Open Access. Powered by Scholars. Published by Universities.®
Physical Sciences and Mathematics Commons™
Open Access. Powered by Scholars. Published by Universities.®
Articles 1 - 3 of 3
Full-Text Articles in Physical Sciences and Mathematics
Forcing Cesium Into Higher Oxidation States Via Useful Hard X-Ray Induced Chemistry At Extreme Conditions, Daniel Thomas Sneed
Forcing Cesium Into Higher Oxidation States Via Useful Hard X-Ray Induced Chemistry At Extreme Conditions, Daniel Thomas Sneed
UNLV Theses, Dissertations, Professional Papers, and Capstones
Recent theoretical work published in Nature Chemistry postulates the existence of cesium in high oxidation states when bonding with fluorine. It is thus predicted to behave as a p-block element (such as xenon) at pressures above 5 GPa. At these pressures, fluorine atoms may bond with the inner p-shell electrons forming CsFn, where n may vary from 2 up to 6; thus the oxidation state of Cs may change up to 6+. My research focused on physically synthesizing these compounds and to verify that, given the right conditions, bonding doesn't only occur with valence electrons, but with the inner p-shell …
High-Pressure Properties Of Several Narrow Bandgap Semiconductors From First-Principles Calculations, Andrew Michael Alvarado
High-Pressure Properties Of Several Narrow Bandgap Semiconductors From First-Principles Calculations, Andrew Michael Alvarado
UNLV Theses, Dissertations, Professional Papers, and Capstones
The electronic, thermodynamic, and structural properties of three semiconducting materials, ZnO, InN, and PbS, at high pressure are investigated utilizing first-principles calculations based on density function theory. The first two systems, ZnO and InN, crystalize as hexagonal structures at ambient conditions and transition to a cubic structure at higher pressures. The last system, PbS, is cubic at ambient conditions, but transitions to an orthorhombic structure at higher pressure. At ambient conditions, these materials are well known semiconductors with vast amount of research and a variety of wide ranging applications in electrical devices. However, there is a lack of understanding of …
Impedance Spectroscopy Studies Of Yttria Stabilized Zirconia Under Extreme Conditions, Quinlan Blaine Smith
Impedance Spectroscopy Studies Of Yttria Stabilized Zirconia Under Extreme Conditions, Quinlan Blaine Smith
UNLV Theses, Dissertations, Professional Papers, and Capstones
Yttria Stabilized Zirconia (YSZ) is of interest for many industries. Varying amounts of Yttria (Y2O3) can be doped into Zirconia (ZrO2) to create materials with specific characteristics. For instance, 3mol% YSZ (3YSZ) is known to be a super hard material and is used as a coating on drill tips and as an abrasive. Eight mol% YSZ (8YSZ) is commonly used as a solid electrolyte in Solid Oxide Fuel Cells because of its good ionic conducting abilities and stability at high temperatures. In this thesis project, a novel experimental setup was created and used to study the ionic conductivity of (3 …