Physical Sciences and Mathematics Commons^™

New Applications Of Mass Spectrometry For Drug And Lipid Analysis, Elizabeth Lauren Emerson

Graduate Theses and Dissertations

Mass spectrometry is an important tool used in many different disciplines and settings that include forensics, drug discovery, environmental analysis, and proteomics. Gas chromatography - mass spectrometry (GC-MS) and matrix assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI - TOF MS) are two of the most important instruments used for analysis of compounds. Chapters 1 and 2 of this discussion use GC-MS for the investigation of synthetic cannabinoids in `K2' incense products and the detection of metabolites in urine samples from individuals suspected of consuming these mixtures. Analytical standards were synthesized and used for identification and confirmation of structures. Detection of …

Refractive Index Chemical Sensing With Noble Metal Nanoparticles, Phillip Blake

Graduate Theses and Dissertations

Chemical sensing is a key component in modern society, especially in engineering applications. Because of their widespread impact, improvements to chemical sensors are a significant area of research. One class of sensors, plasmonic sensors, is being heavily researched because of their ability to detect low levels of analyte in near real time without destroying the analyte. This work studies a new class of plasmonic sensor that utilizes diffractive coupling to improve sensor performance. Specifically, this work outlines the first study of diffractive coupling sensors with typical nanoparticle shapes. Sensitivity of this new class of sensor is directly compared to typical …

Long-Term Effects Of Rice Rotation, Tillage, And Fertility On Near-Surface Soil Carbon And Nitrogen Cycling, Jill Marie Motschenbacher

Graduate Theses and Dissertations

Rice (Oryza sativa L.)-based cropping systems are different from other row crops due to the flood-irrigation scheme used from about one month after planting to a few weeks prior to harvest. The frequent cycling between anaerobic (i.e., flooding during the growing season) and aerobic (i.e., generally, the remainder of the year) conditions can influence the rate of soil organic matter (SOM) decomposition, which can greatly influence carbon (C) and nitrogen (N) storage and sequestration in the soil over time. Therefore, a study was conducted on a silt-loam soil (fine, smectitic, thermic, Typic Albaqualf) at the Rice Research and Extension Center …

Evaluation Of The Effects Of Absorption Field Product Architecture Type On Effluent Dispersal And Soil Chemical Properties In A Profile-Limited Soil, Nina J.M. Prater

Graduate Theses and Dissertations

On-site wastewater treatment systems (OWTSs) are commonly used by households in areas of low population density to treat household wastewater and recycle it back to the environment. The traditional absorption field product used in OWTSs is a pipe-and-gravel architecture type, which has been used for decades and is the basis for most design regulations. However, new products of differing architecture types including chambers, polystyrene-aggregate, pipe-and-tire-chip, and gravel-less-pipe systems have recently become available. A three-year field study was conducted in Bethel Heights, AR to assess the performance of several newer products and to compare different architecture types to the traditional pipe-and-gravel …

Prehistoric Human Ecodynamics In The Rub Al-Khali Desert: Results Of Remote Sensing And Excavations In Dubai, United Arab Emirates, Jason T. Herrmann

Graduate Theses and Dissertations

Archaeological investigations in the Emirate of Dubai, UAE conducted by the Dubai Department of Archaeology and the University of Arkansas demonstrate that the desert inland of the Oman Peninsula was occupied not only during the Arabian Neolithic (8000-4400 BC), when the region experienced a moist period referred to as the Holocene Climatic Optimum (HCO), but also during the more arid millennia following the decline of the HCO into the Christian Era. During this period, desert settlement clustered near a band of oases, in contrast to the more widespread spatial distribution of remains of nomadic pastoralists from the Neolithic. Excavations at …

Stratigraphic Variations In The Carboniferous Section Across The Arkansas-Oklahoma State Line Arch, Tyler Dean Engelhardt

Graduate Theses and Dissertations

The State Line Arch is represented by a structural high that trends through the study area in a loose alignment with the Arkansas-Oklahoma state line. Evidence of the arch extending further to the north includes a structural high and stratigraphic variation at an outcrop on Highway 59 near Evansville Mountain in Crawford County, Arkansas. The exact timing of the formation of the arch remains undetermined, but upper Devonian thinning at the top of the arch indicates the structure is pre-Mississippian. The reason for the development of the arch is poorly understood, but evidence linking Mississippian-aged Waulsortian mounds to Precambrian Spavinaw …

Assessing The Impacts Of Surface Water Removal For Use In Natural Gas Extraction On A Watershed Level, Carrie Ann Davis

Graduate Theses and Dissertations

In this study, the Soil and Water Assessment Test (SWAT) was used as a tool to predict whether diffuse water removal from the Cadron Creek watershed for use with natural gas development would have an impact on downstream flow within the watershed. Cadron Creek watershed expands across four counties within Arkansas and is located in the Fayetteville Shale Gas region. This region is experiencing significant growth in natural gas development. Successful development of shale gas depends on the identification of what water supplies are available for production without interfering with community and environmental needs. The SWAT model used to evaluate …

An Economic Alternative To The C Chart, Ryan William Black

Graduate Theses and Dissertations

Because the probability of Type I error is not evenly distributed beyond upper and lower three-sigma limits the c chart is theoretically inappropriate for a monitor of Poisson distributed phenomena. Furthermore, the normal approximation to the Poisson is of little use when c is small. These practical and theoretical concerns should motivate the computation of true error rates associated with individuals control assuming the Poisson distribution. An economic alternative to the c chart is described as a statistical model of upward shift from c0 to c1 and the two charts are compared in theory. For a range of c chart …

Design Of A Pretreatment And Enzymatic Saccharification Scheme Of Understory From Managed Pine Forest For A Biochemical-Refinery Platform: The Example Of The Sweetgum Tree, Angele Djioleu

Graduate Theses and Dissertations

The possibility of using sweetgum from southern pine dominated forests as a biobased refinery feedstock was investigated. First, a baseline hydrolysis scheme for sweetgum wood and bark was designed. Sweetgum wood and bark were pretreated with 0.98% (v/v) sulfuric acid at 140°C for 30, 40, 50, 60 or 70 min and at 160°C for 30, 40, 50 or 60 min. The water insoluble solid (WIS) fraction was hydrolyzed with a cellulase enzyme cocktail. Results showed that maximum xylose and glucose yields from the wood were 82 and 86%, respectively. Similarly, the respective maximum yields of xylose and glucose from the …

A Watershed Scale Evaluation Of Selected Second Generation Biofeedstocks On Water Quality, Gurdeep Singh

Graduate Theses and Dissertations

This study compares a novel simulation approach to the conventional Soil and Water Assessment Tool (SWAT) modeler's approach for targeting biofuel crop production on marginal lands. In conventional SWAT modeling approach, non-spatial definition of hydrological response units (HRUs) results in the simulation of biofuel crops on both marginal and non-marginal land. This study provides an alternative approach in which a marginal-land raster was integrated into the land use and land cover (LULC) raster in such a way that the land uses were divided into marginal and non-marginal components. This modified LULC was used for model setup which resulted in marginal …

Penetration Forces For Subsurface Regolith Probes, Ahmed Elshafie

Graduate Theses and Dissertations

Investigating planetary bodies using penetrometers can provide detailed information about its history and evolution. An estimation of subsurface density and porosity can be made from the shape of the penetration curve. Using penetrometers mounted on planetary platforms could be challenging due to the uncertainty of the subsurface composition and since the maximum allowed force for penetration is the weight of the lander or rover on the surface. Estimation of penetration forces can provide a reliable constraint on the maximum reachable depth without endangering the whole mission. Therefore, knowledge of the required penetration force to specific depths can be helpful in …

On The Representation Of Inverse Semigroups By Difunctional Relations, Nathan Bloomfield

Graduate Theses and Dissertations

A semigroup S is called inverse if for each s in S, there exists a unique t in S such that sts = s and tst = t. A relation σ contained in X x Y is called full if for all x in X and y in Y there exist x' in X and y' in Y such that (x, y') and (x', y) are in σ, and is called difunctional if σ satisfies the equation σ σ^-1 σ = σ. Inverse semigroups were introduced by Wagner and Preston in 1952 and 1954, respectively, and difunctional relations were …

Plasmonic And Photonic Designs For Light Trapping In Thin Film Solar Cells, Liming Ji

Graduate Theses and Dissertations

Thin film solar cells are promising to realize cheap solar energy. Compared to conventional wafer cells, they can reduce the use of semiconductor material by 90%. The efficiency of thin film solar cells, however, is limited due to insufficient light absorption. Sufficient light absorption at the bandgap of semiconductor requires a light path more than 10x the thickness of the semiconductor. Advanced designs for light trapping are necessary for solar cells to absorb sufficient light within a limited volume of semiconductor. The goal is to convert the incident light into a trapped mode in the semiconductor layer.

In this dissertation, …

Investigating The Sensitivity Of Goodness-Of-Fit Indices To Detect Measurement Invariance In The Bifactor Model, Jam Khojasteh

Graduate Theses and Dissertations

A Monte Carlo simulation study was conducted to evaluate the sensitivities of five commonly used goodness-of-fit indices to detect metric invariance properties of the bifactor model. The fit indices that performed the best in terms of power were Gamma and Mc. In addition, Gamma, Mc, CFI, and RMSEA all held Type I error to a minimum. However, only Gamma and CFI are recommended to use in the bifactor model because the other GOF indices have cutoff values that are too large. For Gamma and CFI values of -.026 to -.045 and -.004 to -.009, respectively indicate a lack of metric …

Habitat Modeling Of Three Endemic Crayfish Species In The Black River Drainage Of Missouri And Arkansas: Factors Affecting Distribution And Abundance, Matthew Stephen Nolen

Graduate Theses and Dissertations

The Ozark faunal region of Missouri and Arkansas harbors a high level of aquatic biological diversity, especially in regards to endemic crayfish. Orconectes eupunctus, Orconectes marchandi, and Cambarus hubbsi are three such endemics that are threatened by a limited natural distribution and the invasions of Orconectes neglectus. I sought to determine how natural and anthropogenic factors influence these three species across multiple spatial scales. Local and landscape data were used in decision tree analyses (CART) to determine their influence effect on presence/absence and density of the three species. Predictive models were validated using k-fold cross validation. O. eupunctus presence was …

Diagenesis And Reservoir Characterization Of The Pennsylvanian Middle Atoka Formation, Sebastian And Logan Counties, West-Central Arkansas, Elvis Chekwube Bello

Graduate Theses and Dissertations

The Middle Atoka Formation evolved from a stable passive margin during the early Pennsylvanian time to a rapidly subsiding basin, with the sedimentary fill thickening greatly southward during the middle Pennsylvanian time. The basin dips in north-south direction. An east-west anticlines and synclines were observed.

The purpose of this study is to establish the stratigraphic units, reservoir geometry and distribution, and infer the depositional environments and reservoir quality. Well correlation and petrographic studies are used to achieve the goals.

Sandstone Point Count method was used. The Point Counts was divided into five categories. They include the framework grains (quartz, feldspar, …

Pulse Sharpening Effects Of Thin Film Ferroelectric Transmission Lines, Robert J. Sleezer

Graduate Theses and Dissertations

Advances in material science have resulted in the development of electrically nonlinear high dielectric thin film ferroelectrics, which have led to new opportunities for the creation of novel devices. This dissertation investigated one such device: a low voltage nonlinear transmission line (NLTL). A finite element simulation of ferroelectric transmission lines showed that NLTLs are capable of creating shockwaves. Additionally, if the losses are kept sufficiently low, it was shown that voltage gain should be possible. Furthermore, a method of accounting for material dispersion was developed. Results from simulations including material dispersion showed that temporal solitons might be possible from a …

Exploring The Surface Liquid And Lake Regions Of Titan With Laboratory Experimentation And Cassini Spacecraft Data, Felix Casimir Wasiak

Graduate Theses and Dissertations

The surface liquids and lake regions of Titan are studied utilizing three unique techniques, the results of which are reported in this dissertation. The development of a facility to simulate the surface conditions of Titan, and to conduct experiments on samples within that facility, brings an understanding of Titan's surface not possible through observation and modeling alone. The properties of this facility are presented, including conceptual methodology, design, implementation, performance, and experimental results. The facility, the main component of which is a simulation chamber, allows for Titan temperatures of 90 - 94 K and a 1.5 bar N2 atmosphere. The …

Effects Of Testing Time On Anaerobic Toxicity Assessment, Omolola Atinuke Akintomide

Graduate Theses and Dissertations

Anaerobic digestion has been widely used for wastewater treatment for decades. Several Anaerobic Toxicity tests have been developed to screen wastewater for toxicity and assess the treatability of such toxicants. However, past research and reviews on Biochemical Methane Potential (BMP) test and Anaerobic Toxicity Assay (ATA) were considered in this study.

The experimental tests included ammonium-nitrogen and sodium chloride toxicity tests with varied concentration and solid retention time. These tests were designed to demonstrate the impact of ammonia- nitrogen and sodium chloride on the biological degradation process. The anaerobic test set-up includes bench-scale test reactors and respirometers used for measuring …

Magnitude And Frequency Of Floods For Rural, Unregulated Streams Of Tennessee By L-Moments Method, Hongxiang Yan

Graduate Theses and Dissertations

This study presents a regional frequency analysis of Tennessee using the well-known Bulletin-17B method standardly used in the United States and the relatively new and developing L-Moments methods. Flood frequency characteristics were defined for 416 gaging stations located primarily in rural and lightly developed areas of Tennessee. All the gaging stations have 10 or more years of record through 2006. Using the L-Moments method, the generalized extreme value distribution was identified as the most robust distribution for each of four hydrologic areas. Multiple regression equations were also calculated for estimating the flood frequency of ungaged, unregulated, rural streams in each …

The Development Of A High Performance Concrete To Store Thermal Energy For Concentrating Solar Power Plants, Emerson Esmond John

Graduate Theses and Dissertations

In recent years, due to rising energy costs as well as an increased awareness of the environmental effects of greenhouse gas emissions produced through traditional forms of energy production, there is great interest in developing alternative sources of energy. One of the most viable alternative energy sources is solar energy. In particular, concentrating solar power (CSP) technologies have been identified as an option for meeting utility needs in the U.S. Southwest. These systems are required to produce electricity not only during periods of high solar radiation but also during times of reduced radiation due to cloud cover, and even extend …

Locating And Protecting Facilities Subject To Random Disruptions And Attacks, Hugh Medal

Graduate Theses and Dissertations

Recent events such as the 2011 Tohoku earthquake and tsunami in Japan have revealed the vulnerability of networks such as supply chains to disruptive events. In particular, it has become apparent that the failure of a few elements of an infrastructure system can cause a system-wide disruption. Thus, it is important to learn more about which elements of infrastructure systems are most critical and how to protect an infrastructure system from the effects of a disruption. This dissertation seeks to enhance the understanding of how to design and protect networked infrastructure systems from disruptions by developing new mathematical models and …

Investing In An Agricultural Legacy, Leo Paul Goeringer

Graduate Theses and Dissertations

America's agricultural producers continue to age. According to the U.S. Census of Agriculture, the average age of farm operators increased from 55.3 in 2002 to 57.1 in 2007. During the same period, the Census shows a thirty percent decrease in the number of farmers under age 25. Young and beginning producers (YBPs) entering agriculture face high startup costs and a shortage of land to own or rent.

With these concerns in mind, this manuscript details the impact of an innovative proposed loan program for YBPs in Arkansas, which would offer concessionary interest rates and loan fees by participating banks for …

Outcrop Investigation Of The Reeds Spring (Boone, Mississippian) Of The Hindsville Quarry Using Terrestrial Lidar, Terryl Glenn Daniels

Graduate Theses and Dissertations

In northern Oklahoma and southern Kansas the Reeds Springs Formation (Boone, Mississippian) is a hydrocarbon exploration objective (Mazullo et al, 2011). The Hindsville quarry located in the northeastern portion of Washington County in Arkansas is the focus of this study. The objective of this study is to characterize the Reeds Spring at the Hindsville Quarry. The use of terrestrial light detecting and ranging(LiDAR) is used to assist in the characterization of the quarry.

The unit architecture within the Hindsville Quarry outlines varying transitional periods that give insight into the deposition of the Reeds Springs Formation. There are comparable formations within …

Semiconductor Nanocrystals: From Quantum Dots To Quantum Disks, Zheng Li

Graduate Theses and Dissertations

The bottom-up colloidal synthesis opened up the possibility of finely tuning and tailoring the semiconductor nanocrystals. Numerous recipes were developed for the preparation of colloidal semiconductor nanocrystals, especially the traditional quantum dots. However, due to the lack of thorough understanding to those systems, the synthesis chemistry is still on the empirical level. CdS quantum dots synthesis in non-coordinating solvent were taken as a model system to investigate its molecular mechanism and formation process, ODE was identified as the reducing agent for the preparation of CdS nanocrystals, non-injection and low-temperature synthesis methods developed. In this model system, we not only proved …

A Daily Temperature Record For Central Texas, 1896-2011, Matthew Kain Taylor

Graduate Theses and Dissertations

A continuous record of 882,693 daily maximum, minimum, and mean temperature measurements for seven weather stations in central Texas dating from August 1, 1896, to August 31, 2011, were screened and corrected for missing values and inhomogeneities. The resulting data were averaged to create a 115-year unbroken regional record of daily temperature for central Texas. This record indicates warming in daily, seasonal, and annual temperatures. Winter warm temperature extremes have increased over the period of record while warm temperature extremes during the summer months have remained largely unchanged. Summer heat wave days and the length of heat waves have increased …

A Subsurface Stratigraphic Study Of The Middle Atoka, Sebastian County, Arkansas, Sara Beth Sutton

Graduate Theses and Dissertations

Raster log images were analyzed to study the subsurface stratigraphy of the Middle Atoka in the Arkoma Basin of the western portion (Sebastian County) of Arkansas. The most significant sandstone units of the Middle Atoka in this area were determined to be two generally coarsening-upward sequences in the lower portion of the formation. Based on lithologic correlations, these two units were determined to be the informally named Casey and Freiburg members of the Middle Atoka. Thickness information based on picked tops was used to create isopach maps of the units of interest. The log signatures and geometry of the sand …

The Relationship Between Middle Level School Science Programs And A Residential Environmental Learning Center, Ryan Mathew Walker

Graduate Theses and Dissertations

A multiple case study investigation examines the relationship between a residential environmental learning center and six schools that attend their program. Pre-experience interviews were conducted with teachers to gain understanding of how they integrate the residential experience with formal classroom instruction. On-site observations of teacher participation during the program provided insight into how they foster student learning during the experience. A student questionnaire was used to reveal students' perceptions of three areas of interest: 1) most meaningful aspects of the experience, 2) most confusing aspects of the experience and 3) topics they would like to know more about. These data …

An Extension To Particle Polarizability To Predict Coupling Behavior In Periodic Nanoplasmonic Arrays, Drew Dejarnette

Graduate Theses and Dissertations

Plasmonic nanoparticles organized in arrays interact to create spectral patterns which are amplified by individual particle polarizability. It was hypothesized that particle polarizability could be used as a predictor of spectral behavior from far-field interactions within the array. Inter-particle coupling produced an extraordinary peak in extinction efficiency at wavelengths equal to or larger than the single particle plasmon resonance peak. Interactions that produced constructive coupling were found to mimic changes in the particle polarizability model. Testing of the hypothesis was performed using the coupled dipole approximation with parametric characterization of array geometries, giving specific particle size and lattice constant combinations …

Reservoir Characterization And Outcrop Analog: The Osagean Reeds Spring Formation (Lower Boone), Western Osage And Eastern Kay County, Oklahoma, Taylor Friesenhahn

Graduate Theses and Dissertations

The Reeds Spring Formation (Osagean) is a member of the Lower Mississippian carbonate series developed on the Cherokee Platform Province of northeastern Oklahoma. On the western flank of the Ozark Dome, these rocks dip in a west-southwest direction into the subsurface where they are oil and gas reservoirs. A series of road cuts and surface exposures are cropped out in the tri-state area of northwest Arkansas, northeastern Oklahoma, and southwestern Missouri. Outcrop characteristics, including an abundant amount of nodular, anastomosing chert, generally finer-grained carbonate texture, and stratigraphic relationships provide an analog for its subsurface counterpart. Based on core description and …