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Articles 1 - 6 of 6
Full-Text Articles in Physical Sciences and Mathematics
Potential Application Of Ionic Liquids For Electrodeposition Of The Material Targets For Production Of Diagnostic Radioisotopes, Maciej Chotkowski, Damian Połomski, Kenneth Czerwinski
Potential Application Of Ionic Liquids For Electrodeposition Of The Material Targets For Production Of Diagnostic Radioisotopes, Maciej Chotkowski, Damian Połomski, Kenneth Czerwinski
Chemistry and Biochemistry Faculty Research
An overview of the reported electrochemistry studies on the chemistry of the element for targets for isotope production in ionic liquids (ILs) is provided. The majority of investigations have been dedicated to two aspects of the reactive element chemistry. The first part of this review presents description of the cyclotron targets properties, especially physicochemical characterization of irradiated elements. The second part is devoted to description of the electrodeposition procedures leading to obtain elements or their alloys coatings (e.g., nickel, uranium) as the targets for cyclotron and reactor generation of the radioisotopes. This review provides an evaluation of the role ILs …
Lead Complexation By Humic Acids And Their Analogs: A Voltammetric Study, Spencer Steinberg, Vernon Hodge
Lead Complexation By Humic Acids And Their Analogs: A Voltammetric Study, Spencer Steinberg, Vernon Hodge
Chemistry and Biochemistry Faculty Research
© 2020 by the authors. Licensee MDPI, Basel, Switzerland. Differential pulse polarography (DPP) was used to assess the interaction of Pb2+ with various humic acid analogs and several humic acids. DPP analysis demonstrated that the reduction peak maximum (Ep) for Pb2+ shifted to more negative values in the presence of humic acids and humic acid analogs. The observed Ep for Pb2+ in the presence of humic acids and humic acid analogs is influenced by ligand concentration, solution pH and Pb2+ concentration. Shifts in the Ep for Pb2+ are related to the reduction potential and can be rationalized using the Lingane …
Countercurrent Actinide Lanthanide Separation Process (Alsep) Demonstration Test With A Simulated Purex Raffinate In Centrifugal Contactors On The Laboratory Scale, Andreas Wilden, Fabian Kreft, Dimitri Schneider, Zaina Paparigas, Giuseppe Modolo, Gregg J. Lumetta, Artem V. Gelis, Jack D. Law, Andreas Geist
Countercurrent Actinide Lanthanide Separation Process (Alsep) Demonstration Test With A Simulated Purex Raffinate In Centrifugal Contactors On The Laboratory Scale, Andreas Wilden, Fabian Kreft, Dimitri Schneider, Zaina Paparigas, Giuseppe Modolo, Gregg J. Lumetta, Artem V. Gelis, Jack D. Law, Andreas Geist
Chemistry and Biochemistry Faculty Research
An Actinide Lanthanide Separation Process (ALSEP) for the separation of trivalent actinides (An(III)) from simulated raffinate solution was successfully demonstrated using a 32-stage 1 cm annular centrifugal contactor setup. The ALSEP solvent was composed of a mixture of 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester (HEH[EHP]) and N,N,N′,N′-tetra-(2-ethylhexyl)-diglycolamide (T2EHDGA) in n-dodecane. Flowsheet calculations and evaluation of the results were done using the Argonne’s Model for Universal Solvent Extraction (AMUSE) code using single-stage distribution data. The co-extraction of Zr(IV) and Pd(II) was prevented using CDTA (trans-1,2-diaminocyclohexane-N,N,N′,N′-tetraacetic acid) as a masking agent in the feed. For the scrubbing of co-extracted Mo; citrate-buffered acetohydroxamic acid was …
Chemist Table: A Tool For Designing Or Modifying Instruction For A Systems Thinking Approach In Chemistry Education, Sarah York, Marykay Orgill
Chemist Table: A Tool For Designing Or Modifying Instruction For A Systems Thinking Approach In Chemistry Education, Sarah York, Marykay Orgill
Chemistry and Biochemistry Faculty Research
Recently, there have been calls to integrate systems thinking approaches into chemistry education in order to strengthen students’ conceptual understanding, build their problem-solving capabilities, and prepare them to make informed, ethical decisions about globally relevant issues, such as sustainability. Unfortunately, implementation of systems thinking approaches in chemistry classrooms currently poses challenges. Exemplar systems thinking materials with a STEM focus are limited, particularly at the tertiary level. Moreover, the science education community has yet to agree upon a systems thinking definition or develop a comprehensive list of systems thinking skills that students should develop. Thus, a current priority for the advancement …
Thermotropic Liquid-Crystalline And Light-Emitting Properties Of Bis(4-Aalkoxyphenyl) Viologen Bis(Triflimide) Salts, Pradip K. Bhowmik, Muhammed Kareem M. Al-Karawi, Shane T. Killarney, Erenz J. Dizon, Anthony Chang, Jongin Kim, Si L. Chen, Ronald Carlo G. Principe, Andy Ho, Haesook Han
Thermotropic Liquid-Crystalline And Light-Emitting Properties Of Bis(4-Aalkoxyphenyl) Viologen Bis(Triflimide) Salts, Pradip K. Bhowmik, Muhammed Kareem M. Al-Karawi, Shane T. Killarney, Erenz J. Dizon, Anthony Chang, Jongin Kim, Si L. Chen, Ronald Carlo G. Principe, Andy Ho, Haesook Han
Chemistry and Biochemistry Faculty Research
A series of bis(4-alkoxyphenyl) viologen bis(triflimide) salts with alkoxy chains of different lengths were synthesized by the metathesis reaction of respective bis(4-alkoxyphenyl) viologen dichloride salts, which were in turn prepared from the reaction of Zincke salt with the corresponding 4-n-alkoxyanilines, with lithium triflimide in methanol. Their chemical structures were characterized by 1H and 13C nuclear magnetic resonance spectra and elemental analysis. Their thermotropic liquid-crystalline (LC) properties were examined by differential scanning calorimetry, polarizing optical microscopy, and variable temperature X-ray diffraction. Salts with short length alkoxy chains had crystal-to-liquid transitions. Salts of intermediate length alkoxy chains showed both crystal-to-smectic A (SmA) …
Author Correction: Closing The Nuclear Fuel Cycle With A Simplified Minor Actinide Lanthanide Separation Process (Alsep) And Additive Manufacturing, Artem V. Gelis, Peter Kozak, Andrew T. Breshears, M. Alex Brown, Cari Launiere, Emily L. Campbell, Gabriel B. Hall, Tatiana G. Levitskaia, Vanessa E. Holfeltz, Gregg J. Lumetta
Author Correction: Closing The Nuclear Fuel Cycle With A Simplified Minor Actinide Lanthanide Separation Process (Alsep) And Additive Manufacturing, Artem V. Gelis, Peter Kozak, Andrew T. Breshears, M. Alex Brown, Cari Launiere, Emily L. Campbell, Gabriel B. Hall, Tatiana G. Levitskaia, Vanessa E. Holfeltz, Gregg J. Lumetta
Chemistry and Biochemistry Faculty Research
No abstract provided.