinated calcium phosphate, has been identified as a potential matrix for the entombment of the zirconium fluoride fission product waste stream from the proposed FLEX process. If the efficacy of fluorapatite based waste-storage can be demonstrated, then new and potentially more-efficient options for handling and separating high-level wastes, based on fluoride-salt extraction, will become feasible. This proposal is for renewal of the UNLV portion of a dual-path research project to develop a process to fabricate a synthetic fluorapatite waste form for the ZrF4, FP waste stream, characterize the waste form, examine its performance under environmental conditions, and …