Physical Sciences and Mathematics Commons^™

Specific Phosphate Sorption Mechanisms Of Unaltered And Altered Biochar, Kathryn D. Szerlag

Masters Theses

Biochar has been shown to act as an effective sorbent for many organic and inorganic contaminants (including phosphate) and can help to improve the quality of our fresh water resources by preventing eutrophication. Most of the high efficiency biochar phosphate-adsorbent feedstocks are modified with chemical pretreatment, phytoremediation or anaerobic digestion to accumulate desired elements. The main objectives of this project were to first engineer magnesium (Mg) and calcium (Ca) altered biochar by chemical pretreatment followed by pyrolysis at either 350 or 550°C and evaluate their phosphate adsorption rate and potential as compared to their unaltered counterparts. Determination of surface physiochemical …

Fault Interaction Within Restraining Bend Fault Systems, Aviel Rachel Stern

Masters Theses

Numerical simulations of a 15° restraining bend analog claybox experiment include considering the fault geometry, rheology, and boundary conditions. The numerical models show that a growing fault from an analog experiment propagates at depth rather than at the surface and is exposed in later stages of the experiment, and that the wet kaolin clay from the analog experiment is partially decoupled from the steel plate. The numerical models provide the stresses to predict accurate fault growth from the analog experiment and provide the evolution of external work within the fault system. The external work from the numerical models decrease as …

Ecological Consequences Of Lost Anadromous Forage Fish In Freshwater Ecosystems, Steven R. Mattocks

Masters Theses

Beginning in the early 1600s, dam construction in New England obstructed anadromous fish access to spawning grounds during migration. As a result, anadromous forage fish populations have declined, which has impacted freshwater, marine, and terrestrial ecosystems. To determine the impacts of dams on anadromous forage fish and freshwater ecosystems, I used historical and current data to estimate population changes in alewives (Alosa pseudoharengus) from 1600-1900. A significant reduction in spawning habitat occurred in New England as a result of 1,642 dams constructed between 1600 and 1900, resulting in 14.8% and 16.6% lake and stream habitat remaining by 1900, …

Development Of Filter-Based Surface Enhanced Raman Spectroscopic Assays For Rapid Detection Of Chemical And Biological Contaminants In Water, Siyue Gao

Masters Theses

Surface enhanced Raman spectroscopy (SERS) has been widely applied for rapid and sensitive detection of various chemical and biological targets. Here, we incorporated a syringe filter system into the SERS method to detect pesticides, protein toxins and bacteria in water. For the detection of chemical and protein targets, silver nanoparticles (Ag NPs) were aggregated by sodium chloride (NaCl) to form nanoclusters that could be trapped in the pores of the filter membrane to from the SERS-active membrane. Then a coating of capture (e.g. aptamer) was integrated on the nanoparticle substrate if needed. Then samples were filtered through the membrane. After …

A Comparison Of Techniques For Handling Missing Data In Longitudinal Studies, Alexander R. Bogdan

Masters Theses

Missing data are a common problem in virtually all epidemiological research, especially when conducting longitudinal studies. In these settings, clinicians may collect biological samples to analyze changes in biomarkers, which often do not conform to parametric distributions and may be censored due to limits of detection. Using complete data from the BioCycle Study (2005-2007), which followed 259 premenopausal women over two menstrual cycles, we compared four techniques for handling missing biomarker data with non-Normal distributions. We imposed increasing degrees of missing data on two non-Normally distributed biomarkers under conditions of missing completely at random, missing at random, and missing not …

Factors Affecting Habitat Quality For Wintering Wood Thrushes In A Coffee Growing Region In Honduras, Brett A. Bailey

Masters Theses

Amongst the diversity of taxa that occur in the Neotropics, 200 migratory bird species that breed in temperate North America can be found. Many of these populations have seen significant declines since the 1960s. The Wood Thrush, Hylocichla mustelina, is one such species. Shade coffee and other agroforestry practices show potential for benefiting migratory species, but the quality of coffee habitat and optimal habitat characteristics for Wood Thrushes remain unknown.

I surveyed a spatially complex, agricultural landscape in Honduras outside the recognized winter range of the Wood Thrush and radio-tagged 46 individuals within rustic coffee farms during the winters …

Restoration: Bridging The Gaps A Graphic Translation Of Ecological Restoration, Alyssandra Black

Masters Theses

The terms restoration ecology and ecological restoration are used interchangeably confusing the definition and work of ecological restoration and its many components. Restoration ecology is a type of scientific practice whose work will be a component of a restoration project while ecological restoration is the sum of practices, social, historical and ecological that constitute the field of restoration (Higgs, 2005). Within our rapidly urbanizing society the role of ecological restoration and restoring ecosystem services is increasingly important, especially within our coastal cities. The goals of restoration differ when the classification of restoration techniques is by ecosystem service, not ecological function, …

Sleep Patterns, Urinary Levels Of Melatonin And Subsequent Weight Change In The Women’S Health Initiative Observational Study, Nicole M. Barron

Masters Theses

Results from prospective studies examining associations between sleep duration and weight gain have been mixed. Melatonin has been hypothesized to mediate the association between sleep duration and weight/body composition. In cross-sectional studies, aMT6s has been shown to be inversely associated with weight/body fat percentage. We examined associations between baseline sleep duration, insomnia status, aMT6s levels with weight/body fat percentage through 6 years, utilizing a subset 690 women who participated in a breast cancer case-control study nested within the WHI-OS. Multi-variable and mixed-effects regression was used to calculate beta-coefficients and 95% confidence intervals. Cross-sectional analyses showed urinary aMT6s levels were inversely …

A Haptic Surface Robot Interface For Large-Format Touchscreen Displays, Mark Price

Masters Theses

This thesis presents the design for a novel haptic interface for large-format touchscreens. Techniques such as electrovibration, ultrasonic vibration, and external braked devices have been developed by other researchers to deliver haptic feedback to touchscreen users. However, these methods do not address the need for spatial constraints that only restrict user motion in the direction of the constraint. This technology gap contributes to the lack of haptic technology available for touchscreen-based upper-limb rehabilitation, despite the prevalent use of haptics in other forms of robotic rehabilitation. The goal of this thesis is to display kinesthetic haptic constraints to the touchscreen user …

Designing Active Granular Squares, Christopher C. Olson

Masters Theses

The goal of this thesis has been to find a means of i) designing an active square particle, and ii) continuously varying its degree of activity with the objective of understanding the effects of activity on the various phases of granular matter. The motivations, results and limitations of our methods of creating active particles are discussed in this thesis. The applicability of a stochastic model based on the Langevin equation in 2D as well as implications for future experiments are also discussed.

A Comparative Sustainability Study For Treatment Of Domestic Wastewater: Conventional Concrete And Steel Technology Vs. Vegetated Sand Beds (Vsb’S) And Their Relative Differences In Co2 Production, Alicia M. Milch

Masters Theses

Conventional wastewater treatment in the U.S. is an energy dependent and carbon dioxide emitting process. Typical mechanical systems consume copious amounts of energy, which is most commonly produced from fossil fuel combustion that results in the production of CO₂. The associated organic load is also metabolized by microorganisms into CO₂ and H₂O. As the desire to reduce CO₂ output becomes more prominent, it is logical to assess the costs of conventional treatment methods and to compare them to alternative, more sustainable technology. Vegetated Sand Bed (VSB) and Reed Bed (RB) systems are green technologies …

Micropaleontology And Isotope Stratigraphy Of The Upper Aptian To Lower Cenomanian (~114-98 Ma) In Odp Site 763, Exmouth Plateau, Nw Australia, Ali Alibrahim

Masters Theses

The biostratigraphy and isotope stratigraphy of the upper Aptian to lower Cenomanian interval including oceanic anoxic events OAE1b, 1c and 1d are investigated in ODP Site 763, drilled on the Exmouth Plateau offshore northwest Australia. Benthic foraminifera suggest that Site 763 was situated in outer neritic to upper bathyal water depths (~150-600 m). OAEs of the Atlantic basin and Tethys are typically associated with organic carbon-rich black shales and δ¹³C excursions. However, OAEs at this high latitude site correlate with ocean acidification and/or pyrite formation under anoxic conditions rather than black shales. Ocean acidification maybe responsible for sporadic …

Invasive Species Occurrence Frequency Is Not A Suitable Proxy For Abundance In The Northeast, Tyler J. Cross

Masters Theses

Spatial information about invasive species abundance is critical for estimating impact and understanding risk to ecosystems and economies. Unfortunately, at landscape and regional scales, most distribution datasets provide limited information about abundance. However, national and regional invasive plant occurrence datasets are increasingly available and spatially extensive. We aim to test whether the frequency of these point occurrences can be used as a proxy for abundance of invasive plants. We compiled both occurrence and abundance data for nine regionally important invasive plants in the northeast US using a combination of herbarium records, surveys of expert knowledge, and various invasive species spatial …

Oceanic Anoxia Event 2 (~94 Ma) In The U.S. Western Interior Sea: High Resolution Foraminiferal Record Of The Development Of Anoxia In A Shallow Epicontinental Sea, Amanda L. Parker

Masters Theses

The Upper Cretaceous Tropic Shale of southern Utah captures critical oceanographic changes that occurred during Oceanic Anoxic Event 2 (OAE 2) and the transgression of the Greenhorn Sea. We investigated the response of planktic and benthic foraminifera in a shallow (<100 >m) marine environment stressed by the onset of OAE 2 during the Cenomanian-Turonian boundary (CTB; 93.9 Ma) to determine the oceanographic mechanisms controlling the observed turnovers in the foraminiferal record. This study is based on high-resolution quantitative foraminifera counts and isotope paleoecology (d¹⁸O and d¹³C) from a 40-m outcrop. The OAE 2 interval is identified …

Sources Of Water And Solutes To The Salar De Atacama, Chile: A Coupled Hydrologic, Geochemical, And Groundwater Modeling Study, Lilly G. Corenthal

Masters Theses

Focused groundwater discharge in endorheic basins provides opportunities to investigate mechanisms for closing hydrologic budgets in arid regions. The Salar de Atacama (SdA), a closed basin in northern Chile, has accumulated over 1800 km³ of halite and a lithium-rich brine since the late Miocene primarily through evapotranspiration of groundwater. The hydrologic balance of SdA and sources of water and solutes required to explain this deposit are not well constrained. An adapted chloride mass balance method drawing on a database of over 200 water sample sites is applied to a remotely-sensed precipitation dataset to estimate spatially-distributed modern groundwater recharge. Comparing …