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Physical Sciences and Mathematics Commons

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Full-Text Articles in Physical Sciences and Mathematics

Patterns In Trash: Factors That Drive Municipal Solid Waste Recycling, Jared Starr Jan 2014

Patterns In Trash: Factors That Drive Municipal Solid Waste Recycling, Jared Starr

Masters Theses 1911 - February 2014

Municipal recycling is driven by a variety of factors. Yet how these factors change over time is not well understood. I analyze a suite of contextual and program variable in multiple time periods, spanning 16 years, in the Commonwealth of Massachusetts. Based on the models run, I reach the surprising conclusion that most program variables have an insignificant effect on recycling rates. These findings can inform municipal officials and waste managers as they seek new ways to increase municipal recycling participation.


Push-Pull Molecules: Models And Polymer Building Blocks For Organic Photovoltaic Applications, Raymond Devaughn Jan 2014

Push-Pull Molecules: Models And Polymer Building Blocks For Organic Photovoltaic Applications, Raymond Devaughn

Masters Theses 1911 - February 2014

Several fluorenone alkynyl based oligo conjugated molecules were synthesized and characterized. Most compounds exhibited UV-Vis absorption onset at ca. 500 nm and a PL emission onset of ~329-370 nm, with excimer emission suspected from most systems near ~530-560 nm. Experimentally determined EHOMO and ELUMO energies range from -6.02 to -5.73 eV and -3.47 and 3.55 eV, respectively, with the lowest experimental Eg lying at -2.26 eV for 2-(trimethoxyphenylacetylene)-fluorenone. Cyclic voltammetry indicates quasi-reversible reduction for all systems, with 2,7-bis(nitrophenylacetylene)fluorenone exhibiting a high reduction potential of -1.25 eV. Only 2,7-bis(trimethoxyphenylacetylene)fluorenone exhibited a quasi-reversible oxidation, due to electron rich methoxy …


Free Wake Potential Flow Vortex Wind Turbine Modeling: Advances In Parallel Processing And Integration Of Ground Effects, Nathaniel B. Develder Jan 2014

Free Wake Potential Flow Vortex Wind Turbine Modeling: Advances In Parallel Processing And Integration Of Ground Effects, Nathaniel B. Develder

Masters Theses 1911 - February 2014

Potential flow simulations are a great engineering type, middle-ground approach to modeling complex aerodynamic systems, but quickly become computationally unwieldy for large domains. An N-body problem with N-squared interactions to calculate, this free wake vortex model of a wind turbine is well suited to parallel computation. This thesis discusses general trends in wind turbine modeling, a potential flow model of the rotor of the NREL 5MW reference turbine, various forms of parallel computing, current GPU hardware, and the application of ground effects to the model. In the vicinity of 200,000 points, current GPU hardware was found to be nearly 17 …