Physical Sciences and Mathematics Commons^™

Historical And Forecasted Kentucky Specific Slope Stability Analyses Using Remotely Retrieved Hydrologic And Geomorphologic Data, Daniel M. Francis

Theses and Dissertations--Civil Engineering

Hazard analyses of rainfall-induced landslides have typically been observed to experience a lack of inclusion of measurements of soil moisture within a given soil layer at a site of interest. Soil moisture is a hydromechanical variable capable of both strength gains and reductions within soil systems. However, in situ monitoring of soil moisture at every site of interest is an unfeasible goal. Therefore, spatiotemporal estimates of soil moisture that are representative of in-situ conditions are required for use in subsequent landslide hazard analyses.

This study brings together various techniques for the acquisition, modeling, and forecasting of spatiotemporal retrievals of soil …

Tryptophan-Like Fluorescence And Non-Point Source Pollution In Karst Basins, Inner Bluegrass Region, Kentucky, Ryan Dapkus

Theses and Dissertations--Earth and Environmental Sciences

Typically, the degree of fecal contamination of water is assessed by the concentration of thermotolerant coliforms, like E. coli. This method is time-consuming, taking > 18 hours between the start of incubation and subsequent enumeration. The current study examines the utility of monitoring tryptophan-like fluorescence (TLF) using in-situ fluorometers as a proxy for fecal contamination, particularly E. coli. Relative timing of discharge peaks and TLF peaks is considered, as well as differences in E. coli concentrations and major anion concentrations between two different basins that were monitored weekly. Results indicate that TLF is somewhat useful in the prediction of …

Assessing Machine Learning Utility In Predicting Hydrologic And Nitrate Dynamics In Karst Agroecosystems, Timothy Mcgill

Theses and Dissertations--Biosystems and Agricultural Engineering

Seasonal hypoxia in the Gulf of Mexico and harmful algal blooms experienced in many inland freshwater bodies is partially driven due to excessive nitrogen loading seen from agricultural watersheds. Within the Mississippi/Atchafalaya River Basin, many areas are underlain with karst features, and efforts to reduce nitrogen contributions from these areas have had varying success, due to lacking a complete understanding of nutrient dynamics in karst agricultural systems. To improve the understanding of nitrogen cycling in these systems, 35 months of high resolution in situ water quality and atmospheric data were collected and fed into a two-hidden layer extreme learning machine …

Tracing Source Contributions To Assess Spatial Patterns Of Erosion In A Mixed Land Use Environment: Otter Creek Catchment, Fort Knox, Kentucky, Cara Peterman

Theses and Dissertations--Earth and Environmental Sciences

There is an inherent difficulty in predicting source contributions of fine-grained fluvial sediment in mixed land-use watersheds. Over a 56-week period, the spatial and temporal variability in sediment-source contributions and water quality was monitored at three sites along Otter Creek in Hardin and Meade counties, Kentucky (USA). The 203-km² study area drains rural and agricultural lands and includes Fort Knox Army Post’s tracked-vehicle training areas. The main objectives for sediment source apportionment were to 1) identify and differentiate characteristics of civilian and military source soils to Otter Creek and 2) to apportion sediment at locations along Otter Creek to …

Isotopic And Geochemical Tracers Of Groundwater Flow In The Shivwits Plateau, Grand Canyon National Park, Jonathan W. Wilson

Theses and Dissertations--Earth and Environmental Sciences

As the impacts of global climate change on water resources continue to become more apparent, proper understanding and management of groundwater resources will be needed as supplies become more strained. Traditional methods of characterizing groundwater systems are time-intensive, costly, and can be difficult to complete in remote areas. Using ambient geochemical tracers from discrete sampling could aid in characterizing spring systems through determining flow paths, recharge areas, and carbon cycling. However, using discrete seasonal samples to understand the hydrogeology of complex, mixed-lithology aquifers has not been extensively examined. Here we explore using δ¹³C of dissolved organic carbon (DOC), …

Assessing The Climate Water Balance Model’S Ability To Predict Soil Moisture Variability And Species Distribution Of A Forested Watershed In The Northern Cumberland Plateau, Katherine J. Love

Theses and Dissertations--Forestry and Natural Resources

Spatial patterns of moisture and tree species have been studied using environmental gradients, often represented by terrain attributes in GIS. With climate change, GIS terrain variables, which are static as long as the elevation remains unchanged, will not reflect alterations in temperature, water cycle, and atmospheric conditions. In this thesis, the commonly used terrain variables and climate water balance variables were evaluated and compared for their ability to explain soil moisture and tree species distributions in a forested watershed in the Northern Cumberland Plateau. The results suggest that GIS terrain variables generally perform better than climate water balance variables, however, …

Temporal And Spatial Variability In Groundwater Flow And Chemistry Along The Cumberland River, Artemus, Kentucky, Amanda Rachelle Sherman

Theses and Dissertations--Earth and Environmental Sciences

Groundwater in the Kentucky Appalachian region is constrained by physiography and lithology. Lithostratigraphy, groundwater flow, and chemistry were delineated in the alluvial aquifer along the Cumberland River at H.L. Disney Training Center. To assess groundwater-river interactions and water quality, 11 monitoring wells were installed and sampled quarterly, plus the river and an existing bedrock well. Analytical results were evaluated for temporal and spatial trends. Collected soil cores were analyzed for bulk chemistry and grain size. Solute speciation and saturation indices were calculated and hydraulic conductivity estimated from grain-size analyses. Pumping and slug tests were performed to estimate hydraulic conductivity and …

Variability In Groundwater Flow And Chemistry In The Houzhai Karst Basin, Guizhou Province, China, Joshua M. Barna

Theses and Dissertations--Earth and Environmental Sciences

Understanding how karst aquifers store and transmit water and contaminants is an ongoing problem in hydrogeology. Flowpath and recharge heterogeneity contribute to the complexity of these systems. This thesis explores karst-conduit connectivity and water chemistry variability in the Houzhai catchment in Guizhou province, China. Artificial tracer tests were conducted during both the monsoon and dry seasons to understand temporal variability in connectivity and water velocity between karst features. Multiple flowpaths through the catchment are activated during the monsoon season and partially abandoned during the dry season. Additionally, gradient reversals during monsoonal high-flow events and as a result of pumping can …

Rethinking Karst Hazard Assessment In Kentucky, William P. Pierskalla Jr.

Theses and Dissertations--Earth and Environmental Sciences

Current karst hazard maps in Kentucky reflect the general lithology of the state and ignore or significantly reduce the impact of the actual sinkholes present within these areas. These maps rely on equal weighting, by area, of the Karst Potential Index (KPI) map and the sinkhole inventory map. The KPI is based on a 1:500,000 geologic map and less than 500 data points of carbonate rocks. The sinkhole inventory is derived from topographic maps updated in the 1970s with approximately 10-foot resolution. This method gives a preferential weighting of the KPI over the sinkhole data. Consequently, the current method is …

Decomposing A Watershed’S Nitrate Signal Using Spatial Sampling And Continuous Sensor Data, Evan Clare

Theses and Dissertations--Civil Engineering

Watershed features, physiographic setting, geology, climate, and hydrologic processes combine to produce a time-variant nutrient concentration signal at the watershed outlet. Anthropogenic influences, such as increased agricultural pressures and urbanization, have increased overall nutrient loadings delivered to the fluvial network. The impact of such increased nutrient loadings on Kentucky’s drinking water remains a potential threat to the region.

By coupling spatial sampling of nitrate concentrations in surface water with contemporary nutrient and water quality sensor technology, a decomposition of the Upper South Elkhorn watershed’s nitrate signal and an estimation of source timing and loading in the watershed was completed. The …

Accounting For Spatial Autocorrelation In Modeling The Distribution Of Water Quality Variables, Lorrayne Miralha

Theses and Dissertations--Geography

Several studies in hydrology have reported differences in outcomes between models in which spatial autocorrelation (SAC) is accounted for and those in which SAC is not. However, the capacity to predict the magnitude of such differences is still ambiguous. In this thesis, I hypothesized that SAC, inherently possessed by a response variable, influences spatial modeling outcomes. I selected ten watersheds in the USA and analyzed them to determine whether water quality variables with higher Moran’s I values undergo greater increases in the coefficient of determination (R²) and greater decreases in residual SAC (rSAC) after spatial modeling. I compared non-spatial ordinary …

Performance Of The Grout Curtain At The Kentucky River Lock And Dam No. 8, Robert C. Hatton

Theses and Dissertations--Civil Engineering

Karst bedrock conditions and deterioration of the lock and dam structures have resulted in significant leakage through, underneath, and around Lock and Dam No. 8 on the Kentucky River. During severe droughts, the water surface in Pool No. 8 has been observed to drop below the crest of the dam, resulting in water supply shortages and water quality issues for surrounding communities reliant on the pool. Presently, the primary purpose of Lock and Dam No. 8 is water supply. Pool No. 8 is currently where the cities of Nicholasville (Jessamine County, KY) and Lancaster (Garrard County, KY) draw their water. …

Hydrologic Monitoring And 2-D Electrical Resistivity Imaging For Joint Geophysical And Geotechnical Characterization Of Shallow Colluvial Landslides, Matthew M. Crawford

Theses and Dissertations--Earth and Environmental Sciences

Landslide characterization and hazard assessments require multidisciplinary approaches that connect geologic processes with geotechnical parameters. Field monitoring of hydrologic variables such as water content and water potential, coupled with geoelectrical measurements that can establish relationships used for geotechnical and landslide hazard investigations is deficient.

This study brings together different techniques to develop a methodology that connects geoelectrical measurements and shear strength. A field-based framework was established that includes (1) analysis of long-term soil moisture fluctuations within different landslides (2) establishment of constitutive and new equations that test the use of electrical conductivity to predict soil-water relationships and shear strength (3) …

Fluvial-Lacustrine Processes Shaping The Landforms Of The Distal Paraguay Fluvial Megafan, Edward Limin Lo

Theses and Dissertations--Earth and Environmental Sciences

Tropical wetlands such as the Pantanal help regulate global biogeochemical cycles, but climate change is modifying these environments. Controls on environmental changes can potentially be assessed from ancient, well-dated lacustrine sedimentary records. An integrated field and laboratory approach was undertaken to study the limnogeology of Lake Uberaba in the northern Pantanal, and test whether the lake has preserved a reliable record of environmental change in its strata. This study was designed to understand how the basin accumulates sediment and to assess its sensitivity to hydroclimatic variability. The data showed that modern Lake Uberaba is a highly dynamic, freshwater fluvial-lacustrine basin. …

Mobility Of Escherichia Coli Within Karst Terrains, Kentucky, Usa, Ashley M. Bandy

Theses and Dissertations--Earth and Environmental Sciences

Bacterial contamination of karst aquifers is a concern as water quality across the globe deteriorates in the face of decreasing water security. This study examined the transport and attenuation of two non-virulent isolates of Escherichia coli in relation to traditional groundwater tracers such as rhodamine WT dye and latex microspheres in two karst regions in Kentucky. Differential movement between the four tracers was observed in both epikarst and karst aquifer traces, with differences in behavior dependent on flow conditions. Attenuation was greater for the bacterial isolate containing the iha gene, compared to the isolate containing the kps gene. Microspheres of …

Deuterium And Oxygen-18 Diffusion In A Confined Aquifer: A Numerical Model Of Stable Isotope Diffusion Across Aquitard-Aquifer Boundaries, Benjamin J. Currens

Theses and Dissertations--Earth and Environmental Sciences

The stable isotopes ²H and ¹⁸O, combined with noble gases and radioisotopes (e.g., ³H, ¹⁴C, ³⁶Cl), are used to infer groundwater age and climate during recharge. Flow regimes within low-velocity flowpaths and long residence times could allow an aquitard-aquifer diffusive flux to alter isotope abundance. Consequently, the diffusion of isotopes (e.g., ¹⁴C, ²H and ¹⁸O) between aquifers and confining layers needs to be considered in such conditions. In this study, COMSOL Multiphysics was used to determine if diffusion of ¹⁸O (and ²H by proxy) from a bounding aquitard could explain …

Spring Responses To Storms And Seasonal Variations In Recharge In The Middle Atlas Region Of Morocco, Brett Andrew Howell

Theses and Dissertations--Earth and Environmental Sciences

Springs in the Middle Atlas Mountains of Morocco are significant sources for public water supply. From March 2014 to May 2015, water temperatures were measured hourly at three springs (Ribaa, Sidi Rached, and Zerouka); water levels were measured hourly at Sidi Rached and Zerouka; and daily turbidity data were obtained from Ribaa. From March 2014 to March 2015, daily water samples were taken at Zerouka for analyses of the stable isotopes deuterium and oxygen-18. Hourly weather data (precipitation and air temperature) were available from March 2014 to May 2015 from Ifrane, near Zerouka. Temperature responses varied between the springs, showing …

Dynamic Surface Water-Groundwater Exchange In Tidal Freshwater Zones: Insights From The Christina River Basin (Delaware, Usa), Cole T. Musial

Theses and Dissertations--Earth and Environmental Sciences

In coastal rivers, tides can propagate for tens to hundreds of kilometers inland beyond the saltwater line. Yet the influence of tides on river-aquifer connectivity and solute transport in tidal freshwater zones (TFZs) is largely unknown. We estimate that along the TFZ of White Clay Creek (Delaware, USA), more than 17% of river water exchanges through hyporheic and riparian storage zones due to tidal pumping alone. Additional hyporheic processes such as flow through bedforms likely contribute even more exchange. The turnover length associated with the tidal pumping process is 39 km, similar to turnover lengths for all hyporheic exchange processes …

Spatio-Temporal Variability In Groundwater Discharge And Contaminant Fluxes Along A Channelized Stream In Western Kentucky, Ganesh N. Tripathi

Theses and Dissertations--Earth and Environmental Sciences

Spatio-temporal variability in groundwater discharge and contaminant fluxes along a channelized stream in western Kentucky

Surface and groundwater discharges and contaminant fluxes can vary with time and space depending upon the hydrogeological processes and geological setting of the area of interest. This study examined a ~300-m-long, channelized reach of a first-order perennial stream, Little Bayou Creek, in the Coastal Plain of far western Kentucky during the period October 2010–February 2012. Along the study reach, springs discharge groundwater contaminated by the chlorinated organic compound trichloroethene (TCE) and radionuclide technetium-99 (⁹⁹Tc) released as a result of past activities at the …

Using Gis To Delineate Headwater Stream Origins In The Appalachian Coal-Belt Region Of Kentucky, Jonathan A. Villines

Theses and Dissertations--Biosystems and Agricultural Engineering

Human activity such as surface mining can have substantial impacts on the natural environment. Performing a Cumulative Hydrologic Impact Assessment (CHIA) of such impacts on surface water systems requires knowing the location and extent of these impacted streams. The Jurisdictional Determination (JD) of a stream’s protected status under the Clean Water Act (CWA) involves locating and classifying streams according to their flow regime: ephemeral, intermittent, or perennial. Due to their often remote locations and small size, taking a field inventory of headwater streams for surface mining permit applications or permit reviews is challenging. A means of estimating headwater stream location …

Fate Of Stable Isotope Label During Predation Of 15N-Tagged Wild-Type Escherichia Coli By Protozoa, Ashley M. Barton

University of Kentucky Master's Theses

Currently, bacterial movement in karst aquifers is not well understood. Use of stable isotopes to label non-pathogenic Escherichia coli as a particulate groundwater tracer in karst systems has been examined in previous studies. Loss of the stable isotope signal is anticipated in traces greater than 500 m in length. Potential loss of ¹⁵N due to predation by protozoa was examined. Filter-sterilized water from Royal Spring in Georgetown, Kentucky, was inoculated with a mixture of either Tetrahymena pyriformis or Colpoda steinii and ¹⁵N-enriched E. coli and stored in the dark at 14°C. Samples were analyzed for their nitrogen isotope …

Chemical Evolution And Residence Time Of Groundwater In The Wilcox Aquifer Of The Northern Gulf Coastal Plain, Estifanos Haile

Theses and Dissertations--Earth and Environmental Sciences

This study aims to integrate groundwater geochemistry and mathematical modeling to determine the dominant geochemical processes and groundwater residence time within the Wilcox aquifer in the northern Gulf Coastal Plain. Groundwater samples were collected and analyzed for major ion chemistry, stable isotopes (¹⁸O, ²H, and ¹³C), and radioisotope ³⁶Cl content. Geochemical modeling enabled the identification of major sources and sinks of solutes in the aquifer. A two-dimensional, finite-difference, numerical model was used to determine the deep groundwater flow rate and transport of ³⁶Cl in the aquifer. Major ion chemistry shows a chromatographic pattern along …

Locating Hot Spots Of Fecal Pollution In An Urban Watershed Of Central Kentucky Using Bacteroides 16s Rrna Markers, Tricia L. Coakley

Theses and Dissertations--Earth and Environmental Sciences

The field of molecular fecal source tracking in the water environment has developed rapidly since the first PCR assays for general and host-­‐specific Bacteroides 16s rRNA markers were published. Numerous host-­‐specific molecular markers and PCR assays have been developed, adding greater specificity, sensitivity and quantitative methods to the array of options. The public demand for readying methods for transfer to the commercial lab, so that they may be used to generate data for public utilities, citizen action groups and regulatory agencies, has fueled the development of an entire new research community. These methods, however plentiful, have not found community agreement …