Physical Sciences and Mathematics Commons^™

Surface Entropy Of Shifts Of Finite Type, Dennis Pace

Electronic Theses and Dissertations

Let χ be the class of 1-D and 2-D subshifts. This thesis defines a new function, H_S : χ x R → [0,∞] which we call the surface entropy of a shift. This definition is inspired by the topological entropy of a subshift and we compare and contrast several structural properties of surface entropy to entropy. We demonstrate that much like entropy, the finiteness of surface entropy is a conjugacy invariant and is a tool in the classification of subshifts. We develop a tiling algorithm related to continued fractions which allows us to prove a continuity result about surface …

T-De Vries Algebra, Nawal Alznad

Electronic Theses and Dissertations

The main point of this dissertation is to introduce the action on de Vries algebra by a topological monoid and we denoted the resulting category by dVT. In order to reach our goal, we started with introducing new proofs for some well known results in the category of flows. Then, we studied the Generalized Smirnov's Theorem for flows. After we studied the new category (dVT), we were able to provide a new way to construct the Čech-stone flow compactification of a given flow. Finally, we developed the co-free T-de Vries algebra for a special case.

Fuel Specific Emissions Trends For In-Use Medium And Heavy-Duty Vehicle Fleets In California, Molly J. Haugen

Electronic Theses and Dissertations

New heavy-duty vehicle regulations have caused significant reductions in hazardous air pollutants, such as particulate matter (PM) and nitrogen oxides (NO_x), due to better engine management and utilization of advanced after-treatment systems. The University of Denver has collected data for gaseous and PM emission measurements from on-road heavy-duty vehicles (HDVs). The On-Road Heavy-Duty Vehicle Emissions Measurement System (OHMS) collected fuel specific emission information on individual HDVs of in-use fleets at two California locations in the spring of 2013, 2015 and 2017. These complimentary fleets, studied over multiple years, produced 7,075 measurements of gaseous and particle emission data providing …

Polarized Bow Shock Nebulae Reveal Features Of The Winds And Environments Of Massive Stars, Manisha Shrestha

Electronic Theses and Dissertations

Massive stars strongly affect their surroundings through their energetic stellar winds during their lifetime and through their energetic deaths as supernovae. When a stellar wind interacts with the local interstellar medium (ISM), if the relative velocity between wind and ISM is supersonic, then a stellar wind bow shock is formed. Bow shocks and related density enhancements produced by the winds of massive stars moving through the interstellar medium provide important information regarding the motions of the stars, the properties of their stellar winds, and the characteristics of the local medium. Since bow shock nebulae are aspherical structures, light scattering within …

Improving The Accuracy Of Mobile Touchscreen Qwerty Keyboards, Amanda Kirk

Electronic Theses and Dissertations

In this thesis we explore alternative keyboard layouts in hopes of finding one that increases the accuracy of text input on mobile touchscreen devices. In particular, we investigate if a single swap of 2 keys can significantly improve accuracy on mobile touchscreen QWERTY keyboards. We do so by carefully considering the placement of keys, exploiting a specific vulnerability that occurs within a keyboard layout, namely, that the placement of particular keys next to others may be increasing errors when typing. We simulate the act of typing on a mobile touchscreen QWERTY keyboard, beginning with modeling the typographical errors that can …

Developing A Femtosecond Stimulated Raman Spectroscopy Experiment For Solid State Materials, Daniel Hammerland

Electronic Theses and Dissertations

Femtosecond Stimulated Raman Spectroscopy (FSRS) is a ultrafast spectroscopy technique first implemented by chemists to understand isomerization and other ultrafast molecular morphology changes by resolving vibrational dynamics[1, 2, 3]. FSRS has an unparalleled temporal and spectral resolution [4, 1, 5, 6] that arises as a result of a clever combination of picosecond and femtosecond pulses. However, despite this capability, FSRS has yet to be applied to modern materials in condensed matter physics. This thesis explores the design and implementation of FSRS to study two-dimensional materials in order to measure their quantum confined vibrational dynamics on utlrafast time scales.

A Bi-Encoder Lstm Model For Learning Unstructured Dialogs, Diwanshu Shekhar

Electronic Theses and Dissertations

Creating a data-driven model that is trained on a large dataset of unstructured dialogs is a crucial step in developing a Retrieval-based Chatbot systems. This thesis presents a Long Short Term Memory (LSTM) based Recurrent Neural Network architecture that learns unstructured multi-turn dialogs and provides implementation results on the task of selecting the best response from a collection of given responses. Ubuntu Dialog Corpus Version 2 (UDCv2) was used as the corpus for training. Ryan et al. (2015) explored learning models such as TF-IDF (Term Frequency-Inverse Document Frequency), Recurrent Neural Network (RNN) and a Dual Encoder (DE) based on Long …

Heat, Charge And Spin Transport Of Thin Film Nanostructures, Devin John Wesenberg

Electronic Theses and Dissertations

Understanding of fundamental physics of transport properties in thin film nanostructures is crucial for application in spintronic, spin caloritronics and thermoelectric applications. Much of the difficulty in the understanding stems from the measurement itself. In this dissertation I present our thermal isolation platform that is primarily used for detection of thermally induced effects in a wide variety of materials. We can accurately and precisely produce in-plane thermal gradients in these membranes, allowing for thin film measurements on 2-D structures. First, we look at thermoelectric enhancements of doped semiconducting single-walled carbon nanotube thin films. We use the Wiedemann-Franz law to calculate …

Selective Carbon-Carbon Bond Formation Promoted By Divalent Samarium Reagents, Christopher David-James Aretz

Electronic Theses and Dissertations

Three efficient methods for synthesis of five membered carbocycles, a highly understudied product motif in samarium(II) chemistry, were explored and optimized. These methods utilized simple starting materials to generate linear substrates with functional groups that are reactive towards samarium(II) iodide. The three methods explored were the Reformatsky-aldol, Reformatsky-alkylation, and pinacol cyclizations. The critical discovery for efficient formation of the Reformatsky-aldol and pinacol carbocycles products was the use of lithium bromide. This addition of lithium bromide facilitates easy in situ formation of samarium(II) bromide. The Reformatsky-alkylation cyclization was a newly realized reaction employing samarium enolates. Two of the three methods, the …

Developing An Affect-Aware Rear-Projected Robotic Agent, Ali Mollahosseini

Electronic Theses and Dissertations

Social (or Sociable) robots are designed to interact with people in a natural and interpersonal manner. They are becoming an integrated part of our daily lives and have achieved positive outcomes in several applications such as education, health care, quality of life, entertainment, etc. Despite significant progress towards the development of realistic social robotic agents, a number of problems remain to be solved. First, current social robots either lack enough ability to have deep social interaction with human, or they are very expensive to build and maintain. Second, current social robots have yet to reach the full emotional and social …

Improving The Detection Limit Of Tau Aggregates For Use With Biological Samples, Emily Rickman Hager

Electronic Theses and Dissertations

The protein Tau is found in neurofibrillary tangles in Alzheimer's disease and over 20 other neurodegenerative diseases. An assay has been developed to detect minute amounts of fibrils from human brain tissue. This assay subjects brain tissue extract and recombinant Tau to several rounds of sonication and incubation. Incubation allows recombinant Tau to add itself to the ends of the existing fibrils in brain tissue extract. Sonication breaks the existing fibrils in the brain tissue extract offering more ends for Tau to add onto. Cycles of sonication and incubation have been shown to allow for amplification of Tau fibrils from …

Photochemistry Of Polycyclic Aromatic Hydrocarbons With Environmentally Relevant Metals, John P. Haynes

Electronic Theses and Dissertations

The details of the work presented in this dissertation focus on simulated reactions in the atmosphere and water systems between persistent aromatic compounds and varying species of metals with an emphasis on iron. Bulk water suspensions of a standard soil and polycyclic aromatic hydrocarbons (PAH) were analyzed for soluble iron by inductively-coupled plasma mass spectroscopy (ICP-MS) following a 16 hour reaction period using simulated sunlight. Significant increases in soluble iron were only seen with 2-3 ring linear PAH and carboxylic acids.

A two-stage study was conducted to investigate the potential for and possible mechanisms involving the photo-oxidation of PAH into …

Paleoflood Hydrology And Basin Morphometric Characteristics Related To Flooding In The Colorado Front Range, Natalie Trivino

Electronic Theses and Dissertations

Flooding hazards are common in the Colorado Front Range due to the steep, complex terrain of the mountains where waters quickly spill out onto the most populated region of Colorado. This region has experienced numerous catastrophic floods, such as the 2013 Front Range Floods, the Fort Collins Flood of 1997, and the Big Thompson Canyon Flood of 1976 to name a few. The objective of this study was to analyze basin morphometric characteristics of several drainage basins throughout the Colorado Front Range South Platte River tributaries and determine how these characteristics relate to extreme flooding. This was done through three …

The Investigation Of Lactoferrin Nitration: Quantification, Function, And Inhibition, Amani Yahya Alhalwani

Electronic Theses and Dissertations

Lactoferrin (LF) is an iron-binding glycoprotein of molecular mass ca. 80 kDa that is predominantly found in mammalian body fluids. Lactoferrin is a multifunctional protein that has a wide range of properties such as antibacterial, antiviral, anti-inflammatory, and anti-allergic functions. Tyrosine residues in the protein play a part in many lactoferrin functions. Protein tyrosine nitration modification represents an oxidative and nitrosative stress process which can be caused by the exposure of proteins to oxidants from air pollution or disease. Understanding the way nitrated lactoferrin interacts with the biochemical environment of the body is thus important to the broader goal of …

Learning From Disorder And Noise In Physical Biology, Taylor Emil Firman

Electronic Theses and Dissertations

Stochasticity, disorder, and noise play crucial roles in the functioning of many biological systems over many different length scales. On the molecular scale, most proteins are envisioned as pristinely folded structures, but intrinsically disordered proteins (IDPs) have no such folded state and still serve distinct purposes within the cell. At the scale of gene regulation, realistic in vivo conditions produce stochastic fluctuations in gene expression that can lead to advantageous bet-hedging strategies, but can be difficult to characterize using a deterministic framework. Even at the organismal scale, germband extension (GBE) in Drosophila melanogaster embryos systematically elongates the epithelial tissue using …

The Ecology Of Land Managers In Riparian Restoration, Lisa Buie Clark

Electronic Theses and Dissertations

While previous studies in restoration ecology have focused on the efficacy of direct management actions, the driving forces on management decisions (e.g., managers' characteristics or attitudes, environmental conditions) and the indirect impacts on restoration outcomes from management decisions (such as whether to collaborate) are quantified here for the first time. As a case study, I used data from 244 sites across the riparian Southwest US where the invasive shrubby tree Tamarix sp. was removed using various different methods. I surveyed and interviewed the 45 land managers who were responsible for the removal projects to determine their characteristics, attitudes, and …

Automated Cfd Optimization To Maximize Wind Farms Performance And Land Use, Rafael Valotta Rodrigues

Electronic Theses and Dissertations

In this research, a computational system was designed to analyze and optimize the layout of wind farms under variable operational conditions. At first, a wind turbine computational fluid dynamic (CFD) model was developed covering the near wake. The near wake flow field was validated against near wake velocity data from the MEXICO experiment. The CFD simulation demonstrated that the tip speed ratio and the pitch angle greatly influence the near wake behavior, affecting the velocity deficit and the turbulence intensity profile in this region. The CFD model was extended to cover the far wake, aiming to become a computational tool …

Categories Of Residuated Lattices, Daniel Wesley Fussner

Electronic Theses and Dissertations

We present dual variants of two algebraic constructions of certain classes of residuated lattices: The Galatos-Raftery construction of Sugihara monoids and their bounded expansions, and the Aguzzoli-Flaminio-Ugolini quadruples construction of srDL-algebras. Our dual presentation of these constructions is facilitated by both new algebraic results, and new duality-theoretic tools. On the algebraic front, we provide a complete description of implications among nontrivial distribution properties in the context of lattice-ordered structures equipped with a residuated binary operation. We also offer some new results about forbidden configurations in lattices endowed with an order-reversing involution. On the duality-theoretic front, we present new results on …

Motivations, Team Dynamics, Development Practices And How They Impact The Success Of Open Source Software: A Study Of Projects Of Code For America Brigades, Le Chang

Electronic Theses and Dissertations

Open data movement has nurtured the growth of civic open source software (OSS) in the recent decade. This emerging phenomenon has demonstrated a way that a community can collectively utilize technology to solve its problems.

This study is based on software projects in brigades of Code for America, which is a network of organizations that group volunteers to create digital solutions to community problems. In this study, we analyze the software engineering practices of current civic open source software development, participants' motivations and perceptions of the projects, and provide insights on the antecedents of success of the application development.

A …

Brønsted Acid Catalyzed Carbon-Carbon Bond Forming Reactions, Jiangyue Miao

Electronic Theses and Dissertations

The focus of this research project lies in the development of new methodology in the field of Brønsted acid catalysis enabling rapid synthesis of medicinally relevant compounds. It is foreseen that small molecule sulfonic acids evaluated in this research project will unveil new asymmetric carbon carbon bond forming reactions between substrates hitherto unexplored with Brønsted acid catalysis. It has been established that strong Brønsted acids, such as phosphoric acids, are capable of mediating highly selective transformations operating through unique mechanistic manifolds.

Specific focus for the sulfonic acid catalysts was geared towards asymmetric coupling reactions with synthetically useful precursors such as …

Algorithmic Music Generation For Pedagogy Of Sight Reading, Ryan Stephen Davis

Electronic Theses and Dissertations

Autodeus is the name of the program that has been developed and was designed to aid guitar students in the attainment and betterment of musical notation sight reading skills. Its primary goal is to provide a very flexible tool that has the ability to generate virtually endless types of sight reading exercises at many various skill levels.

A complimentary 2 year-long comprehensive guitar sight-reading course syllabus can be implemented via Autodeus as it is capable of generating all the necessary exercises. It is able to generate these exercises quickly and efficiently through the use of a back tracking algorithm that …

Development Of A Locomotion And Balancing Strategy For Humanoid Robots, Emile Bahdi

Electronic Theses and Dissertations

The locomotion ability and high mobility are the most distinguished features of humanoid robots. Due to the non-linear dynamics of walking, developing and controlling the locomotion of humanoid robots is a challenging task. In this thesis, we study and develop a walking engine for the humanoid robot, NAO, which is the official robotic platform used in the RoboCup Spl. Aldebaran Robotics, the manufacturing company of NAO provides a walking module that has disadvantages, such as being a black box that does not provide control of the gait as well as the robot walk with a bent knee. The latter disadvantage, …

Weathering Climate Change: Provisions For Climate Change Resiliency In Transboundary River Treaties, Emily Joan Zmak

Electronic Theses and Dissertations

Climate change will be most apparent in alterations to the hydrologic system - shifts in movement, variations in extremes - thereby defining many resource disputes in the coming decades. Water is a boundaryless resource; as its hydrologic patterns shift within and without borders, so too will preexisting agreements on its use and allocation. The question for transboundary water agreements is: how can agreements both satisfy parties' needs and account for future uncertainties of climate-induced changes to their basins' hydrologic systems?

From examining literature and water agreements, this thesis develops a list of provisions identified as foundational to resiliency in transboundary …

Rnn-Based Generation Of Polyphonic Music And Jazz Improvisation, Andrew Hannum

Electronic Theses and Dissertations

This paper presents techniques developed for algorithmic composition of both polyphonic music, and of simulated jazz improvisation, using multiple novel data sources and the character-based recurrent neural network architecture char-rnn. In addition, techniques and tooling are presented aimed at using the results of the algorithmic composition to create exercises for musical pedagogy.